Determination of total sulfur in geothermal water by inductively coupled plasma-atomic emission spectrometry

Sulfur speciation and concentration in geothermal water are of great significance for the research and utilization of the water resources. In most situations, it is necessary to determine the total sulfur in geothermal water. In this study, the method was established for the determination of determining total sulfur content — the inductively coupled plasma-atomic emission spectrometry (ICP-AES), with the wavelength of 182.034 nm selected in spectral line of sulfur. It was identified that the optimal working conditions of the ICP-AES instrument were 1 200 W for high frequency generator power 9 mm for vertical observation height, 0.30 MPa atomizer pressure, and 50 r/min analytical pump speed. The matrix interference of the method was eliminated by the matrix matching method. Using this method, sulfur detection limit and minimum quantitative detection limit were 0.028 mg/L and 0.110 mg/L, respectively, whilst the linear range was 0.0–100.0 mg/L. The recovery rate of sample was between 90.67% and 108.7%, and the relative standard deviation (RSD) was between 0.36% and 2.14%. The method was used to analyze the actual samples and the results were basically consistent with the industry standard method. With high analysis efficiency, the method has low detection limit and minimum quantitative detection limit, wide linear range, good precision and accuracy, and provides an important detection method for the determination of total sulfur in geothermal water.     

湖北铜绿山铜铁矿床中煌斑岩的矿物学特征及岩石成因初探

湖北铜绿山矽卡岩型铜铁矿床处于长江中下游铁铜成矿带西部的鄂东南矿集区。最近我们在该矿区工作中采集到两条侵入于含矿石英二长闪长玢岩中的煌斑岩脉。本文对这些煌斑岩脉进行了详细的镜下岩相学观察,并对其中造岩矿物黑云母、辉石和长石进行了电子探针成分分析。根据这些数据本文论述了煌斑岩的物源、形成环境以及岩浆体系的物理化学条件。研究表明,煌斑岩中云母为富镁黑云母,其形成的岩浆体系处于中低氧逸度(近Ni-Ni O);黑云母与全岩都具有高钛特征,表明煌斑岩的物源深度可能来自较深部地幔(如软流圈)。煌斑岩中辉石为单斜辉石,环带较为发育,有韵律环带和正环带,其韵律环带的形成可能是由于岩浆温压环境存在振荡性变化而形成的。铜绿山矿床中煌斑岩属于云煌岩;其岩浆来源具幔源性,受到地壳的混染作用不强。     

A spatio-temporal analysis of academic performance at the Basic Education Certificate Examination in Ghana

Over the last decade, Ghana has more than tripled investment in its basic education system. Consequently, the country has made huge educational gains, primarily in providing universal access to basic education. However, many stakeholders are worried that academic performance is lagging because of disproportional attention to accessing basic education. Discussion of these concerns is hampered by ongoing disagreement about the true trajectory of academic performance at the basic education level and the widespread nature of students' lagging academic performance. In part, this disagreement stems from the failure of empirical studies to comprehensively examine trends in academic performance standards at the basic education level by concurrently considering a geographical and longitudinal perspective. Thus, this study examines the spatio-temporal trends of academic performance at the junior high school level since 2009 by using multilevel growth curve modeling, spatial statistics, and district-level longitudinal data. Results reveal 3 statistically distinct trajectories of academic performance: erratic, accelerating, and decelerating changes. Results also show that rural–urban gaps explain 31% of the performance trajectories, a trend which is expected to persist in the long term. In addition, we find extreme variations in academic performance within rural areas. Given the varying trajectories and geographical variability in academic performance, we suggest a localized approach to addressing challenges of low academic achievement at the basic education level in Ghana.     

