Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.     

A new approach to estimate canopy evaporation and canopy interception capacity from evapotranspiration and sap flow measurements during and following wetting

Canopy interception and its evaporation into the atmosphere during irrigation or a rainfall event are important in irrigation scheduling, but are challenging to estimate using conventional methods. This study introduces a new approach to estimate the canopy interception from measurements of actual total evapotranspiration (ET) using eddy covariance and estimation of the transpiration from measurements of sap flow. The measurements were conducted over a small‐scale sprinkler‐irrigated cotton field before, during and after sprinkler irrigation. Evaporation and sap flow dynamics during irrigation show that the total ET during irrigation increased significantly because of the evaporation of free intercepted water while transpiration was suppressed almost completely. The difference between actual ET and transpiration (sap flow) during and immediately following irrigation (post irrigation) represents the total canopy evaporation while the canopy interception capacity was calculated as the difference between actual ET and transpiration (sap flow) during drying (post irrigation) following cessation of the irrigation. The canopy evaporation of cotton canopy was calculated as 0.8 mm, and the interception capacity was estimated to be 0.31 mm of water. The measurement uncertainty in both the non‐dimensional ET and non‐dimensional sap flow was shown to be very low. Copyright © 2015 John Wiley & Sons, Ltd.     

Analysis of shaft resistance of jacked piles in sands

In recent years, pile jacking has become a viable alternative installation method for displacement piles. Pile jacking produces minimal noise, vibration and air pollution during installation. In addition, it is possible, at the end of jacking, to have a good estimate of the ultimate static capacity of the pile. In this paper, the shaft resistance of piles jacked into sand is studied using one‐dimensional finite element analysis. The finite element simulations, using a two‐surface plasticity model, demonstrate the effects of relative density and confinement on the unit shaft resistance of piles jacked in sand. The impact of the number of jacking strokes on the unit shaft capacity is also assessed. Based on the numerical results, we developed equations for shaft resistance quantifying the effects of relative density, initial confinement and number of jacking strokes. Predictions using these equations are compared with data obtained from centrifuge tests and field tests. Copyright © 2010 John Wiley & Sons, Ltd.     

附有物理量和气象条件约束的光学卫星国土观测有效覆盖率评估

传统光学卫星国土观测覆盖评估建立在卫星对地理想覆盖的基础上,并未考虑卫星存储、星地数据传输、观测时长等物理量及观测区域气象因素对于覆盖性能的影响。本文针对光学遥感卫星的国土观测需求.建立国土观测有效覆盖能力评估指标体系,根据卫星数据存储能力、星地数据传输能力、卫星单圈最大观测时长、卫星观测太阳高度角等性能参数,提出了基于物理性能约束下的有效覆盖计算方法。根据气象台站历年气象数据,提出了气象约束因子的计算方法。综合考虑卫星物理性能约束与观测区域气象约束,计算光学遥感卫星对地观测有效覆盖能力。最后根据专家设计的光学遥感卫星国土观测有效覆盖能力评估指标权重,利用层次分析法(AHP)评估光学遥感卫星系统对于国土观测的需求满足程度。试验结果表明,本文方法对于国土观测有效覆盖的估算和评价结果更加精确,更接近于国土观测的实际应用需求,为对地观测有效覆盖能力评估提供了一种更为精确的可行方案。     

Development and Utilization of the World’s and China’s Bulk Mineral Resources and their Supply and Demand Situation in the Next Twenty Years

