SHRIMP U–Pb ages of detrital zircons from the Early Cretaceous Nakdong Formation,South East Korea: Timing of initiation of the Gyeongsang Basin and its provenance

To constrain the depositional age of the lowermost Nakdong Formation in the Early Cretaceous Gyeongsang Basin, SHRIMP U–Pb age determination was carried out on zircon separates. The U–Pb compositions of detrital zircons from the Nakdong Formation yield a wide range of ages from the Archean to the Cretaceous but show a marked contrast in age distribution according to the geographical locations within the basin. The provenance of the southern Nakdong Formation is dominantly the surrounding Yeongnam Massif, which is composed of Paleoproterozoic metamorphic rocks and Triassic to Jurassic plutonic rocks, whereas the central to northern Nakdong Formation records significant sediment derivation from the Okcheon Metamorphic Belt, which is distributed to the northwest, in addition to the contribution from the Yeongnam Massif. It is suggested that the maximum depositional age of the Nakdong Formation is ca 127 Ma, based on its youngest detrital zircon age population. The onset of its deposition at 127 Ma coincided with the tectonic inversion in East Asia from a compressional to an extensional geodynamic setting, probably due to the contemporaneous change in the drift direction of the Izanagi Plate and its subsequent oblique subduction.     

Deglacial palaeoclimate at Puerto del Hambre,subantarctic Patagonia,Chile

The primary objective of this study is to further substantiate multistep climatic forcing of late‐glacial vegetation in southern South America. A secondary objective is to establish the age of deglaciation in Estrecho de Magallanes–Bahía Inútil. Pollen assemblages at 2‐cm intervals in a core of the mire at Puerto del Hambre (53°36′21″S, 70°55′53″W) provide the basis for reconstructing the vegetation and a detailed account of palaeoclimate in subantarctic Patagonia. Chronology over the 262‐cm length of core is regulated by 20 AMS radiocarbon dates between 14 455 and 10 089 ¹⁴C yr BP. Of 13 pollen assemblage zones, the earliest representing the Oldest Dryas chronozone (14 455–13 000 ¹⁴C yr BP) records impoverished steppe with decreasing frequencies and loss of southern beech (Nothofagus). Successive 100‐yr‐long episodes of grass/herbs and of heath (Empetrum/Ericaceae) before 14 000 ¹⁴C yr BP infer deglacial successional communities under a climate of increased continentality prior to the establishment of grass‐dominated steppe. The Bølling–Allerød (13 000–11 000 ¹⁴C yr BP) is characterised by mesic grassland under moderating climate that with abrupt change to heath dominance after 12 000 ¹⁴C yr BP was warmer and not as humid. At the time of the Younger Dryas (11 000–10 000 ¹⁴C yr BP), grass steppe expanded with a return of colder, more humid climate. Later, with gradual warming, communities were invaded by southern beech. The Puerto del Hambre record parallels multistep, deglacial palaeoclimatic sequences reported elsewhere in the Southern Andes and at Taylor Dome in Antarctica. Deglaciation of Estrecho de Magallanes–Bahía Inútil is dated close to 14 455 ¹⁴C yr BP, invalidating earlier dates of between 15 800 and 16 590 ¹⁴C yr BP. Copyright © 2000 John Wiley & Sons, Ltd.     

华北克拉通太古宙典型地区栖霞县幅1∶5万地质图修编——野外地质调查和SHRIMP锆石U-Pb定年

栖霞是胶东早前寒武纪变质基底的典型地区。在原1∶5万地质图中,许多TTG岩石都被作为胶东群表壳岩看待,岩石形成时代也只在少数露头被确定。根据野外地质调查和SHRIMP锆石U-Pb定年,对该区TTG岩石时空分布进行了研究。在新修编的1∶5万地质图中,太古宙变质基底的主要岩石类型为约2.9Ga、约2.7Ga和约2.5Ga的英云闪长质片麻岩,也存在少量同时代的奥长花岗质片麻岩。2.9Ga和2.5Ga左右的表壳岩(黄崖底表壳岩和胶东群)比原认为要少得多。所有岩石大致呈北西西—南东东向分布,它们在空间上共存,可能是新太古代晚期和古元古代晚期强烈构造热事件作用的结果。这是国内首次在复杂的太古宙高级变质岩区,以野外地质调查和SHRIMP锆石U-Pb定年有机结合,确定不同类型、不同时代地质体时空分布的有益尝试,对于今后类似地区开展专题地质填图具有重要的借鉴意义。     

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.     

