超声提取-气相色谱法测定覆盖区土壤中的六六六和滴滴涕

将超声波提取技术引入到覆盖区土壤样品六六六、滴滴涕组分的预处理中,建立了超声提取,磺化法净化,气相色谱测定的分析方法。对被测组分在超声波提取中的稳定性进行了试验,对超声提取时间、提取温度、提取溶剂用量以及磺化净化过程可能导致组分损失的各种相关条件逐个试验筛选,采用样品加标回收法对六六六、滴滴涕的8种组分进行了两种浓度的精密度和准确度试验,RSD值均小于10％,平均回收率92．5％-103．9％。方法对各种异构体的六六六、滴滴涕的最低检测浓度为0．30-3．89ng／g。     

山东省桓台地区土壤F的地球化学特征及其影响因素

为研究土壤氟的地球化学特征及其影响因素,选取山东省桓台地区为研究区,系统采集了70件表层土壤样品,并测试分析了其中F元素、有机碳含量、pH值等共计8项指标。绘制了元素地球化学图,掌握了该区F元素含量的空间分布特征。研究结果表明,表层土壤F含量范围为466.30~793.40 mg/kg,平均F含量为621.31 mg/kg,显著高于山东省背景值和全国背景值,具有潜在环境生态风险。研究区总面积70%的土壤F含量较高,其中F含量过剩的土壤相对集中分布在城镇附近;研究区东南部青银高速附近和北部呈零星分布的土壤中氟为适中及边缘含量水平。土壤中F含量主要受控于土壤pH、有机碳含量和施肥。该研究结果为改善研究区环境质量,防止地方性氟中毒提供了基础数据和科学依据。     

基于地质建造的西南山区成土母质分类方案——以大凉山区为例

为适应生态地质调查和评价工作对成土母质研究的要求,以四川大凉山区为例,提出基于地质建造的成土母质分类方案,即以地质构造演化和地质建造环境为依据,结合残坡积物的成因类型对成土母质进行分类。大凉山区的成土母质可划分为第四纪冲洪积物、新近纪—第四纪砂泥岩类残坡积物、侏罗纪—白垩纪泥质岩类残坡积物、三叠纪砂泥岩类残坡积物、中生代中酸性岩类残坡积物、二叠纪基性—超基性岩类残坡积物、震旦纪—三叠纪砂泥岩类残坡积物、震旦纪—三叠纪碳酸盐岩类残坡积物、元古宙中酸性岩类残坡积物、元古宙火山碎屑岩类残坡积物、元古宙基性—超基性岩类残坡积物、元古宙变质岩类残坡积物等12类。研究表明,大凉山区成土母质和土壤存在差异性,但同一成土母质上的不同土壤类型具有一定相似的地球化学特征,不同成土母质形成的同一种土壤类型存在较大的地球化学差异。因此,基于地质建造的成土母质分类方案既能有效反映不同构造背景和成岩环境下的成土母质差异,又能有效表征成土母质与其上土壤的内在联系。     

青藏公路多年冻土区冻土工程研究新进展

系统回顾了青藏高原多年冻土区公路工程冻土研究的过程和研究的内容 ,重点阐述了 90年代开展的冻土研究的研究成果 ,从冻土工程地质、路基下冻土温度场、冻土环境的影响、冻土工程分类、地理信息系统 5个侧面 ,来反映近年来在青藏公路研究中所取得的研究成果 ,这些成果为青藏铁路建设中重大冻土工程技术问题和工程设计提供了解决问题的科学依据     

Effects of Enclosure on Plant and Soil Nutrients in Different Types of Alpine Grassland

Enclosure is one of the most widely used management tools for degraded alpine grassland on the northern Tibetan Plateau, but the responses of different types of grassland to enclosure may vary, and research on these responses can provide a scientific basis for improving ecological conservation. This study took one site for each of three grassland types (alpine meadow, alpine steppe and alpine desert) on the northern Tibetan Plateau as examples, and explored the effects of enclosure on plant and soil nutrients by comparing differences in plant community biomass, leaf-soil nutrient content and their stoichiometry between samples from inside and outside the fence. The results showed that enclosure can significantly increase all aboveground biomass in these three grassland types, but it only increased the 10-20 cm underground biomass in the alpine desert. Enclosure also significantly increased the leaf nutrient content of the dominant plants and contents of total nitrogen (N), total potassium (K), and organic carbon (C) in 10-20 cm soil in alpine desert, thus changing the stoichiometry between C, N and P (phosphorus). However, enclosure significantly increased only the N content of dominant plant leaves in alpine steppe, while other nutrients and stoichiometries of both plant leaves and soil did not show significant differences in alpine meadow and alpine steppe. These results suggested that enclosure has differential effects on these three types of alpine grasslands on the northern Tibetan Plateau, and the alpine desert showed the most active ecological conservation in the responses of its soil and plant nutrients.     