Bulk mineral resources of iron ores, copper ores, bauxite, lead ores, zinc ores and potassium salt play a pivotal role on the world’s and China’s economic development. This study analyzed and predicted their resources base and potential, development and utilization and their world’s and China’s supply and demand situation in the future 20 years. The supply and demand of these six bulk mineral products are generally balanced, with a slight surplus, which will guarantee the stability of the international mineral commodity market supply. The six mineral resources(especially iron ores and copper ores) are abundant and have a great potential, and their development and utilization scale will gradually increase. Till the end of 2014, the reserveproduction ratio of iron, copper, bauxite, lead, zinc ores and potassium salt was 95 years, 42 years, 100 years, 17 years, 37 years and 170 years, respectively. Except lead ores, the other five types all have reserve-production ratio exceeding 20 years, indicative of a high resources guarantee degree. If the utilization of recycled metals is counted in, the supply of the world’s six mineral products will exceed the demand in the future twenty years. In 2015–2035, the supply of iron ores, refined copper, primary aluminum, refined lead, zinc and potassium salt will exceed their demand by 0.4–0.7 billion tons(Gt), 5.0–6.0 million tons(Mt), 1.1–8.9 Mt, 1.0–2.0 Mt, 1.2–2.0 Mt and 4.8–5.6 Mt, respectively. It is predicted that there is no problem with the supply side of bulk mineral products such as iron ores, but local or structural shortage may occur because of geopolitics, monopoly control, resources nationalism and trade friction. Affected by China’s compressed industrialized development model, the demand of iron ores(crude steel), potassium salt, refined lead, refined copper, bauxite(primary aluminum) and zinc will gradually reach their peak in advance. The demand peak of iron ores(crude steel) will reach around 2015, 2016 for potassium salt, 2020 for refined lead, 2021 for bauxite(primary aluminum), 2022 for refined copper and 2023 for zinc. China’s demand for iron ores(crude steel), bauxite(primary aluminum) and zinc in the future 20 years will decline among the world’s demand, while that for refined copper, refined lead and potassium salt will slightly increase. The demand for bulk mineral products still remains high. In 2015–2035, China’s accumulative demand for iron ores(crude steel) will be 20.313 Gt(13.429 Gt), 0.304 Gt for refined copper, 2.466 Gt(0.616 Gt) of bauxite(primary aluminum), 0.102 Gt of refined lead, 0.138 Gt of zinc and 0.157 Gt of potassium salt, and they account for the world’s YOY(YOY) accumulative demand of 35.17%, 51.09%, 48.47%, 46.62%, 43.95% and 21.84%, respectively. This proportion is 49.40%, 102.52%, 87.44%, 105.65%, 93.62% and 106.49% of that in 2014, respectively. From the supply side of China’s bulk mineral resources, it is forecasted that the accumulative supply of primary(mine) mineral products in 2015–2035 is 4.046 Gt of iron ores, 0.591 Gt of copper,1.129 Gt of bauxite, 63.661 Mt of(mine) lead, 0.109 Gt of(mine) zinc and 0.128 Gt of potassium salt, which accounts for 8.82%, 13.92%, 26.67%, 47.09%, 33.04% and 15.56% of the world’s predicted YOY production, respectively. With the rapid increase in the smelting capacity of iron and steel and alumina, the rate of capacity utilization for crude steel, refined copper, alumina, primary aluminum and refined lead in 2014 was 72.13%, 83.63%, 74.45%, 70.76% and 72.22%, respectively. During 2000–2014, the rate of capacity utilization for China’s crude steel and refined copper showed a generally fluctuating decrease, which leads to an insufficient supply of primary mineral products. It is forecasted that the supply insufficiency of iron ores in 2015–2035 is 17.44 Gt, 0.245 Gt of copper in copper concentrates, 1.337 Gt of bauxite, 38.44 Mt of lead in lead concentrates and 29.19 Mt of zinc in zinc concentrates. China has gradually raised the utilization of recycled metals, which has mitigated the insufficient supply of primary metal products to some extent. It is forecasted that in 2015–2035 the accumulative utilization amount of steel scrap(iron ores) is 3.27 Gt(5.08 Gt), 70.312 Mt of recycled copper, 0.2 Gt of recycled aluminum, 48 Mt of recycled lead and 7.7 Mt of recycled zinc. The analysis on the supply and demand situation of China’s bulk mineral resources in 2015–2035 suggests that the supply-demand contradiction for these six types of mineral products will decrease, indicative of a generally declining external dependency. If the use of recycled metal amount is counted in, the external dependency of China’s iron, copper, bauxite, lead, zinc and potassium salt will be 79%, 65%, 26%, 8%, 16% and 18% in 2014, respectively. It is predicted that this external dependency will decrease to 62%, 64%, 20%,-0.93%, 16% and 14% in 2020, respectively, showing an overall decreasing trend. We propose the following suggestions correspondingly.(1) The demand peak of China’s crude steel and potassium salt will reach during 2015–2023 in succession. Mining transformation should be planned and deployed in advance to deal with the arrival of this demand peak.(2) The supply-demand contradiction of China’s bulk mineral resources will mitigate in the future 20 years, and the external dependency will decrease accordingly. It is suggested to adjust the mineral resources management policies according to different minerals and regions, and regulate the exploration and development activities.(3) China should further establish and improve the forced mechanism of resolving the smelting overcapacity of steel, refined copper, primary aluminum, lead and zinc to really achieve the goal of "reducing excess production capacity".(4) In accordance with the national strategic deployment of "One Belt One Road", China should encourage the excess capacity of steel, copper, alumina and primary aluminum enterprises to transfer to those countries or areas with abundant resources, high energy matching degree and relatively excellent infrastructure. Based on the national conditions, mining condition and geopolitics of the resources countries, we will gradually build steel, copper, aluminum and lead-zinc smelting bases, and potash processing and production bases, which will promote the excess capacity to transfer to the overseas orderly.(5) It is proposed to strengthen the planning and management of renewable resources recycling and to construct industrial base of renewable metal recycling.(6) China should promote the comprehensive development and utilization of paragenetic and associated mineral species to further improve the comprehensive utilization of bulk mineral resources.     

