贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

胶州湾营养盐的现状和变化

报道了１９９１年５月至１９９４年２月１２个航次胶州湾ＮＯ３－Ｎ，ＮＯ２－Ｎ，ＮＨ４－Ｎ，ＰＯ４－Ｐ和ＳｉＯ３－Ｓｉ的时空分布基本特征，６０年代于至９０年代的变化表明，胶州湾营养盐的浓度和分布已发生显变化。尤其从６０年代至８０年代，３０年来，胶州湾中东部水城ＰＯ４－Ｐ，ＮＯ３－Ｎ和ＮＨ４－Ｎ浓度分别增加２．２，７．３和７．１倍，ＴＯＮ浓度也增加了３．５倍，ＴＩＮ／ＰＯ４－Ｐ从１０增加至２４．２；Ｔ     

新疆福海第一农场水库浮游植物生态初步研究

于2008年7月(平水期)、10月(枯水期)和次年5月(丰水期)对新疆阿勒泰地区福海县第一农场水库浮游植物进行了生态学调查.共采集到浮游植物8门75种(属),其中绿藻28种、硅藻21种、蓝藻13种、裸藻6种、黄藻2种、甲藻2种、隐藻2种和金藻1种,绿藻和硅藻在种类组成上占明显优势.各期优势种不尽相同:平水期优势种为类颤...     

金衢盆地第四纪红土沉积粒度组成特征

浙江金衢盆地第四纪红土分布广泛,是开展红土与全球变化研究的理想场所之一。汤溪红土沉积剖面的粒度组成研究表明:砂(>63μm)含量极少,平均1.58%,粉砂(4~63μm)和黏粒(<4μm)为众数粒组,其含量的平均值分别为48.51%和49.91%,频率曲线呈双峰式,推测红土母质具风成特性,沉积后经历了较强的风化成壤作用;均质红土与网纹红土具有相似的粒度分布特征,但网纹红土的分选更为复杂,底部有近源物质的混入;汤溪红土粒度的纵向变化旋回和纵向变化趋势,可能指示了中更新世以来南方气候的不稳定性和气候逐渐变干冷的趋势。     

渤海的平均余环流

利用72个渤海石油平台、站点测流资料,阐明了渤海的平均余环流特征,并用已有的数值计算结果阐明了其形成机制。观测表明在黄河三角洲近海存在一支北-东北向的流动,可抵达秦皇岛附近水域,数值计算表明该支流动主要是潮生的;在辽东湾北部存在一顺时针向的涡旋运动,在冬半年该涡旋是风生的;在渤海湾北部存在潮生的逆时针向的余环流。     

点模式条件下的犯罪嫌疑人时空同现模式挖掘与分析

现有时空同现模式挖掘方法因其在空间和时间频繁阈值等参数值的设定上存在困难且缺乏客观依据的问题而难以被应用到犯罪地理研究中。为此,本文通过引入时空状态同现模式和最小时空参与率等概念对现有挖掘方法进行了重新建模,并结合广义Grubbs异常值检验提出了一种点模式分布下的犯罪嫌疑人时空同现模式挖掘框架。基于该框架对中国某省部分犯罪嫌疑人的真实移动轨迹数据的实验分析结果表明,本文所提出的方法能够有效地挖掘出嫌疑人间显著的时空同现模式,且这些模式的时空分布特征不仅与犯罪活动易发生在非农业生产区这一共识基本相符,还与日常活动理论的基本观点相适应。本文拓展了时空同现模式挖掘在犯罪地理研究中的应用,研究成果对公安机关等执法部门在重点监控某些犯罪嫌疑人以及合理分配和部署警力资源方面具有重要意义。     

Reprint of: Diagenetic controls on evolution of porosity and permeability in lower Tertiary Wilcox sandstones from shallow to ultradeep (200–6700 m) burial,Gulf of Mexico Basin,U.S.A.

Reservoir quality is a critical risk factor in deep to ultradeep reservoirs at depths >4.5 km. Analysis of Paleogene Wilcox sandstones on the upper Texas Gulf Coast provides insight into the evolution of reservoir quality during shallow to ultradeep burial diagenesis. Reduction of porosity and permeability with burial in Wilcox sandstones was evaluated using subsurface samples from 200 to 6700 m, at temperatures of 25–230 °C. Diagenesis and petrophysical properties were interpreted from petrographic data and core analyses. Wilcox sandstones are mostly lithic arkoses and feldspathic litharenites having an average composition of Q₅₉F₂₂R₁₉. Provenance did not change significantly during Wilcox deposition in this area, nor does average sandstone composition vary among lower, middle, and upper Wilcox sandstones. However, composition does vary with sequence-stratigraphic position; lowstand slope-fan deposits contain more rock fragments than do deposits from highstand or transgressive systems tracts. Given observations from this onshore dataset, Wilcox sandstones deposited in deepwater environments in the Gulf of Mexico are likely to contain more rock fragments than their linked highstand equivalents.     

