氯化镁及其水合物的标准溶解焓与生成焓

利用精密量热仪测定了MgCl_2、MgCl_2·2H_2O、MgCl_2·4H_2O和MgCl_2·6H_2O在298.15°K溶于水的积分溶解热,并利用Pitzer电解质溶液的。~ΦL方程,计算了溶质的相对表观摩尔热焓,从而得到标准溶解焓分别为(KJ·mol~(-1))—155.86±0.17、—79.45±O.17,—41.78±O.18和—14.58±0.16;晶格能分别为—2490.36,—3158.37,—3772.70和—4376.56。二、四、六水合物的标准生成焓分别为—1289.39,—1898.72和—2497.58;水合焓分别为—76.41,—114.08和—141.28。     

北京塔院井水位短临预报指标的研究

对塔院井３年水位、气压、固体的逐时值进行一系列数据处理，并用三角多项式拟合以消除年周期影响，把水位日气压系数和水位残差日均方差的余差作为塔院井短临预报指标，改进了水位前兆异常的提取方法。同时用熵的概念对这两个参数做出较客观的评价，计算出它们的前兆效益水平分别达到０．６５和０．５９，说明其较好的反映了地震的前兆信息     

Thermodynamic properties,low-temperature heat-capacity anomalies,and single-crystal X-ray refinement of hydronium jarosite, (H<Subscript>3</Subscript>O)Fe<Subscript>3</Subscript>(SO<Subscript>4</Subscript>)<Subscript>2</Subscript>(OH)<Subscript>6</Subscript>

Crystals of hydronium jarosite were synthesized by hydrothermal treatment of Fe(III)–SO₄ solutions. Single-crystal XRD refinement with R₁=0.0232 for the unique observed reflections (|F_o| > 4_F) and wR₂=0.0451 for all data gave a=7.3559(8) Å, c=17.019(3) Å, V^o=160.11(4) cm³, and fractional positions for all atoms except the H in the H₃O groups. The chemical composition of this sample is described by the formula (H₃O)_0.91Fe_2.91(SO₄)₂[(OH)_5.64(H₂O)_0.18]. The enthalpy of formation (H^o_f) is –3694.5 ± 4.6 kJ mol^–1, calculated from acid (5.0 N HCl) solution calorimetry data for hydronium jarosite, -FeOOH, MgO, H₂O, and -MgSO₄. The entropy at standard temperature and pressure (S^o) is 438.9±0.7 J mol^–1 K^–1, calculated from adiabatic and semi-adiabatic calorimetry data. The heat capacity (C_p) data between 273 and 400 K were fitted to a Maier-Kelley polynomial C_p(T in K)=280.6 + 0.6149T–3199700T^–2. The Gibbs free energy of formation is –3162.2 ± 4.6 kJ mol^–1. Speciation and activity calculations for Fe(III)–SO₄ solutions show that these new thermodynamic data reproduce the results of solubility experiments with hydronium jarosite. A spin-glass freezing transition was manifested as a broad anomaly in the C_p data, and as a broad maximum in the zero-field-cooled magnetic susceptibility data at 16.5 K. Another anomaly in C_p, below 0.7 K, has been tentatively attributed to spin cluster tunneling. A set of thermodynamic values for an ideal composition end member (H₃O)Fe₃(SO₄)₂(OH)₆ was estimated: G^o_f= –3226.4 ± 4.6 kJ mol^–1, H^o_f=–3770.2 ± 4.6 kJ mol^–1, S^o=448.2 ± 0.7 J mol^–1 K^–1, C_p (T in K)=287.2 + 0.6281T–3286000T^–2 (between 273 and 400 K).     

Incoherent internal tidal currents in the deep ocean

Eleven months current meter observations from the deep Bay of Biscay were examined for the residual (incoherent internal tidal; icIT) signal, left after harmonic analysis using eight tidal constituents (large-scale barotropic or coherent baroclinic signal) within the semidiurnal band. This residual signal comprised 30% of the total tidal kinetic energy and, due to its flat spectral appearance, it was responsible for typically 5–7 days intermittency. Although icIT was part of the red noise internal wave band continuum, it was not attributable to instrumental noise. It consisted of quasi-harmonics at non-tidal harmonic frequencies having amplitudes larger than N₂, the third largest semidiurnal tidal constituent. It is suggested that the kinetic energy at these non-tidal frequencies reflects interaction between semidiurnal tidal motions and the slowly varying background conditions.Responsible Editor: Roger Proctor     

A model study on seasonal spatial-temporal variability of the Lagrangian Residual Circulations in the Bohai Sea

The spatial distribution and seasonal variation of the tide-induced Lagrangian Residual Circulations (LRC hereafter), wind-driven LRC, and the coupling dynamic characteristics were simulated using ECOM, given the Hellerman and Rosenstein global monthly-mean wind stresses. The results showed that the tide-induced LRC of the harmonic constituent m2 bears an identical pattern in four seasons in the Bohai Sea: the surface one is weak with random directions; however, there exist a southeast current from the Bohai Strait to the Laizhou bay, and a weakly anticlockwise gyre in the south of the Bohai Strait for the bottom layer LRC. The magnitude of bottom layer tide-induced LRC is larger than the surface one, and moreover, it contributes significantly to the whole LRC in the Bohai Sea. Unlike the identical structure of the tide-induced LRC, the wind driven LRC varies seasonally under the prevailing monsoon. It forms a distinct gyre under the summer and winter monsoons in July and January respectively, but it seems weak and non-directional in April and September.     