Geochemical and geochronological characteristics of the Um Rus granite intrusion and associated gold deposit,Eastern Desert,Egypt

The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.     

A GIS-based multi-proxy analysis of the evolution of subglacial dynamics of the Quebec–Labrador ice dome,northeastern Quebec,Canada

The glacial records of the inner-core regions of the Laurentide Ice Sheet (LIS) document complex yet coherent patterns reflecting ice-sheet change (e.g. ice-divide migration), providing unique insights into past glacial conditions. This study develops a conceptual model of subglacial dynamics evolution within a major ice-dispersal centre of the LIS in northeastern Quebec, Canada using a GIS-based analysis of the surficial geologic record. Multiple proxies of subglacial conditions (subglacial streamlined landforms, lake density and lake area over thin drift/bedrock) were analysed through grid-overlay techniques and then classified based on different proxy variables ranging from highly mobile warm-based to immobile cold-based conditions. An additional proxy (till blanket) was used to identify areas of thick till deposition, but with few proxies (few lake or landform metrics). Based on local ice-flow reconstructions, the most ‘relict’ glacial terrain zone (GTZ1) has warm-based conditions over 66% of its area and is remarkably well preserved, suggesting laterally extensive warm-based conditions during the oldest identified ice-flow phase. This relict glacial terrain is partially overprinted by two subsequent ice-flow phases in spatially restricted zones in the northeast (73% warm-based), east-central (41% warm-based), and northwest (33% warm-based) of the study area. A zone of more sluggish conditions (only 3% warm-based) was identified in the highlands at the centre of the study area, characterized by thin till cover, few landforms, yet with large patches of relatively abundant small lakes, indicative of areal scouring. No clear evidence of sustained cold-based conditions (i.e. high chemical index of alteration values or high ¹⁰Be abundances) was found in the study area. These results suggest that warm-based conditions (active erosion and/or deposition) were uniformly widespread during the earliest ice-flow phase, later becoming more spatially restricted with broader sluggish ice conditions. These spatially restricted regions of warm-based subglacial regimes were likely controlled by surrounding and down-flow ice streaming. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Timing and development of sedimentation of the Cleaverville Formation and a post‐accretion pull‐apart system in the Cleaverville area,coastal Pilbara Terrane,Pilbara, Western Australia

In the Cleaverville area of Western Australia, the Regal, Dixon Island, and Cleaverville Formations preserve a Mesoarchean lower‐greenschist‐facies volcano‐sedimentary succession in the coastal Pilbara Terrane. These formations are distributed in a rhomboidal‐shaped area and are unconformably overlain by two narrowly distributed shallow‐marine sedimentary sequences: the Sixty‐Six Hill and Forty‐Four Hill Members of the Lizard Hills Formation. The former member is preserved within the core of the Cleaverville Syncline and the latter formed along the northeast‐trending Eighty‐Seven Fault. Based on the metamorphic grade and structures, two deformation events are recognized: D₁ resulted in folding caused by a collisional event, and D₂ resulted in regional sinistral strike‐slip deformation. A previous study reported that the Cleaverville Formation was deposited at 3020 Ma, after the Prinsep Orogeny (3070–3050 Ma). Our SHRIMP U–Pb zircon ages show that: (i) graded volcaniclastic–felsic tuff within the black shale sequence below the banded iron formation in the Cleaverville Formation yields an age of (3 114 ±14) Ma; (ii) the youngest zircons in sandstones of the Sixty‐Six Hill Member, which unconformably overlies pillow basalt of the Regal Formation, yield ages of 3090–3060 Ma; and (iii) zircons in sandstones of the Forty‐Four Hill Member show two age peaks at 3270 Ma and 3020 Ma. In this way, the Cleaverville Formation was deposited at 3114–3060 Ma and was deformed at 3070–3050 Ma (D₁). Depositional age of the Cleaverville Formation is at least 40–90 Myr older than that proposed in previous studies and pre‐dates the Prinsep Orogeny (3070–3050 Ma). After 3020 Ma, D₂ resulted in the formation of a regional strike‐slip pull‐apart basin in the Cleaverville area. The lower‐greenschist‐facies volcano‐sedimentary rocks are distributed only within this basin structure. This strike‐slip deformation was synchronous with crustal‐scale sinistral shear deformation (3000–2930 Ma) in the Pilbara region.     

