广西佛子冲矿区花岗闪长岩成岩时代讨论

广西佛子冲铅锌矿区岩浆岩发育,其中花岗闪长岩与矿化存在密切的空间分布关系,在花岗闪长岩与围岩接触带形成矽卡岩化,主要铅锌矿体分布于矽卡岩蚀变带中。本文通过对花岗闪长岩和伟晶岩中锆石的研究,并采用LA—ICP-MS对单颗锆石进行了年龄测定,分别获得～228Ma和～248Ma两组和谐年龄,以及一批锆石稀土元素数据。在空间上,伟晶岩脉仅仅分布于花岗闪长岩附近,在伟晶岩中有花岗闪长岩残留。两组锆石样品中的稀土配分特征十分相似,两者的单颗粒锆石同位素年龄值也基本一致,这一时间与广西钦防海槽开始闭合,华夏板块与扬子板块发生碰撞的时间一致;反映出在海西．印支早期沿岑溪．博白深大断裂有一次岩浆上侵于老地层中,形成侵入岩和铅锌矿床。     

Arc magmatism in the Delhi Fold Belt: SHRIMP U–Pb zircon ages of granitoids and implications for Neoproterozoic convergent margin tectonics in NW India

The northwestern region of Peninsular India preserves important records of Precambrian plate tectonics and the role of Indian continent within Proterozoic supercontinents. In this study, we report precise SHRIMP zircon U–Pb ages from granitoids from the Sirohi terrane located along the western fringe of the Delhi Fold Belt in Rajasthan, NW India. The data reveal a range of Neoproterozoic ages from plagiogranite of Peshua, foliated granite of Devala, and porphyritic granite of Sai with zircon crystallization from magmas at 1015 ± 4.4 Ma, 966.5 ± 3.5 and 808 ± 3.1 respectively. The plagiogranite shows high SiO₂, Na₂O and extremely low K₂O, Rb, Ba, comparable with typical oceanic plagiogranites. These rocks possess low LREE and HREE concentrations and a relatively flat LREE–HREE slope, a well-developed negative Eu-anomaly and conspicuous Nb and Ti anomalies. Compared to the plagiogranite, the foliated Devala granite shows higher SiO₂ and moderate Na₂O, together with high K₂O and comparatively higher Rb, Ba, Sr and REE, with steep REE profiles and a weak positive Eu anomaly. In contrast to the plagiogranite and foliated granite, the porphrytic Sai granite has comparatively lower SiO₂ moderately higher Na₂O, extremely high Y, Zr, Nb and elevated REE. The geochemical features of the granitoids [HFSE depletion and LILE enrichment, Nb- and Ta-negative anomalies], and their plots in the fields of Volcanic Arc Granites and those from active continental margins in tectonic discrimination diagrams suggest widespread Neoproterozoic arc magmatism with changing magma chemistry in a protracted subduction realm. Our results offer important insights into a long-lived active continental margin in NW India during early and mid Neoproterozoic, consistent with recent similar observations on Cryogenian magmatic arcs widely distributed along the margins of the East African Orogen, and challenge some of the alternate models which link the magmatism to extensional tectonics associated with Rodinia supercontinent breakup.     

Middle-Late Alpine thermotectonic evolution of the southern Rhodope Massif,Greece