pT-effects of Pleistocene glacial periods on permafrost,gas hydrate stability zones and reservoir of the Mittelplate oil field,northern Germany

During the past two million years low surface temperatures as well as episodically advancing ice sheets from Scandinavia acted on the subsurface pT-regime of northern Germany. Their likely effects on the petroleum system of Schleswig-Holstein were investigated. For the entire Quaternary mean annual ground temperature (MAGT) was reconstructed at a resolution of 1000 years by calibrating oxygen isotope records from ODP-site 659 to the climate of northern Germany of the past 120 kyr. The resulting MAGT trend served as input to an ice sheet model and a permafrost model along a 2D section crossing the petroleum bearing south-western part of Schleswig-Holstein. Here advances and retreats of the Scandinavian ice sheet during Saalian and Elsterian glaciation Stages were reconstructed. Maximum ice thicknesses of up to 1700 m and up to 20 periods of regional permafrost in northern Germany were reconstructed for the past 1.25 million years. Based on a basal heat flow of 50 mW/m² permafrost thicknesses exceeded 100 m during most of these periods, temporarily extending down to depths of more than 300 m. Favourable surface temperatures and long durations of cold periods provided favourable conditions for onshore gas hydrate stability zones at Mittelplate. Implementing these glacial dynamics into 2D basin modelling (PetroMod, IES, Aachen, Germany) of the Mittelplate oil field reveals five phases of gas hydrate stability at depths down to 750 m. The latest of these events occurred during the Weichselian about 20 kyr ago. The effect of the ice sheets on pore pressure in the subsurface strongly depends on the hydraulic boundary conditions at the ice base (e.g. frozen vs. temperate ice sheet base). Excess pore pressure in the reservoir of more than 10 MPa during ice overriding is possible and probable. The calculated temperature effect of the Pleistocene cooling on the Mittelplate reservoir is in the range of 3–7 °C. Even today temperature in the reservoir is still lowered by about 4 °C in comparison to pre-Pleistocene times. Despite the fact that a significant influence of glacial effects on petroleum generation can be ruled out at Mittelplate, we state that pT-effects in reservoirs related to glacial processes in formerly glaciated areas have been underestimated in the past.     

Reservoir potential of Late Cretaceous terrestrial to shallow marine sandstones,Taranaki Basin,New Zealand

Late Cretaceous coals and coaly source rocks are the main source of hydrocarbons in the Taranaki Basin, yet to date there have not been any hydrocarbon discoveries within Cretaceous strata, and sandstone distribution and reservoir quality for this interval have been poorly understood. The Late Cretaceous sediments were deposited in several sub-basins across Taranaki, with their distribution largely determined by sediment supply, subsidence, and sea level change. In this study, we describe potential reservoir facies in well penetrations of Cretaceous strata in Taranaki, as well as from outcrop in northwest Nelson, on the southern edge of the basin.     

长江口及邻近海域表层沉积物中重金属元素含量分布及其影响因素

根据2003和2006年长江口及邻近海域表层沉积物样品的粒度组成和元素铬、铜、镍、铅、锌、铝、钙和锶的含量,分析了重金属元素含量的分布特征,探讨了含量的变化趋势及其对人类活动的响应。自2003年三峡工程一期蓄水完成到2006年6月,长江输沙量逐年减少,长江口海域沉积物中黏土的百分含量明显增加,但是沉积物分布的总体格局并没有发生明显的变化。重金属元素大多在泥质区沉积物中富集,高值区沿岸线呈带状分布,在最大浑浊带和口外羽状锋处达到峰值。在长江大量物质输入的背景下,研究区沉积物中重金属元素含量相对其他类似河口较低。河流的陆源颗粒输入、水动力条件、细颗粒物质的吸附以及絮凝作用是控制沉积物中重金属元素含量分布的主要因素,氧化还原条件也对重金属元素含量变化有一定的影响。人类活动(重大工程的建设和人为污染)对长江口外泥质区中重金属元素含量有重要影响,尤其对铅和锌的含量及其分布的影响显著。自2003年三峡工程一期蓄水以来,长江口海域表层沉积物中重金属元素沉积机制未有明显的变化,但是重金属元素含量有逐渐降低的趋势。