Primary vs. secondary curved fold axes: Deciphering the origin of the Aït Attab syncline (Moroccan High Atlas) using paleomagnetic data

The Aït Attab syncline, located in the Central High Atlas, displays a curved geometry in plan view, and is considered as one of the most spectacular fold shapes in the Central High Atlasic belt. We conducted a paleomagnetic study in Jurassic-Cretaceous red beds to investigate the origin of this geometry. The Natural Remanent Magnetization (NRM) is dominated by a secondary magnetization carried by haematite with unvarying normal polarity that has been dated at about 100 Ma. The regional fold test performed in both limbs of the syncline is positive and the paleomagnetic vectors (after tectonic correction) are parallel throughout the curvature, indicating a negative oroclinal bending test. These results are inconsistent with previous works that consider the bent geometry of this syncline to result from subsequent distortion of originally NE–SW trending structures by rotation about a vertical axis. We interpret the NRM data to demonstrate that the changing trend of the Aït Attab syncline is a primary feature, resulting from the influence of pre-existing, NE–SW and E-W-striking extensional faults that developed during a strike-slip regime. Paleomagnetic results also reveal that the tilting observed in the sampled red beds is post Albian, probably linked to the Cenozoic inversion of the High Atlasic belt.     

基于测月雷达机制月壤相对介电常数反演方法模拟研究

嫦娥三号卫星于2013年12月2日发射,并成功着陆月球,其巡视器上搭载的测月雷达实现了首次雷达就位探测月球。基于测月雷达的探测机制,给出了两种计算月壤相对介电常数的方法,标定件标定法和双天线时延法,并通过仿真验证了两种计算方法的有效性,文中同时给出了两种计算方法存在的局限性,为后期基于嫦娥三号雷达数据进行月球次表层的介电特性反演提供了重要依据。     

京津冀及周边地区冬季能见度与PM2.5浓度和环境湿度的多元回归分析

2013年至今,中国冬季与雾霾相伴的低能见度事件频发,京津冀及周边地区尤为严重。PM_2.5浓度与环境湿度是导致低能见度的最关键影响因素。为了深入研究PM_2.5浓度与环境湿度对大气能见度的影响,利用2017年1月京津冀及周边地区MICAPS气象数据与PM_2.5观测数据,运用天气学诊断分析方法讨论了不同相对湿度下PM_2.5浓度、环境湿度对冬季能见度变化的相对贡献,按照地理环境与污染程度差异将京津冀及周边地区划分为北京-天津地区与河北-山东地区,建立了PM_2.5浓度与环境湿度（由露点温度、温度代表）对能见度的多元回归方程,并对2015、2016、2018、2019年冬季能见度进行了回算检验。结果显示:相对湿度低于70%、PM_2.5浓度低于75 μg/m3时,北京-天津地区与河北-山东地区能见度多高于10 km,PM_2.5浓度升高是此时能见度迅速降低的主导因素;相对湿度从70%上升至85%和PM_2.5浓度从75 μg/m3升高200 μg/m3的共同作用导致了能见度降低到10 km至5 km;能见度进一步从5 km下降至2 km则更多依赖于相对湿度进一步从85%升高至95%,PM_2.5浓度与此时能见度相关减弱;能见度降低至2 km甚至更低主要是由于水汽近饱和状态下（相对湿度95%以上）的雾滴消光引起,与PM_2.5浓度的变化关系不大。与不分组直接拟合相比,以相对湿度85%为界线,分别拟合能见度能够很大程度优化多元回归模型,相对湿度高于85%时能见度拟合值的均方根误差从9.2和5.2 km下降至0.5和0.7 km,5 km以下拟合能见度的误差大幅度减小。按相对湿度85%将数据分组所得的拟合方程对2015、2016、2018、2019年1月能见度估算结果较好,观测值与拟合值相关系数均高于0.91,为雾-霾数值预报系统提供了新的能见度参数化算法。      