Abstract

The transition from the Alpine tectonic assembly to the exhumation of the units in the Rhodope metamorphic province in northernmost Greece has been refined by ⁴⁰Ar/³⁹Ar laserprobe mica analyses. Preservation of pre-Alpine (~ 280 Ma and 145 Ma) muscovite cooling ages at the western margin of the Rhodope indicate that subsequent events failed to reset the argon system thermally in white mica in the outcropping basement of this region. The central and eastern Rhodope are characterized by white mica cooling ages of 40–35 Ma with ages gradually decreasing to ca. 15 Ma near the eastern margin of the Strymon Valley. The Eo-Oligocene ages reflect the regional exhumation of the metamorphosed units to shallow crustal levels, with corresponding temperatures below ca. 350 °C, by 40–35 Ma. The younger cooling ages are attributed to the initiation and subsequent operation of the Strymon-Thasos detachment system since ca. 30 Ma. This study provides a crucial contribution to future regional tectonic models for the Rhodope region as it recognizes an early stage of development of the Strymon-Thasos detachment system, and has constrained the regional exhumation of the Rhodope metamorphic province since 40 Ma indicating that the regionally observed amphibolite facies metamorphism had terminated by this time. © 2000 Editions scientifiques et médicales Elsevier SAS     

拉萨地体东南缘始新世早期变质作用及其构造意义

本文对位于青藏高原拉萨地体东南缘林芝杂岩中的片麻岩进行了岩石学和锆石U-Pb年代学研究.所研究的样品包括正片麻岩和副片麻岩,它们经历了中压角闪岩相变质作用.岩石地球化学分析结果表明,所研究的正片麻岩的原岩具有钙碱性岛弧岩浆岩的特征.锆石U-Pb年代学分析结果表明,副片麻岩中的碎屑锆石核部为岩浆成因,它们给出的206Pb/238U年龄范围为3012～ 522Ma,其锆石的增生边给出了～51Ma的变质年龄.在正片麻岩中,黑云母片麻岩给出了～67Ma的原岩结晶年龄和～ 55 Ma的变质年龄;石榴石角闪黑云斜长片麻岩给出了～58Ma的原岩结晶年龄和～54Ma的变质年龄.因此,所研究的林芝杂岩并不能代表拉萨地体中的前寒武纪变质基底,而是古生代的沉积岩和晚白垩纪至早新生代的岩浆岩在始新世早期变质而成.这一时期,表壳岩和侵入岩一起经历的中压角闪岩相变质作用很可能跟新特提斯洋俯冲导致的地壳增生、加厚有关.     

西藏青草山斑岩铜金矿含矿斑岩锆石U-Pb年代学、微量元素地球化学及地质意义

西藏青草山斑岩铜金矿是班公湖-怒江缝合带北侧、羌塘地块南缘新发现的具有超大型远景的斑岩型铜金矿床。本文首次对青草山含矿花岗岩闪长斑岩的锆石进行了 LA-ICPMS U-Pb年代学和微量元素地球化学研究,通过对含矿斑岩中锆石的13个点的U-Pb定年,得出锆石²⁰⁶Pb/²³⁸U加权平均年龄为114.60±1.20Ma (MSWD=1.07),此年龄与同样分布于该带上的多不杂斑岩铜矿含矿斑岩成岩年龄、波龙斑岩铜矿成矿年龄基本一致。应用锆石Ti温度计,计算出含矿斑岩中绝大部分锆石的结晶温度小于700℃,如此低的结晶温度指示含矿斑岩岩浆来源于水近饱和条件下发生的部分熔融。通过对锆石微量元素的详细研究,得出青草山含矿斑岩形成于活动大陆边缘的陆缘弧环境,这与前人研究得出的多不杂斑岩铜矿的形成构造背景一致。相近的成岩成矿年龄和一致的形成构造背景揭示以多不杂、青草山、波龙斑岩铜(金)矿床为主要组成的班公湖-怒江斑岩铜矿带的客观存在。依据青草山斑岩铜金矿和多不杂斑岩铜矿的含矿斑岩和同期火山岩的地球化学特征,并结合已有弧环境斑岩铜矿的经典成矿模型,本文提出班公湖-怒江斑岩铜矿带形成的动力学机制,即在早白垩世,班公湖-怒江洋壳向北俯冲,大洋板片向下俯冲到一定深度时,发生大规模脱水作用,释放的流体交代上覆地幔楔,诱发其部分熔融,产生的富含成矿物质的岩浆向上运移,在浅部地壳发育成与成矿相关的岩浆房,部分岩浆上升直接喷出地表,形成下白垩统美日切错组火山岩,部分浅成-超浅成侵位成斑岩体及斑岩型矿床,随着岩浆的多点多期次侵位,最终形成班公湖-怒江斑岩铜矿带。     

