岭澳核电三期强风化角岩边坡岩体直剪试验研究

采用堆载法进行天然状态与饱和状态下强风化角岩边坡岩体的现场直接剪切试验,获得不同正应力水平下剪切应力-剪切变形关系曲线和剪切强度参数,对其剪切应力-剪切变形关系曲线特征和不同正应力作用下剪应力随正应力的变化规律以及水-力耦合作用对剪切强度与变形特性影响进行了分析。试验结果表明：岩体峰值剪切强度和屈服剪切强度均随正应力的增大而增大;天然状态和饱水状态下剪应力随不同正应力的变化趋势基本相同;岩体剪切强度随含水率的增大而减小,在低法向应力下尤其敏感;水对岩体强度参数中黏聚力c的弱化作用更加明显,同时加大了岩体变形量,延长了岩体变形过程;通过现场直剪试验测得的法向变形可以估算岩体的压缩模量,为边坡稳定性分析提供参数。     

岩盐物理力学性质及其工程稳定性应用现状及其展望

在分析国内外有关学者关于岩盐的物理力学性质及其工程稳定性应用研究现状基础上,分别从岩盐物理力学性质、岩盐孔隙度、渗透率、塑性变形能力和损伤恢复等物理特性方面,论述了近年来有关岩盐的短期强度特性、岩盐的蠕变性能、围压作用下的力学特性,以及温度效应对岩盐力学特性影响等有关岩盐工程应用中所表现出的物理力学特性;最后从岩盐在工程应用方面,提出了岩盐及其工程应用的发展方向。     

On the scavenging of SO2 by cloud and raindrops: II. An experimental study of SO2 absorption and desorption for water drops in air

For the purpose of testing our previously described theory of SO₂ scavenging a laboratory investigation was carried out in the UCLA 33 m long rainshaft. Drops with radii between 250 and 2500 m were allowed to come to terminal velocity, after which they passed through a chamber of variable length filled with various SO₂ concentrations in air. After falling through a gas separating chamber consisting of a fluorocarbon gas the drops were collected and analyzed for their total S content in order to determine the rate of SO ₂ absorption.The SO₂ concentration in air studied ranged between 1 and 60% (v). Such relatively large concentrations were necessary due to the short times the drops were exposed to SO₂ in the present setup. The present experimental results were therefore not used to simulate atmospheric conditions but rather to test our previously derived theory which is applicable to any laboratory or atmospheric condition. Comparison of our studies with the results from our theory applied to our laboratory conditions led to predicted values for the S concentration in the drops which agreed well with those observed if the drops had radii smaller than 500 m. In order to obtain agreement between predicted and observed S concentrations in larger drops, an empirically derived eddy diffusivity for SO₂ in water had to be included in the theory to take into account the effect of turbulent mixing inside such large drops.In a subsequent set of experiments, drops initially saturated with S (IV) were allowed to fall through S-free air to determine the rate of SO ₂ desorption. The results of these studies also agreed well with the results of our theoretical model, thus justifying the reversibility assumption made in our theoretical models.In a final set of experiments, the effects of oxidation on SO₂ absorption was studied by means of drops containing various amounts of H₂O₂. For comparable exposure times to SO₂, the S concentration in drops with H₂O₂ was found to be up to 10 times higher than the concentration in drops in which no oxidation occurred.     

静电场轨道阱质谱在水中溶解性有机质表征中的应用进展

溶解性有机质(Dissolved Organic Matter,DOM)在水生生态环境中广泛存在,影响着水环境中多种物质的生物地球化学性质.分析其组成与含量具有重要的生态环境意义,是生态环境科学领域研究的热点.溶解性有机质组成非常复杂,其分子组成的解析一直是难题.近年来,具有高分辨率、高灵敏度、高通量、高扫描速率等特性...     

Determination of scoured bridge natural frequencies with soil–structure interaction

This study developed a finite element method with the effect of soil–fluid–structure interaction to calculate bridge natural frequencies. The finite element model includes bridge girders, piers, foundations, soil, and water. The effective mass above the soil surface was then used to find the first natural frequency in each direction. A field experiment was performed to validate that the natural frequencies calculated using the proposed finite element method had acceptable accuracy. The calculated natural frequencies with the fluid–structure interaction effect are always smaller than those without this effect. However, the frequency change due to the fluid effect is not obvious, so using the soil–structure interaction model is accurate enough in the bridge natural frequency analysis. The trend of the frequency decreases with the increase of the scour depth, but the curve is not smooth because of non-uniform foundation sections and layered soils. However, when the scour depth is such that pile cap is exposed, the changes in natural frequency with the scour depth are more obvious, and this is useful for measurement of the depth using bridge natural frequencies.     

Seismic driven probabilistic classification of reservoir facies for static reservoir modelling: a case history in the Barents Sea

In this paper we present a case history of seismic reservoir characterization where we estimate the probability of facies from seismic data and simulate a set of reservoir models honouring seismically‐derived probabilistic information. In appraisal and development phases, seismic data have a key role in reservoir characterization and static reservoir modelling, as in most of the cases seismic data are the only information available far away from the wells. However seismic data do not provide any direct measurements of reservoir properties, which have then to be estimated as a solution of a joint inverse problem. For this reason, we show the application of a complete workflow for static reservoir modelling where seismic data are integrated to derive probability volumes of facies and reservoir properties to condition reservoir geostatistical simulations. The studied case is a clastic reservoir in the Barents Sea, where a complete data set of well logs from five wells and a set of partial‐stacked seismic data are available. The multi‐property workflow is based on seismic inversion, petrophysics and rock physics modelling. In particular, log‐facies are defined on the basis of sedimentological information, petrophysical properties and also their elastic response. The link between petrophysical and elastic attributes is preserved by introducing a rock‐physics model in the inversion methodology. Finally, the uncertainty in the reservoir model is represented by multiple geostatistical realizations. The main result of this workflow is a set of facies realizations and associated rock properties that honour, within a fixed tolerance, seismic and well log data and assess the uncertainty associated with reservoir modelling.     