1960～2018年中国高温热浪的线性趋势分析方法与变化趋势

高温热浪直接影响人体健康和作物生长。研究全球变暖背景下我国高温热浪发生率的趋势是气候变化研究的基本问题之一,可为人们的生产生活等提供重要的科学信息。目前对于高温热浪趋势的研究大都使用最小二乘（Ordinary Least Squares,OLS）方法估计趋势,结合学生t检验判断趋势的统计显著性。本文审视了以往常用方法在研究我国高温热浪发生率的线性趋势时的适用性。首先,以2018年东北局部地区因当年高温日数异常多而形成离群值的例子展开,说明OLS方法估计趋势时对离群值非常敏感,造成虚假趋势。进一步,通过正态分布检验和自相关计算,发现1960~2018年中国至少有91.14%站点、90.06%格点的高温日数和92.18%站点、87.74%格点的热浪次数的序列不服从正态分布,而且多数存在自相关。采用一种不易受离群值影响并考虑自相关的非参数方法,本文对1960～2018年中国站点和格点、4个典型区域以及全国平均的高温日数和热浪次数的线性趋势做出了更为准确的估计。研究发现,高温日数显著增多的站点主要出现在华南和西北地区,热浪次数呈显著增多趋势的站点目前几乎仅限于华南地区和新疆的个别站点;区域平均而言,仅有华南区域和西北区域的高温日数和热浪次数是显著增多的,华北区域和东北区域趋势并不显著;全国平均的高温日数和热浪次数都是显著增多的。本文对高温热浪的趋势及其显著性估计、统计预测的方法选择上有重要参考价值。     

基于CA-FCM方法的飞机增雨效果检验及分析

采用河南省2013—2017年飞机增雨作业资料,利用CA-FCM方法进行增雨效果检验,以探究CA-FCM方法在河南区域飞机增雨效果检验中的合理性及适用性,并分析相对增雨率与季节、检验物理量、垂直积分液态含水量之间的关系。结果表明：CA-FCM方法应用于河南省飞机增雨效果检验,能够获得定量而合理的增雨效果。多数作业相对增雨率0%—40%,少数作业存在减雨效果。研究中春季、夏季、秋季相对增雨率分别为20.8%、22.4%、-22.6%。春季、夏季飞机增雨效果明显优于秋季,一半的秋季增雨作业呈减雨效果,这可能与作业云层可播性条件有较大关系,春季、夏季云层可播性条件优于秋季。显著性检验表明,65%的作业增雨效果显著。增雨作业区域的垂直积分液态含水量越大,相对增雨率显著增加。具有“作业前回波30—50 dBz”、“作业云层尺度较大”条件的作业,易产生一定增雨效果;作业云层回波20—30 dBz,易产生减雨效果;回波强度及面积的维持或增强对增雨效果有明显贡献。     

大理州潜在蒸散量的计算及应用

利用云南大理州12个气象站1961—2010年气温、日照、风速、蒸发量等观测资料,运用彭曼—蒙蒂斯公式计算大理州潜在蒸散量及湿润度指数,并对大理州潜在蒸散量的时空分布特征进行分析,对干旱情况进行评价。结果表明,大理州潜在蒸散量东部大,南部次之,北部最小。月潜在蒸散量5月最大,12月最小,1—5月递增,5—12月递减。1994—2010的平均潜在蒸散量明显大于1961—1993年。大理州潜在蒸散量与降水量、水汽压、气温、净辐射呈显著正相关关系,与风速没有明显的相关关系。正常年份大理州11月至次年5月都存在不同程度的干旱。     

北京一次持续性雾霾过程的阶段性特征及影响因子分析

利用北京地区高时间分辨率观测资料对2009年11月3—8日一次持续性雾霾天气过程中的气象因素和气溶胶演变特征进行了分析。结果表明,该次雾霾过程具有明显的阶段性特征,前期以霾为主,中期发展为雾霾交替,后期随着相对湿度减小再次转换为霾并最终消散。边界层逆温是低能见度过程形成的必要条件,但并不最终决定雾霾低能见度强度。相对湿度和PM_2.5浓度是决定能见度大小的两个关键影响因子,对能见度的影响体现出阶段性特征。大部分时段PM_2.5浓度是影响能见度的主要因子,当能见度小于1 km时,能见度变化更多受相对湿度影响。不同的情景计算表明,控制PM_2.5浓度对于改善本次过程的能见度有重要作用。