Geochronological Records of Oil-Gas Accumulations in the Permian Reservoirs of the Northeastern Ordos Basin

Geochronology of oil-gas accumulation （OGA） is a challenging subject of petroleum geology in multi-cycle superimposed basins.By K-Ar dating of authigenic illite （AI） and fluid inclusion （FI） analysis combined with apatite fission track （AFT） thermal modeling,a case study of constraining the OGA times of the Permian reservoirs in northeast Ordos basin （NOB） has been conducted in this paper.AI dating of the Permian oil-gas-bearing sandstone core-samples shows a wide time domain of 178-108 Ma.The distribution of the AI ages presents 2-stage primary OGA processes in the Permian reservoirs,which developed in the time domains of 175-155 Ma and 145-115 Ma with 2-peak ages of 165 Ma and 130 Ma,respectively.The FI temperature peaks of the samples and their projected ages on the AFT thermal path not only present two groups with a low and a high peak temperatures in ranges of 90-78℃ and 125-118℃,respectively corresponding to 2-stage primary OGA processes of 162-153 Ma and 140-128 Ma in the Permian reservoirs,but also appear a medium temperature group with the peak of 98℃ in agreement with a secondary OGA process of c.～30 Ma in the Upper Permian reservoirs.The integrated analysis of the AI and FI ages and the tectono-thermal evolution reveals that the Permian reservoirs in the NOB experienced at least 2-stage primary OGA processes of 165-153 Ma and 140-128 Ma in agreement with the subsidence thermal process of the Mid-Early Jurassic and the tectono-thermal event of the Early Cretaceous.Then,the Upper Permian reservoirs further experienced at least 1-stage secondary OGA process of c.～30 Ma in coincidence with a critical tectonic conversion between the slow and the rapid uplift processes from the Late Cretaceous to Neogene.     

Diffusion Coefficients of Noble Gases in Natural Minerals: An Apparent Experimental Time Dependence Caused by Domain Size Spectra

Noble gas diffusion coefficients in natural minerals are of use for evaluating geochronometric dates and other geochemical data. Usually, they are determined by degassing at elevated temperatures grain powders of natural samples containing radiogenic or cosmogenic noble gases. For conventional evaluations of diffusion parameters from degassing experiments, the grains should be uniform with respect to structure, composition, shape, and size. The shape and size prerequisites can hardly be fulfilled, because even two very narrowly meshed sieves produce spectra of domain sizes, partly because of the inhomogeneity of the minerals. Accurate determination of the actual spectrum is difficult and hardly practicable. Calculations of the fractional gas loss of a sample with a spectrum of domain sizes, presented in this study, show that almost any domain size spectrum leads to apparent diffusion coefficients that depend on the extent of degassing. The exception of this rule is given. The deviation from the physical diffusion coefficient can be several orders of magnitude as shown by examples. This effect, resulting from shape and width of the domain size spectra, possibly is responsible both for the large spread of Arrhenius parameters for the same mineral in the literature and for the deviation from linearity of some published Arrhenius lines. For limited domain size spectra and short degassing times, the formula for fractional gas loss is very similar to the formula of the fractional gas loss of a single domain size. An effective domain radius, which ensures that at least the measured diffusion coefficient for very short degassing times equals the physical diffusion coefficient, is given. In addition, the dimensionless treatment of the problem is presented that leads to a method to determine Arrhenius parameters without knowing the domain size spectrum. Accurate diffusion measurements of samples with a spectrum of domain sizes may also be possible if the domain size spectrum is taken into consideration. To this end the domain size spectra should be approximated by Taylor-expandable functions or by series of discrete domain sizes. For both cases, the formulae are given.