A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.     

In Situ Determination of First‐Row Transition Metal,Ga and Ge Abundances in Geological Materials via Medium‐Resolution LA‐ICP‐MS

An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising ⁴³Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 10⁰ μg g^?1 and as high as > 10⁴ μg g^?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2s_m). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials.     

Les orthomicaschistes,produits de la déformation cisaillante ductile synmétamorphe de granites avec transfert de matière : principaux caractères et exemples dans la chaîne varisque du Sud de la France

Résumé

Dans le segment varisque français, les associations d’orthogneiss et de micaschistes sont généralement interprétées comme correspondant originellement soit à des couples socle granitique -couverture pélitique, soit à des granités intrusifs dans un encaissant pélitique, soit encore à des séries détritiques ou volcano-détritiques. Certaines d’entre elles résultent en fait de la déformation cisaillante ductile hétérogène synmétamorphe d’anciens granités, associée à d’importants transferts de matière.

Cette interprétation se fonde essentiellement sur la reconnaissance dans des zones de cisaillement ductile de passages progressifs entre orthogneiss et micaschistes. Cette évolution, qui correspond à une séquence blastomylonitique ou sub-blastomylonitique, est caractérisée par une recristallisation complète, ou quasi-complète, dès le stade orthogneiss, accompagnée par une modification chimique marquée par une perte en Si, Ca et Na et une concentration corrélative en Al, Fe, Mg et Ti. Une telle évolution aboutit à des orthomicaschistes, roches entièrement recristallisées et à foliation bien définie, distincts des phyllonites et analogues aux « micaschistes rétrogrades ». Les associations métagranites - orthogneiss - orthomicaschistes reconnues occupent des surfaces allant de 50 à 500 km2 et l’épaisseur des nombreux niveaux d’orthomicaschistes va de quelques centimètres a plusieurs hectomètres.

En conséquence, dans les régions affectées par une intense déformation cisaillante ductile synmétamorphe, les transformations de granités peuvent être plus variées, plus importantes et plus généralisées qu’on ne l’admettait jusqu’ici.     

Mise en évidence d'un nouveau front de chevauchement dans l'Atlas tunisien oriental de Tunisie par sismique réflexion. Contexte structural régional et rôle du Trias salifère

Structural interpretations of newly acquired seismic lines in northeastern Tunisia allow us to highlight a new thrust front for the Atlasic range of Tunisia, in contrast to the previously Zaghouan fault thrust Dorsale zone. This new thrust front takes place on weakness tectonic zones, materialized by inherited faults anchored on the pre-Triassic basement. This front seems to be a paleogeographic trend controlling structural style and basin fill with a synsedimentary activity. The front is expressed by reverse faults, thrust faults, back thrusting, and decollement structures. To cite this article: S. Khomsi et al., C. R. Geoscience 336 (2004).     

Late Quaternary activity of the Pajarito fault, Rio Grande rift of northern New Mexico, USA

The Pajarito fault forms the western margin of the Rio Grande rift in north-central New Mexico, and lies adjacent to Los Alamos National Laboratory, a major Federal research facility. Vertical displacement on this normal fault over the past 1.2 Ma has created a 50- to 120-m-high fault scarp on Bandelier Tuff (1.2 Ma), yielding a long-term average slip rate of ca. 0.1 mm/yr. In support of a Laboratory-wide seismic hazards assessment, we excavated 14 trenches in the Pajarito fault zone to determine the age of the most recent displacement event, the recurrence interval between events, the displacement per event, and the variability in slip rate and recurrence through time. The large number of trenches was required by the large height of the fault scarp and the complexity of the fault zone. Only about half the trenches contained significant thicknesses of Holocene deposits, but in those trenches there was clear evidence for an early-to-mid-Holocene displacement event. The previous event was at least 20–40 ka, and the average recurrence interval over the past ca. 300 ka was about 20–40 kyr. We infer that much of the structural relief across this fault developed soon after eruption of the Bandelier Tuff between 1.0 and 1.2 Ma, and that slip rate slowed considerably after that time.     

Interpretation of gamma-ray logs: The distribution of uranium in carbonate platform

High gamma-radioactivity in carbonates is usually ascribed to uranium of detrital minerals and organic matter, and to thorium and potassium of clays. The present study based on Urgonian marls and marly limestones (France) shows that some of the most radioactive values correspond instead to some ‘pure’ limestones. These peaks are generally associated with a sequence boundary or a maximum flooding surface. Low-level γ-spectrometry and ICP–MS analyses show that although high radioactivities are mostly associated with uranium, there is no obvious correlation between uranium enrichment and lithology. Also, correlation between high radioactivity and argillaceous beds might not be systematic. To cite this article: M.C. Raddadi et al., C. R. Geoscience 337 (2005).     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Mais comment s'écoule donc un glacier ? Aperçu historique

Ice and snow have often helped physicists understand the world. On the contrary it has taken them a very long time to understand the flow of the glaciers. Naturalists only began to take an interest in glaciers at the beginning of the 19th century during the last phase of glacier advances. When the glacier flow from the upslope direction became obvious, it was then necessary to understand how it flowed. It was only in 1840, the year of the Antarctica ice sheet discovery by Dumont d'Urville, that two books laid the basis for the future field of glaciology: one by Agassiz on the ice age and glaciers, the other one by canon Rendu on glacier theory. During the 19th century, ice flow theories, adopted by most of the leading scientists, were based on melting/refreezing processes. Even though the word ‘fluid’ was first used in 1773 to describe ice, more the 130 years would have to go by before the laws of fluid mechanics were applied to ice. Even now, the parameter of Glen's law, which is used by glaciologists to model ice deformation, can take a very wide range of values, so that no unique ice flow law has yet been defined. To cite this article: F. Rémy, L. Testut, C. R. Geoscience 338 (2006).     

Sur les anomalies structurales de l'anticlinal de l'oued Bahloul de Tunisie : héritage tectonique et plissement cisaillant de couverture

The Oued Bahloul structure exists in the central Atlas of Tunisia. This structure is oriented N70 and it shows a very particular geometry characterized by: (i) an important disharmony between the northern and the southern flanks; (ii) a dissymmetry between the east and the west parts of the structure; (iii) several gaps and progressive unconformities present in the Cretaceous and Eocene series.Three major tectonic directions characterize this structure: (i) the N120 appears in the western part of the anticline; (ii) some north–south faults distinguish the oriental part; (iii) the strike fault, which is confirmed by seismic data, affects the central part of this anticline. To cite this article: A. Saadi et al., C. R. Geoscience 338 (2006).