Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.     

Tectonic Significance of the Taitung Canyon, Huatung Basin, East of Taiwan

Since the beginning of formation of Proto-Taiwan, the subducting Philippine (PH) Sea plate has moved continuously through time in the N307° direction with respect to Eurasia (EU), tearing the EU plate. The subducting EU plate includes a continental part in the north and an oceanic part in the south. The boundary B between these two domains corresponds to the eastern prolongation of the northeastern South China Sea ocean-continent transition zone. In the Huatung Basin (east of Taiwan), the Taitung Canyon is N065° oriented and is close and parallel to B. Seismic profiles show that the southern flank of the canyon corresponds to a fault with a normal component of a few tens of meters in the sediments and possible dextral shearing. Several crustal earthquakes of magnitude >%6 are located beneath the trend of the Taitung Canyon and focal mechanisms suggest that the motion is right-lateral. Thus, faulting within the sedimentary sequence beneath the Taitung Canyon is a consequence of underlying dextral strike-slip crustal motions. As the continental part of the EU slab located north of B has been recently detached, some subsequent dextral strike-slip motion might be expected within the EU slab, along the ocean-continent transition zone, which is a potential zone of weakness. We suggest that the dextral strike-slip motion along the ocean-continent boundary of the EU slab might trigger the observed dextral strike-slip motion within the overlying PH Sea crust and the associated faulting within the sediments of the Huatung Basin, beneath the Taitung Canyon. An erratum to this article is available at .     

九龙江流域水葫芦打捞去除水体营养盐模型研究

水葫芦被收获时,水体中的营养盐也将包含在植物组织中而被去除.本研究首先通过野外实验和参考国内外有关文献,建立了九龙江流域水葫芦生长数学模型和持续生产模型,确定了模型的各有关参数:水葫芦生长容量K值为25.6 kg/m2、最大生长速率rmax为0.12d-1;水体中氮和磷的半饱和系数hN和hP值分别为0.2和0.03;水葫芦最低生长温度(mθin)为7℃,最适水温(oθpt)为30℃,最高生长温度(θmax)为40℃.随后采用所建立的模型计算了研究区水葫芦打捞的营养盐去除效果,研究区面积6 000m2的水体实施水葫芦打捞策略后,1a所能收获的水葫芦最大产量为9.18×105kg,去除的TP为214.4kg,TN为966.6kg.     

Particulate and dissolved amino acids in the lower Mississippi and Pearl Rivers (USA)

In this study, we present seasonal changes (monthly samples from September 2001 to August 2003) in the abundance and composition of dissolved and particulate amino acids, at one station in the lower Mississippi and Pearl Rivers (LA, MS: USA). Spatial changes over a 4-day transmit from river km 390 to river mouth (Head of Passes, LA) in the Mississippi River, and a two-day downstream sampling from Jackson (MS) to Stennis Space Center (MS) were also determined. Temporal data in the lower Mississippi River showed significantly lower concentrations of dissolved combined amino acids (DCAA, 0.8 to 2.2 μM) and dissolved amino acids in high molecular weight fraction (HMW DAA, 0.2–0.4 μM) than in the Pearl River (DCAA, 1.4–4.3 μM; HMW DAA, 0.4–1.4 μM). Dissolved free amino acids (DFAA) were significantly lower than DCAA in both rivers, and displayed minimal seasonal variability. DCAA, HMW DAA, and particulate amino acids (PAA) were generally higher during high-flow periods, which may have suggested dominance in terrestrial sources. Carbon-normalized yield of PAA (%C-PAA) was generally higher during low-flow conditions and positively correlated with chlorophyll-a (chl-a), reflective of in situ sources. Downstream variability in the lower Mississippi River showed stable DCAA concentrations, a decline in PAA (from 1.06 to 0.43 μM), and a gradual increase in mole percent of non-protein amino acids (%NPAA). This likely reflected bacterial degradation of phytoplankton biomass during falling discharge. Nitrogen-normalized yield of PAA (%N-PAA) was inversely correlated with PAA (R = − 0.7, n = 48), indicative of short-term sedimentation and resuspension events. Conversely, downstream decreases in DCAA and middle-reach peaks of PAA and %N-PAA in the Pearl River, likely resulted from photochemical degradation of DOM as well as algal production during base-flow conditions. The comparisons in abundance and composition of DAA and PAA in these different river systems provides important information on in situ nitrogen and carbon cycling as related to riverine inputs of organic matter to coastal ocean.     