纳米TiO2分离富集ICP-MS法测定河口环境样品中重金属研究

建立了以纳米二氧化钛（TiO2）作为吸附剂填充微柱,电感耦合等离子体质谱（ICP-MS）法测试Cu^2＋,Cd^2＋,Pb^2＋和Ni^2＋离子的分析方法．考察了不同pH值、洗脱液浓度、样品流速、体积和外源干扰离子的影响,实验结果表明在pH值8～10范围内待测离子可被TiO2定量吸附,2．0molL^-1HNO3可将吸附在微柱上的待测物完全洗脱,优化条件下本方法对溶液中Cu^2＋,Cd^2＋,Ph^2＋和M^2＋离子检出限分别为：0．02,0．01,0．01,0．02μgL～,相对标准偏差小于2％（n=7）,富集系数50倍．对水系沉积物标准物质（GBW07310）的测定值与标准值相一致,方法具有简便、快速,灵敏度高,重现性好的优点,可满足河口水体与沉积物样品中痕量金属元素定量分析的要求．     

Kinematics of active earthflows revealed by digital image correlation and DEM subtraction techniques applied to multi‐temporal LiDAR data

Earthflow‐type landslides are persistent natural hazards having deep socio‐economic and environmental consequences. They have significantly contributed to the geomorphic evolution of mountainous slopes in Europe since the Late Glacial. An understanding of their complex kinematics is crucial to better constrain the processes governing their occurrence and mobility. In this work we explored the possibility to quantify displacement vectors on a spatially distributed basis and to quantify volumetric transfer at the slope scale with regard to a large flow‐type landslide located in the northern Apennines of Italy. For this purpose we applied digital image correlation (DIC) and digital elevation model differencing (DEMoD) techniques to multi‐temporal airborne LiDAR surveys of 2006, 2007 and 2009. The DIC was applied to greyscale slope gradient maps retrieved after precise co‐registration of LiDAR surveys. Thereby, movement patterns over various sectors of the landslide were reconstructed and quantified, most notably up to 20 m in the head zone, up to 51 m in the lower main track, and up to about 27 m at the landslide toe. The DEMoD analysis revealed significant mass transfer from the source to the tracks and toe zone, with the upper flow tracks acting as temporal storage of large amounts of material. The mass balance indicated that significant amounts of advancing landslide debris were eroded by a local stream. An integrated analysis of DEMoD and DIC results allowed for a discussion of governing processes, such as the transition from slide to flow, the influence of underlying topography on earthflow mobility, and the role of undrained loading as a mechanism of toe zone reactivation. In conclusion, the successful application of DIC and DEMoD to the case study underlines the added value of high‐resolution DEMs in the analysis of earthflow kinematics toward a better understanding of their role in the geomorphic evolution of slopes. Copyright © 2012 John Wiley & Sons, Ltd.     

The potential of historic rock avalanches and man-made structures as chlorine-36 production rate calibration sites

Samples from three medieval rock avalanches from the French (Le Claps, Mont Granier) and Austrian Alps (Dobratsch) and a man-made structure, i.e. the Stephansdom in Vienna, have been analysed for in-situ produced ³⁶Cl by accelerator mass spectrometry (AMS). All four sampling sites of independently known exposure duration turned out to be not appropriate as calibration sites for the determination of the ³⁶Cl-production rate from Ca. Indeed, the determination of short exposure ages for dating rock avalanches and man-made structures by ³⁶Cl is hindered dramatically by inheritance, especially for samples characterized by high ^natCl-concentrations. Generally, there are hints that the theoretical calculation of ³⁶Cl-production from epithermal and thermal neutron-capture on ³⁵Cl is highly underestimated in all existing models, thus, asking for particular precaution if working on high-Cl samples for any project. Hence, this work evidences that potential high inheritance, even for samples reasonably shielded before exhumation, has to be considered especially when dealing with recently exposed surfaces such as glacially polished rocks, alluvial terraces, fault scarps etc.     

Nontectonic signals in reprocessed continuous GPS position time series of CMONOC

The nearly nine-year continuous GPS data collected since 1 March 1999 from the Crustal Motion Observation Network of China (CMONOC) were consistently analyzed. Most of the nonlinear movements in the cumulative position time series produced by CMONOC data center disappeared; and more accurate vertical terms and tectonic signals were extracted. Displacements caused by atmospheric pressure loading, nontidal ocean loading, soil moisture mass loading, and snow cover mass loading using the National Centers for Environmental Prediction (NCEP) Reanalysis I/II models and Estimation of the Circulation and Climate of the Ocean (ECCO) data can explain most of the vertical annual terms at many stations, while only parts can be explained at Lhasa and southern coastal sites, indicating that there are some deformation mechanisms that are still unknown or not modeled accurately. The remarkable differences in vertical position time series for short-baseline sites reveal that GPS stations can be greatly affected by local factors; and attention should be paid when explaining observed GPS velocity vectors.