Influence of heterogeneity on unsaturated hydraulic properties: (1) local heterogeneity and scale effect

Spatial heterogeneity is ubiquitous in nature, which may significantly affect the soil hydraulic property curves. The models of a closed‐form functional relationship of soil hydraulic property curves (e.g. VG model or exponential model) are valid at point or local scale based on a point‐scale hydrological process, but how do scale effects of heterogeneity have an influence on the parameters of these models when the models are used in a larger scale process? This paper uses a two‐dimensional variably saturated flow and solute transport finite element model (VSAFT2) to simulate variations of pressure and moisture content in the soil flume under a constant head boundary condition. By changing different numerical simulation block sizes, a quantitative evaluation of parameter variations in the VG model, resulting from the scale effects, is presented. Results show that the parameters of soil hydraulic properties are independent of scale in homogeneous media. Parameters of α and n in homogeneous media, which are estimated by using the unsaturated hydraulic conductivity curve (UHC) or the soil water retention curve (WRC), are identical. Variations of local heterogeneities strongly affect the soil hydraulic properties, and the scale affects the results of the parameter estimations when numerical experiments are conducted. Furthermore, the discrepancy of each curve becomes considerable when moisture content becomes closer to a dry situation. Parameters estimated by UHC are totally different from the ones estimated by WRC. Copyright © 2012 John Wiley & Sons, Ltd.     

Monitoring over‐winter soil water dynamics in a freezing and snow‐covered environment using a thermally insulated tensiometer

Water potential below a frozen soil layer was continuously monitored over an entire winter period (using thermally insulated tensiometers sheltered in a heated chamber) along with other soil, snow and atmospheric variables. In early winter, the freezing front advanced under a thin snow cover, inducing upward soil water flow in the underlying unfrozen soil. The freezing front started to retreat when the snow cover became thick enough to insulate the soil, resulting in the reversal of the flow direction in the unfrozen zone. These data provide a clear illustration of soil water dynamics, which have rarely been monitored with a tensiometer. Copyright © 2005 John Wiley & Sons, Ltd.     

一种裸露土壤湿度反演方法

针对目前土壤湿度反演方法研究较少且缺少实时性的现状,该文提出一种土壤湿度反演方法——最小二乘支持向量机技术。以积分方程模型为正向算法,数值模拟不同雷达参数(频率、入射角及极化)下后向散射系数随土壤含水量和地表粗糙度的变化情况。经过数据敏感性分析,选取C-波段和X-波段、小入射角下的同极化后向散射系数作为支持向量回归的训练样本信息;经过适当的训练,利用支持向量回归技术对土壤含水量进行了反演研究;并考虑通过多频率、多极化、多入射角数据的组合,消除地表粗糙度的影响,提高反演精度。模拟结果表明,该方法反演土壤湿度具有较高的精度和较好的实时性;同时,与人工神经网络方法的结果比较,证明了该方法的有效性,为土壤湿度的反演研究提供了一种方法。     

基于支持向量机的喀斯特山区土壤环境质量评价——以贵州北部一茶叶园区为例

以贵州北部一茶叶园区80个表层土壤样品为研究对象,对其Hg、As、Cd、Pb、Cr和Cu含量进行测定,在MATLAB中应用支持向量机构建土壤环境质量评价模型,并与模糊综合评价法和内梅罗综合污染指数法的评价结果对比分析,探究支持向量机模型在喀斯特山区土壤环境质量评价中的适用性,其结果表明:研究区土壤质量Ⅰ类与Ⅱ类样品比例为33∶7,土壤环境质量大多数为I类;支持向量机方法的评价结果与模糊综合评价法和内梅罗综合污染指数法结果的相同率分别达到82.5%和80.0%,并分析结果有差异的样品,发现支持向量机评价结果更符合实际情况,这说明该模型适用于土壤环境质量的评价。