会泽超大型铅锌矿床成矿时代研究

云南会泽超大型铅锌矿床由麒麟厂和矿山厂两个独立的铅锌矿床组成。利用两组同源矿物组合Rb Sr等时线方法测定了麒麟厂6号矿体的成矿时代,测定结果分别为(225 1±2 9)Ma和(225 9±3 1)Ma,根据已知的分布于该矿床北部和西南部分布的峨眉山玄武岩成岩时代为250Ma左右,有多个火山喷发旋回,显示多期次的喷发活动,认为川—滇—黔成矿区内铅锌成矿作用与峨眉山玄武岩岩浆活动存在成因联系。     

合肥盆地钻井地层的同位素测年与地层划分

合肥盆地内部中、新界地层大面积被第四系覆盖，其地层的时代与划分主要依赖已有的6口深井地层资料。由于缺乏可靠的化石记录，这6口深井地层时代与划分一直存在着很大的分歧，制约了对该盆地的油气勘探与远景评价。本文利用这6口深井泥岩类岩屑中自生伊利石，在其结晶度分析基础上，进行了K-Ar同位素测年，成功地获得了不同深度上的地层形成时代。据此地层年龄，文中对这6口深井所钻遇的地层进行了重新的划分。     

Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.     

基于可持续发展的广东省城市供水价格改革探讨

针对目前城市供水价格计算与计量方式不合理和突出的水资源供需矛盾,提出了按全成本水价模式测算广东省城市供水价格,并采用阶梯水价、两部制水价和季节水价计量方式逐步达到全成本水价的措施与实施步骤,确保水资源的持续利用支撑广东省经济社会的可持续发展.     

河南嵩县店房金矿区花岗斑岩锆石U-Pb年龄、Hf同位素及岩石地球化学

华北陆块南缘外方山店房金矿区内出露后沟、水漉塘和店房钾长花岗斑岩体(脉),其与隐爆角砾岩筒及金矿化有密切的空间关系。为查明钾长花岗斑岩体的侵位时代、岩石成因和源区性质,本次开展了锆石U-Pb定年、锆石Hf同位素及岩石地球化学分析等研究。结果表明岩体具有高硅、高钾、富铝、低镁的特征,属钾玄岩系列Ⅰ型花岗岩,轻重稀土元素分馏明显,具有弱的Eu负异常,岩石富集Rb、K、Ba等,亏损Nb、Ta、Sr、P、Ti等元素。锆石具有核—边结构,其中锆石边SHRIMP U-Pb年龄142.6±2.1Ma(MSWD=1.4),_(εHf)(t)=-23.0~-13.8,两阶段模式年龄主要集中于2075~2652 Ma;锆石核LA-ICPMS U-Pb年龄可分为两组,即2169~2336Ma和1732~1881Ma,Hf同位素组成可分为两组,_(εHf)(t)分别集中于-13.1~-4.8和-4.5~3.7,模式年龄主要集中于2376~2805Ma。表明钾长花岗斑岩体形成于142.6±2.1Ma的早白垩世早期,岩浆可能由2169~2336Ma的古老下地壳新太古代太华群部分熔融而成,并有地幔组分参与,岩浆在上升或定位过程中捕获了1732~1881Ma熊耳群火山岩的锆石。结合区域构造背景认为,该岩体是早白垩世古太平洋板块向欧亚大陆俯冲致使华北陆块岩石圈减薄伸展而引起的岩浆活动的产物。     

冀北中低级变质表壳岩的年代学特征及其对华北克拉通构造演化的约束

华北克拉通在新太古代末期发生克拉通化,形成了现今规模的古陆,大量的太古宙岩石均经历了~2500Ma左右的区域高级变质作用(高角闪岩相-麻粒岩相)。而华北克拉通北部冀北地区出露一套中低级变质(绿片岩相-角闪岩相)的火山-沉积岩系,主要包括胡麻营地区红旗营子表壳岩和大阴山地区单塔子表壳岩中变质程度较低的部分。胡麻营地区红旗营子表壳岩系主要岩石组合为变基性火山岩、绿帘角闪岩、斜长角闪岩、含石榴石斜长角闪岩、角闪斜长片麻岩、黑云斜长片麻岩、黑云角闪斜长片麻岩、黑云二长片麻岩、石英片岩、磁铁石英岩等,SIMS锆石U-Pb定年结果表明斜长角闪岩形成于2486±18Ma(MSWD=1.4),而黑云斜长片麻岩形成于2507±37Ma(MSWD=2.0)。大阴山地区单塔子中低级变质表壳岩系主要由浅变质火山岩、云母石英片岩、斜长角闪岩、磁铁石英岩和大理岩等组成,SHRIMP锆石U-Pb定年结果显示,浅变质火山岩中的变玄武岩形成于2490±19Ma(MSWD=2.0),而变英安岩形成于2502±8Ma(MSWD=0.83)。因此,冀北中低级变质的表壳岩系主要形成于新太古代末期,形成年龄为2507~2486Ma;结合冀东青龙地区新太古代末期(2511~2503Ma)的浅变质火山-沉积岩系(青龙表壳岩),我们认为新太古代末期,中低级变质表壳岩系广泛分布于华北克拉通的核部和边缘地区,此套岩系覆盖在太古宙高级变质杂岩之上,代表华北克拉通化之后的稳定盖层,是克拉通化的主要标志之一。     

广西珊瑚钨锡矿床成矿年代学研究及其地质意义

珊瑚钨锡矿床位于富贺钟钨锡多金属成矿集中区的中部,是南岭钨锡多金属成矿带内典型的热液石英脉型矿床之一。本文采用白云母~(40)Ar-~(39)Ar法和石英流体包裹体Rb-Sr法,对矿床V32号含矿石英脉进行精细年代学研究,获得石英脉中白云母~(40)Ar-~(39)Ar坪年龄为101.7±0.7 Ma(MSWD=0.34),正等时线年龄为102.0±1.0 Ma(MSWD=1.17);石英流体包裹体Rb-Sr等时线年龄为106.4±3.5 Ma(MSWD=0.83)。它们在误差范围内一致,是华南地区燕山晚期成岩成矿高峰期的产物。同时通过石英包裹体H-O同位素组成的初步分析,认为成矿流体属于"再平衡岩浆水",主要来自岩浆,在矿床深部可能存在隐伏花岗岩体。该成果对研究区域成矿规律,指导类似地区的找矿勘查工作具有重要意义。     

黑河新生地区中侏罗世花岗质岩石锆石U-Pb年龄、地球化学特征及岩石成因

黑河新生地区西古兰河以北二长花岗岩的LA-ICP-MS锆石U-Pb同位素测试结果表明,其形成时代为中侏罗世((163.8±1)Ma)。这些中侏罗世二长花岗岩属于弱过铝质高钾钙碱性系列的Ⅰ型花岗岩,明显富集大离子亲石元素(Rb、Ba、Th)和亏损高场强元素(Zr、Hf、Nb、Ta),元素Sr具有明显的负异常,表明其原始岩浆起源于地壳火成岩的部分熔融。结合区域资料同时代火成岩的组合特征和古太平洋板块的构造演化,认为该二长花岗岩形成于活动大陆边缘,而其形成的地球动力学背景可能为古太平洋板块向欧亚板块俯冲造山后的伸展环境。