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61.
Adrian Lawrence Marianne Stuart Colin Cheney Neil Jones Richard Moss 《Hydrogeology Journal》2006,14(8):1470-1482
Contaminant migration behaviour in the unsaturated zone of a fractured porous aquifer is discussed in the context of a study site in Cheshire, UK. The site is situated on gently dipping sandstones, adjacent to a linear lagoon historically used to dispose of industrial wastes containing chlorinated solvents. Two cores of more than 100 m length were recovered and measurements of chlorinated hydrocarbons (CHCs), inorganic chemistry, lithology, fracturing and aquifer properties were made. The results show that selecting an appropriate vertical sampling density is crucial both to providing an understanding of contaminant pathways and distinguishing whether CHCs are present in the aqueous or non-aqueous phase. The spacing of such sampling should be on a similar scale to the heterogeneity that controls water and contaminant movement. For some sections of the Permo-Triassic aquifer, significant changes in lithology and permeability occur over vertical distances of less than 1 m and samples need to be collected at this interval, otherwise considerable resolution is lost, potentially leading to erroneous interpretation of data. At this site, although CHC concentrations were high, the consistent ratio of the two main components of the plume (tetrachloroethene and trichloroethene) provided evidence of movement in the aqueous phase rather than in dense non-aqueous phase liquid (DNAPL). 相似文献
62.
S-S. Xu A. F. Nieto-Samaniego S. A. Alaniz-Álvarez L. G. Velasquillo-Martínez 《International Journal of Earth Sciences》2006,95(5):841-853
The power-law exponent (n) in the equation: D=cL
n
, with D = maximum displacement and L = fault length, would be affected by deviations of fault trace length. (1) Assuming n=1, numerical simulations on the effect of sampling and linkage on fault length and length–displacement relationship are done in this paper. The results show that: (a) uniform relative deviations, which means all faults within a dataset have the same relative deviation, do not affect the value of n; (b) deviations of the fault length due to unresolved fault tip decrease the values of n and the deviations of n increase with the increasing length deviations; (c) fault linkage and observed dimensions either increase or decrease the value of n depending on the distribution of deviations within a dataset; (d) mixed deviations of the fault lengths are either negative or positive and cause the values of n to either decrease or increase; (e) a dataset combined from two or more datasets with different values of c and orders of magnitude also cause the values of n to deviate. (2) Data including 19 datasets and spanning more than eight orders of fault length magnitudes (10−2–105 m) collected from the published literature indicate that the values of n range from 0.55 to 1.5, the average value being 1.0813, and the peak value of n
d (double regression) is 1.0–1.1. Based on above results from the simulations and published data, we propose that the relationship between the maximum displacement and fault length in a single tectonic environment with uniform mechanical properties is linear, and the value of n deviated from 1 is mainly caused by the sampling and linkage effects. 相似文献
63.
The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol. 相似文献
64.
Mass size distribution of the crustal elements (Al, Ca, Fe, Mg, Si, Ti), anthropogenic elements (Zn, Mn, Cr, Cu, K, P, Pb) and sea elements (Na, Cl) were obtained from measurements carried out with an inertial cascade impactor in Sfax. A fitting procedure by data inversion was applied to those data. This procedure yields accurate size distributions of aerosols in the diameter range 0.1–25 μm in two different sites. In a coastal industrial site, the mass distribution of the aerosol showed a bimodal structure; and in urban area, the lower particle mode cannot be observed. The elemental dry deposition flux was calculated as a function of particle size. The element flux size distribution increased rapidly with particle size. The modelling results indicate that the majority of the crustal and anthropogenic elements flux (>90%) was due to particles larger than 3 μm in diameter. 相似文献
65.
Mark E. Hodson 《Chemical Geology》2002,190(1-4):91-112
Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10−14 mol/m2/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10−14 mol/m2/s) and sheet silicates (100×10−14 mol/m2/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10−14 mol/m2/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions. 相似文献
66.
Channel curvature produces secondary currents and a transverse sloping channel bed, along which the depth increases towards the outer bank. As a result deep pools tend to form adjacent to the outer bank, promoting bank collapse. The interaction of sediment grains with the primary and secondary flow and the transverse sloping bed also causes meanders to move different grain sizes in different proportions and directions, resulting in a consistent sorting pattern. Several models have been developed to describe this process, but they all have the potential to over‐predict pool depth because they cannot account for the influence of erodible banks. In reality, bank collapse might lead to the development of a wider, shallower cross‐section and any resulting flow depth discrepancy can bias associated predictions of flow, sediment transport, and grain‐size sorting. While bed topography, sediment transport and grain sorting in bends will partly be controlled by the sedimentary characteristics of the bank materials, the magnitude of this effect has not previously been explored. This paper reports the development of a model of flow, sediment transport, grain‐size sorting, and bed topography for river bends with erodible banks. The model is tested via intercomparison of predicted and observed bed topography in one low‐energy (5·3 W m?2 specific stream power) and one high‐energy (43·4 W m?2) study reach, namely the River South Esk in Scotland and Goodwin Creek in Mississippi, respectively. Model predictions of bed topography are found to be satisfactory, at least close to the apices of bends. Finally, the model is used in sensitivity analyses that provide insight into the influence of bank erodibility on equilibrium meander morphology and associated patterns of grain‐size sorting. The sensitivity of meander response to bank cohesion is found to increase as a function of the available stream power within the two study bends. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
67.
68.
69.
两个冰期-间冰期旋回的黄土记录及其古气候意义 总被引:9,自引:14,他引:9
北京邻区枣沟、斋堂和赤峰黄土-古土壤剖面粒度和磁化率变化在幅度和相位上都有明显的差异。在两个冰期-间冰期旋回,磁化率记录具有冰量变化模式,而粒度记录具有轨道周期特点,粒度和磁化率之间的相位关系在从冰期向间冰期转换和冰期向间冰期过渡的过程中,既有滞后也有超前的表现,很难单纯以成土作用来解释。由于黄土粒度主要反映粉尘源区环境和古风场强度的变化,而磁化率主要记录的是沉积区的成壤作用,反映夏季风的强度变化,因此剖面粒度和磁化率变化的不协调说明古风场和粉尘源区变化与粉尘沉积区气候变化之间不统一。这可能意味着控制夏季风强度变化和控制冬季风强度变化的机制存在差异。 相似文献
70.
坝上高原安固里淖粒度年纹层与环境变化 总被引:9,自引:2,他引:9
在安固里淖湖心区获取一未扰动沉积物样柱,分析发现了由冬季风搬运物与湖心沉积共同形成的粒度年纹层,建立了纹层年表,恢复了安固里淖湖区8507aB.P,以来的环境变化过程。8507-5429aB.P。冬季风活动较弱,后期的所波动;5429-3244aB.P.冬季风活动较强,3244-2494aB.P。冬季风活动减弱;2494-1165aB.P。冬季风活动略有增强;1165aB.P以来,冬季风活动减弱。安固里小淖粒度年纹层反映的冬季风变化情况与我国北方地区同期的环境变化和海平面变化有很好的对应关系。 相似文献