北京某山坡湿陷性土层地基处理可行性分析与建议

北京市密云区某拟建别墅工程,属于山体边坡地基基础工程,任务要求对湿陷性地基土层进行湿陷性消除,并将其地基土承载力特征值提高到fak≥130 kPa。此外,还需要考虑边坡稳定性及其永久性加固问题。对该项目进行了深入分析、研究,并采用概念设计方法,对其进行设计预演,发现该项目存在工序复杂、不易实施、在永久性使用方面存在一定隐患、并具有责任不当等问题。对该地基基础工程进行了重新分析,建议取消地基处理措施,改用嵌岩桩作为拟建物的基础。     

Compression limit state of HVAC submarine cables

An industry accepted standard does not currently exist for determination of compression limits in a subsea cable. This has resulted in most manufacturers specifying that subsea cables are not permitted to be axially loaded in compression.Additionally industry guidance does not exist regarding the consequences of inducing compression forces within subsea cables and the resulting effect on cable integrity. Industry recommended practice and guidance also does not have any information regarding experimental test arrangements to determine allowable compression levels within a subsea cable. This lack of modelling/testing guidance along with manufacturer recommendations of zero compressive loads within subsea cables results in overly conservative and restrictive design parameters for subsea cable installation and use.Due to the complex interaction within a subsea cable structure, such as contact interaction and friction between cable strands, theoretical modelling has been unable to provide reliable stress predictions and therefore an experimental testing regime is required if compression limits within the cable are to be appropriately determined. This paper describes combined axial and bending test arrangements that can be used as a guideline for determination of allowable compression limits for subsea cables.     

围填海对海洋水动力与生态环境的影响

近10年来,中国海岸带围填海活动呈现出规模大、速度快的发展态势。围填海能带来显著的经济效益,但对海洋环境与生态的负面影响也不可忽视。针对围填海对海洋环境和生态的影响及作用机制,分别从水动力和生态系统两个方面进行了概述。围填海改变了海洋的自然几何属性(原始岸线、地形地貌、海湾面积),引起水动力环境的变化(潮汐系统和海湾水交换能力),进而影响了海湾的环境容量;围填海破坏了生物栖息地、导致生物多样性的丧失,影响到生态系统结构与功能的稳定性;水动力与生物多样性的变化可显著影响到生物地球化学过程,加速富营养化进程,恶化水质,增加生态灾害风险。目前,围填海后的生态修复策略主要有增加生物量、建设自然保护区、退陆还海3种方式;而生态补偿策略则多基于“生态系统服务功能与生境面积的大小为线性关系”,通过对其经济价值的量化后进行生态补偿与实施相关政策。国际上,生态系统服务功能的量化参数逐步纳入实际管理,并在线性关系研究的基础上,逐步纳入一些非线性的理念,使生态补偿机制更为合理化;而我国对于围填海生态效应的定量化研究及科学理论在管理政策中的实际应用仍亟待提高。整体而言,全面、准确地评估围填海对海洋环境与生态的影响离不开自然科学与社会科学的交叉与融合。     

Geological control factors of micro oil distribution in tight reservoirs

Understanding the oil distribution characteristics in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil distribution characteristics are mostly concerned with the basin scale. Based on Lucaogou core samples, geochemical approaches including Soxhlet extraction, total organic carbon (TOC), and Rock-Eval are combined with reservoir physical approaches including mercury injection capillary pressure (MICP) and porosity-permeability analysis, to quantitatively evaluate oil distribution of tight reservoirs on micro scale. The emphasis is to identify the key geological control factors of micro oil distribution in such tight reservoirs. Dolomicrites and non-detrital mudstones have excellent hydrocarbon generation capacity while detritus-containing dolomites, siltstones, and silty mudstones have higher porosity and oil content, and coarser pore throat radius. Oil content is mainly controlled by porosity, pore throat radius, and hydrocarbon generation capacity. Porosity is positively correlated with oil content in almost all samples including various lithologies, indicating that it is a primary constraint for providing storage space. Pore throat radius is also an important factor, as oil migration is inhibited by the capillary pressure which must be overcome. If the reservoir rock with suitable porosity has no hydrocarbon generation capacity, pore throat radius will be decisive. As tight reservoirs are generally characterized by widely distributed nanoscale pore throats and high capillary pressure, hydrocarbon generation capacity plays an important role in reservoir rocks with suitable porosity and fine pore throats. Because such reservoir rocks cannot be charged completely. The positive correlation between hydrocarbon generation capacity and oil content in three types of high porosity lithologies (detritus-containing dolomites, siltstones, and silty mudstones) supports this assertion.     

基于高效生态农业布局导向性的资源环境承载力评价—以黄河三角洲高效生态经济区为例

该文在对研究区资源环境本底基本了解的基础上,建立了包括耕地资源、水资源、社会经济资源、土壤环境、极端气候发生率和地质环境6个二级指标的资源环境承载力评价指标体系,采用定性和定量相结合的方法,利用层次分析法确定相关指标权重,分别对6个要素进行承载力评价。在各单元要素评价基础上,结合黄河三角洲高效生态经济区农业发展要求,划分出了沿海湿地生态系统保护带、北部盐渍化土质特色种植区、南部优质粮食生产区和果蔬集中种植区4个生态农业布局适宜区,并提出发展建议。