Maintenance of headland-associated linear sandbanks: modelling the secondary flows and sediment transport

Linear sandbanks are located globally in areas where there are strong currents and an abundance of sand. In the recent years, these sandbanks have become of strategic interest as a potential source of marine aggregates (sand and gravel) and mineral deposits. They form the seaward boundary of the nearshore zone and therefore are important for the stability of the coastal system. They also commonly reach the sea surface and thus pose a threat to navigation. Headland-associated linear sandbanks are a specific type of sandbanks which are located in the lee of coastal topographic features such as headlands and islands. Interaction between tidal currents and topographic features generate complex three-dimensional circulation patterns that significantly influence the distribution of sediments in the vicinity of the feature. Field and numerical model investigations of the three-dimensional flow structure have been undertaken on the Levillain Shoal, a headland-associated linear sandbank present in the lee of Cape Levillain (Shark Bay, Western Australia). The field data indicated the presence of secondary flows near the tip of the cape and around the bank which were re-produced in the numerical simulations. Numerical results have shown that residual eddies are not representative of the sediment transport and that secondary currents enhance the convergence of sediment towards the sandbank. Maintenance processes have been investigated. Sediment transport paths near the cape and the bank indicate that the sandbank is part of a sand circulation cell where the sand is circulating around the bank with exchanges between the sandbank and the headland.     

非均质复杂断块油藏高含水期开发调整方法研究--以板北注水开发区为例

以解决非均质油藏高含水期开发过程中存在的问题为目的，以非均质油藏——板北注水开发区为例，在总结该类油藏剩余油分布规律及其潜力类型基础上，针对油藏各类潜力的分布特点及其受控因素提出了切实可行的调整挖潜方法，数值模拟及实际实施结果表明，这些方法的实施可明显改善油藏开发效果，提高非均质油藏最终采收率。     

Assessment of liquefaction and lateral spreading on the shore of Lake Sapanca during the Kocaeli (Turkey) earthquake

The 1999 Kocaeli earthquake of Turkey (M_w = 7.4) caused great destruction to buildings, bridges and other facilities, and a death tall of about 20,000. During this earthquake, severe damages due to soil liquefaction and associated ground deformations also occurred widespread in the eastern Marmara Region of Turkey. Soil liquefaction was commonly observed along the shorelines. One of these typical sites is Sapanca town founded on the shore of Lake Sapanca. This study was undertaken as quantitative measurement of ground deformations induced by liquefaction along the southern shore of Lake Sapanca. The permanent lateral ground deformation was measured through the aerial photogrammetry technique at several locations both along the shoreline and in the town. In situ soil profiles and material properties at Sapanca area were obtained based on the data from 55 borings and standard penetration tests (SPT), and laboratory tests, respectively. The data and the empirical methods recommended by an NCEER workshop were employed to evaluate the liquefaction resistance of the soils. In addition, simple shaking tests on a limited number of samples were also performed. The permanent ground displacements were estimated from the existing empirical models, sliding block method and residual visco-elastic finite element methods. Then these estimations were compared with the observed ground displacements. The assessments suggested that liquefaction at Sapanca have occurred within Quaternary alluvial fan deposits at depths 1 and 14 m, and the major regions of liquefaction and associated ground deformations were located along the shore and creeks. The evaluations also indicated that for sites with no sand boils but with ground displacement greater than 1 m, thickness of the non-liquefiable layer was large. It is also noted that no liquefaction-induced ground surface disruption is expected at the site when the thickness of the liquefiable and non-liquefiable layers vary between 0.5 and 1.5 m, and 3.5 and 5.5 m, respectively. Except one model, all the empirical models employed in the study over-predicted the observed lateral ground displacements, while sliding block method and residual visco-elastic finite element methods yielded reasonably good results if the known properties of liquefied soils are used.     

Dissolution Enthalpies of Magnesian Calcites

A series of synthetic and biogenicmagnesian calcites was dissolved in weak acetic acidsolutions to measure the enthalpies of dissolution at25°C. For the synthetic phases, heat releasedwas 33.5 kJ/mol for calcite, decreasing to 33 kJ/molfor a phase of 2 mol % MgCO3, and increasing to35 kJ/mol for a phase of 15 mol %. Values of excessenthalpies, ΔHxs, calculated using calciteand magnesite end-members, average about -1 kJ/mol forthe synthetic phases. Total entropies of solidsolution formation, ΔSSS, also werecalculated using available data on Gibbs free energiesof formation and these excess enthalpies. Values ofΔSSS range from -2 J/(mol-K) at 2 mol % to-5 J/(mol-K) at 15 mol % MgCO3. These negativevalues of ΔHxs and ΔSSSsuggest that some form of ordering (cation?) isobtained in the synthetic phases, and that vibrationalentropies of the solid solution are diminished incomparison to the end-members. In contrast, biogenic samples generally have positivevalues of ΔHxs, increasing from +1 kJ/molat 5 mol % to +3 kJ/mol at 20 mol % MgCO3. Mostvalues of ΔSSS are equal (within errors)to values expected from configurational enthalpyalone. Thus, in most biogenic materials cationordering probably is not obtained, and most phases aremore typical of equivalent-site solid solutions.     

试论残留型盆地研究思路和油气勘探方法

残留型地具有抬升剥蚀剧烈,原形盆地难以恢复,经历多期构造运动的改造和建造油气成藏动力学过程复杂,热演化程度较高,油气保存条件复杂等特点,但是残留型盆地油气资源丰富,勘探前景广阔,依据残留型盆地的特征和油气资源潜力,提出应全面,发展地认识盆地,静动结合地研究盆地,运用先进而实用的新技术新方法评价盆地,按照勘探程序勘探盆地,在研究工作上应以分地及其邻区作为整体研究对象,以区域地质研究一石油地质研究－综