The rapidly shrinking cryopshere in the past decade：an interpretation of cryospheric changes from IPCC WGI Sixth Assessment Report北大核心CSCD

The Working Group I report of the Sixth Assessment Report（AR6）of the Intergovernmental Panel on Climate Change（IPCC）was released in August 2021. Base on updated and expanding data, AR6 presented the improved assessment of past changes and processes of cryosphere. AR6 also predicted the future changes us⁃ ing the models in CMIP6. The components of cryosphere were rapid shrinking under climate warming in the last decade. There were decreasing trends in Arctic sea-ice area and thickness. Sea-ice loss was significant. The Greenland Ice Sheet, the Antarctic Ice Sheet and all glaciers lost more mass than in any other decade. Global warming over the last decades had led to widespread permafrost warming, active layer thickness increasing and subsea permafrost extent reducing. Snow cover extent in the Northern Hemisphere also decreased significantly. However, the variations of snow depth and snow water equivalent showed great spatial heterogeneity. The rapid shrinking of the cryosphere accelerated the global mean sea level rise. The impact of human activities on cryo⁃ sphere will become more significant in the future. The Arctic sea-ice area will decrease, and the Arctic Ocean will likely become practically sea ice-free. The Greenland Ice Sheet, the Antarctic Ice Sheet and glaciers will continue to lose mass throughout this century. Permafrost and Northern Hemisphere snow cover extent will con⁃ tinue to decrease as global climate continues to warm. In addition, there are still uncertainties in the prediction of cryosphere due to the absence of observations, the poor sensitivity of models to the components and processes of cryosphere, and the inexplicit represent of the mechanism of light-absorbing impurities. More attentions should be paid on these issues in the future. © 2022 Science Press (China). All rights reserved.     

溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。     

A two-zone model for the broad iron line emission in MCG–6-30-15

We reanalyse the ASCA and BeppoSAX data of MCG–6-30-15, using a double-zone model for the iron line profile. In this model, the X-ray source is located around ≈10 Schwarzschild radii and the regions interior and exterior to the X-ray source produce the line emission. We find that this model fits the data with a similar reduced χ ² to the standard single-zone model. Thus we show that the presence of a broad iron line feature does not necessarily require that the X-ray source be located close to the last stable orbit or in the disc rotation axis.
Within the framework of this model, the best-fitting inclination angle of the source     for the intermediate-intensity ASCA data set is compatible with that determined by earlier modelling of optical lines. The observed variability of the line profile with intensity can be explained as variations of the X-ray source size. That several active galactic nuclei with broad lines have the peak centroid near 6.4 keV can be explained under certain conditions.
We also show that the simultaneous broad-band observations of this source by BeppoSAX rule out the Comptonization model which was an alternative to the standard inner-disc one. We thereby strengthen the case that line broadening occurs as a result of the strong gravitational influence of a black hole.     

软土地基坑中坑支护体系温度效应的数值分析

环境温度变化导致基坑支护结构内支撑轴力和变形过大的问题不容忽视。本文以福州地铁6号线潘墩站坑中坑工程为例,选取该基坑代表性区段采用ABAQUS程序及邓肯-张模型对其开挖和支护全过程进行三维有限元模拟,并将分析结果与现场部分监测数据进行对比,验证了所建模型及其材料参数取值的可靠性。同时,利用所建模型着重分析当地可能的季节或昼夜温差变化幅度内支撑轴力及围护墙水平位移的变化规律。结果表明：基坑开挖完成后,温度变化时支撑轴力与温度呈线性相关关系,轴力变化主要体现在内外坑的首道支撑上,此时围护结构整体向坑内或坑外运动,且地连墙侧移受温度影响范围主要集中在基坑开挖深度以上。不同开挖阶段的温度变化引起的温度效应相差较大,潘墩站最不利工况发生在最后一道支撑架设完毕后,此时地连墙水平位移增量及轴力变化幅度最大,温度效应最明显。该研究成果对类似软土基坑工程具有重要的理论和实践意义。     