Red Tide Frequency Analysis Using the Extreme Value Theory

In recent years, the red tide erupted frequently, and caused a great economic loss. At present, most literatures emphasize the academic research on the growth mechanism of red tide alga. In order to find out the characters of red tide in detail and improve the precision of forecast, this paper gives some new approaches to dealing with the red tide. By the extreme values, we deal with the red tide frequency analysis and get the estimation of T-times red tide level U （T） , which is the level once the consistence of red tide alga exceeds on the average in a period of T times.     

Shoreline variability via empirical orthogonal function analysis: Part I temporal and spatial characteristics

Empirical orthogonal functions (EOFs) or principal components were used to extract the significant modes of shoreline variability from several data sets collected at three very different locations. Although EOFs have proven to be a valuable tool in the analysis of nearshore data, most applications have focused on the ability of the technique to describe cross-shore or profile variability. Here however, EOFs were used to help identify the dominant modes of longshore shoreline variability at Duck, North Carolina, the Gold Coast, Australia, and at several locations within the Columbia River Littoral Cell in the U.S. Pacific Northwest. In part one of this analysis, characteristic patterns of shoreline variability identified by the EOF analysis are described in detail. At each site, the dominant modes consisting of the first four eigenfunctions were found to describe nearly 95% of the total shoreline variability. At both Duck and the Gold Coast, several interesting longshore periodic features suggestive of sand waves were identified, while boundary effects related to natural headlands and navigational structures/entrances dominated the Pacific Northwest data sets.     

等高线自动绘制中断层处理的新方法

提出了一种断层处理新方法——分块法与断层恢复法合成算法，这种方法兼有分块法与断层恢复法的优点同时又克服了其不足，较好地解决了含逆断层时煤层底板等高线自动绘制及任意边界的构网问题，使绘出的等值线图误差较小，更加符合实际。     

软土海岸地区测量控制点标志的设立

分析了软土、湿地、滩涂地区特殊地理环境对测量控制点的影响;主要探讨了此类地区控制点标志的设计、施工。借助于建筑桩基技术和道桥施工方法,首次成功实现了某三角洲湿地滩涂地区统一布网。几年来,结合滩涂湿地测量、海岸防护和滩涂开发工程对部分控制点进行了初步检测,给出了部分检测数据。应用和检测均表明:桩基标石可较好地解决软土、湿地、滩涂地区控制点布设难题,显著提高软土海岸地区测量控制点标志的稳固性,从而延长控制网的可使用期。     

黄河尾闾河道1996年改道的意义及黄河三角洲演化趋势

现代黄河三角洲由几个亚三角洲组成。 1 85 5 -1 93 4年 ,形成了以宁海为顶点的第一亚三角洲 ;1 93 4-1 996年 ,三角洲冲积扇顶点进一步下移 ,形成了以渔洼为顶点的第二亚三角洲。最近的一次改道是在 1 996年 6月 ,改道后的河流沿清水沟流路的清 8剖面附近东流入海。这次改道可能是第三亚三角洲形成的开始。以后数十年内的黄河尾闾摆动将在清 8剖面附近进行。虽然人类活动将对三角洲的发展演化产生越来越明显的影响 ,但这些亚三角洲的发育演化仍有明显的规律性     

台湾海峡西岸第四纪沉积层中的老红砂

本文对采自福建沿海的老红砂作了粒度分析、矿物鉴定和石英电镜扫描。结果表明,组成老红砂的成分主要为中细砂,砂含量大于70%,粘土和粉砂含量较少。概率累积曲线多为跳跃、悬浮两段式,其次为滚动、跳跃、悬浮三段式。轻矿物以石英为主,长石含量居次。含量较高的重矿物有磁铁矿、钛铁矿、白钛石,其次有锆石、赤铁矿、褐铁矿、电气石、绿帘石等。文章对老红砂的成因提出一些粗浅的看法。