第四纪以来天津北部燕山隆升与山前盆地的形成*

文中报道了天津市北部燕山山前地带共4个高岩心采取率钻孔的沉积学、地层学、年代学和微体古生物综合研究。420个热退磁样品的磁倾角曲线显示,具147 m厚松散地层的标准孔Z3孔下部地层属于2.58 Ma的松山(Matuyama)极性带。随着地壳沉降,只是从早更新世,冲积扇侧缘泥质沉积物才开始充填了底砾岩层之上的沉积空间,形成广义的山前盆地中的泛滥平原;与传统上视为上新统特征沉积的红棕色黏土类似的亮黄橙-黄橙色-亮红棕色黏土,延续出现到早更新世中期,当时区域沉降中心位于距离山前断裂不足4 km处。0.78 Ma以来的布容(Brunhes)极性带厚57.8 m。谨慎地依据120 ka的布莱克(Blake)亚时确定上更新统后,可见中更新统大部缺失,与天津市区沧县隆起和北京永定河冲积平原南部所见此时的地层间断十分相近。3个钻孔的7个¹⁴C测年数据证实,距离山前断裂不足2 km的钻孔45 ka以来的地层最厚达41 m;显示自MIS3初始期,沉降中心向北迁移更靠近山前断裂,且在构造断裂作用下形成了新的狭义的山前盆地。研究区可见15 ka富有机质黏土及上覆泥炭,表明末次冰消期开始的气候转暖首先影响到华北平原山前地区。此项工作为研究晚新生代以来“源到汇”过程中渤海湾西岸的沉降提供了一个基准点。     

树轮长年表在全球变化相关领域中的应用研究进展-以14C曲线校正、环境考古和地质灾害事件定年为例

近几十年树轮年代学得到了迅速发展,现已成功建立了大量长度逾千年的树轮长年表。本文评述树轮长年表在全球变化相关研究领域中的应用。树轮长年表可为¹⁴C定年提供校准曲线,从而将样本的¹⁴C年龄转化为日历年龄,提高了¹⁴C测年的精度;也可为环境考古如古木建筑及墓葬等提供定年服务,确定古木构建筑的建造年代;树轮长年表在地质灾害事件定年方面也发挥了重要作用。然而,树轮长年表在上述研究领域的应用也存在不足,最新的国际¹⁴C会议公布的¹⁴C校正曲线中能够准确定年的树轮校正部分仅为过去12 410年,目前尚无法提供更长时间尺度的树轮校正曲线。在对木构建筑进行定年时受到古木样本量不足的限制等。因此,为了更好地发挥树轮长年表的应用潜力,应不断发掘与延长现有树轮宽度长年表,同时建立长年表的C、O同位素序列,以期为长年表的应用不断做出贡献。     

小冰期福建海岸沙丘的沉积环境

选取福建东南沿海典型海岸沙丘——东海沙丘,运用GPR（Ground Penetrating Radar）技术探测海岸沙丘内部构造,辅助天然剖面和人工探槽观测,进行系统的年代采样与OSL（Optically Stimulated Luminescence）测年,并选择物理意义明确的粒度参数作为主要环境代用指标,获得了亚热带季风区砂质海岸带典型海岸沙丘的沉积年代和沉积结构。结果表明：（1）东海沙丘是由若干灌丛沙丘组成的横向沙丘,0～6 m主要是～0.45 ka BP以来形成的海岸风成沙丘,可以划分为～0.45 ka BP和0.22～0.12 ka BP两个阶段。（2）东海沙丘沉积过程是多因素共同作用的结果,冷干的气候环境是沙丘发育的适宜条件,入境台风频率增加可能加快了风沙的沉积过程。对比历史文献资料发现,气候异常期往往与社会动荡期、重要历史事件相对应。