沉淀-陈化-返溶作用和压力对热液中氟钛络合物高温水解的影响及地质意义

钛是自然界中最不活泼的金属元素之一,然而越来越多的证据显示钛可以在特定条件下能进入热液流体中发生迁移,其中氟可能在其中扮演着重要的角色。本文研究了300℃和50~400MPa压力条件下氟钛络合物(K2Ti F6)的稳定性以及沉淀-陈化-返溶作用和压力对氟钛络合物水解行为的影响。研究结果显示,氟钛络合物水解的过程中,由于Ti O2沉淀物的陈化作用,在稳定的温度和压力条件下,沉淀物的返溶很难发生;但在缓慢降温和机械性振荡过程中,沉淀物的返溶会明显发生。而且,在温度不变的情况下,压力的改变对K2Ti F6水解并没有显著的影响,显示氟钛络合物不管在高压还是低压环境下均遵循近似的水解规律。本文认为主要的原因在于压力的增高会促进水解反应沉淀物的陈化,进而抑制沉淀物的返溶,但并不破坏水解反应的平衡。最后,本文提出金属络合物的形成-水解-沉淀/返溶-陈化过程是水-岩作用或热液成矿过程中高场强元素活化、迁移和成矿的主要机制。     

川口油田长6储层成岩作用

详细分析了川口油田长6储层的成岩作用类型、储层物性演化及影响因素。通过岩石学、铸体薄片、电镜扫描等研究方法说明川口油田长6储层主要成岩作用包括压实-压溶作用、胶结作用、交代蚀变作用及溶蚀作用等,成岩阶段属晚成岩A期。其中,机械压实作用、化学胶结作用是导致砂岩孔隙度降低、储集性能变差的主要因素。机械压实作用主要表现为软碎屑的塑性变形、颗粒间由点接触向凹凸接触演变;胶结作用表现为浊沸石、绿泥石、粘土矿物、碳酸盐胶结;石英和长石的次生加大、溶蚀作用特别是浊沸石的溶蚀在一定程度上提高和改善了砂岩储集性能。结果表明,影响储层物性的主要因素为沉积作用和成岩作用。     

Comparison of coupled and uncoupled models in simulating Monsoon Intraseasonal Oscillation from CMIP6

The monsoon intraseasonal oscillation (MISO) is the dominant variability over the Indian Ocean during the Indian summer monsoon (ISM) season and is characterized by pronounced northward propagation. Previous studies have shown that general circulation models (GCMs) still have difficulty in simulating the northward-propagating MISO, and that the role of air-sea interaction in MISO is unclear. In this study, 14 atmosphere-ocean coupled GCMs (CGCMs) and the corresponding atmosphere-only GCMs (AGCMs) are selected from Phase 6 of the Coupled Model Intercomparison Project (CMIP6) to assess their performance in reproducing MISO and the associated vortex tilting mechanism. The results show that both CGCMs and AGCMs are able to well simulate the significant relationship between MISO and vortex tilting. However, 80% of CGCMs show better simulation skills for MISO than AGCMs in CMIP6. In AGCMs, the poor model fidelity in MISO is due to the failure simulation of vortex tilting. Moreover, it is found that failure to simulate the downward motion to the north of convection is responsible for the poor simulation of vortex tilting in AGCMs. In addition, it is observed that there is a significant relationship between the simulated sea surface temperature gradient and simulated vertical velocity shear in the meridional direction. These findings indicate that air-sea interaction may play a vital role in simulating vertical motions in tilting and MISO processes. This work offers us a specific target to improve the MISO simulation and further studies are needed to elucidate the physical processes of this air-sea interaction coupling with vortex tilting.     

A NEW FINDING OF SURFACE RUPTURE ZONES ASSOCIATED WITH THE 1936 LINGSHAN M6(3/4) EARTHQUAKE,GUANGXI, CHINA

On April 1, 1936, an M6(3/4) earthquake occurred on the Fangcheng-lingshan Fault. This event is the biggest historical earthquake on the coastal seismic zone, South China ever. But so far, no any findings about the surface rupture of this event have been reported. This paper is the first to find several intact surface rupture zones associated with the 1936 Lingshan seismic event, in the areas of Gaotang, Jiaogengping etc. on the northeast segment of the Fangcheng-Lingshan Fault. According to the field work, the surface rupture stretches to 10km and distributes along NE direction in front of Luoyang Mountain, represented by earthquake scarp, extensional fracture, dextrally faulted gully and river system etc. The characteristics of surface ruptures and faulted landforms indicate that the surface rupture is of normal-dextral strike slip faulting. The trenching on this fault exposed that at least three seismic events have been recorded, including two historical earthquake events and the latest one is the 1936 Lingshan M6(3/4) earthquake. These surface rupture zones are the key to the detection of seismogenic structure and the re-estimate of magnitude of this event. The new finding of these surface rupture zones would be particularly significant for the detection of the seismogenic structure of Lingshan M6(3/4) earthquake.