粤北连平地区钨锡多金属矿床成矿时代研究

粤北连平地区钨锡多金属矿床类型主要为石英脉型.采用云母Ar-Ar法和石英包裹体Rb-Sr法.分别获得:锯板坑含钨锡石英脉中的云母Ar-Ar坪年龄为(139.2±1.5)Ma(等时线年龄为143.6±3.9 Ma,MSWD:0.30):鸡啼石含钨石英脉中石英包裹体Rb-Sr等时线年龄为(155.4±5.1)Ma(MSWD=2.1).结果表明该区存在燕山早期和燕山早晚过渡期两期钨锡多金属成矿作用,并且认为:(1)鸡啼石钨矿为南岭地区中生代大规模成岩成矿作用高峰期(150～160 Ma)的产物;(2)南岭地区140 Ma左右也有大型钨锡多金属矿的形成.这一成果为研究区域成矿规律,指导区域找矿提供了重要同位素年代学依据.     

西准噶尔玛依勒山枕状熔岩地质特征及大地构造意义

玛依勒蛇绿混杂岩带位于西准噶尔增生造山带西南缘.本文重点研究分布于玛依勒山一带枕状熔岩的地质地球化学特征和形成时代,为讨论西准噶尔造山带的形成演化提供依据.玛依勒山蛇绿混杂岩剖面中枕状熔岩、放射虫硅质岩和岩墙等出露较齐全,枕状熔岩为一套碱性玄武岩,源区为富集地幔,构造环境可能为洋盆中海山或洋岛.枕状熔岩Rb-Sr同位素等时线年龄为(435.3±6.5)Ma和(432.5±7.4)Ma,说明其形成时代为志留纪.奥陶—志留纪时,沿玛依勒一线可能出现较开阔的洋盆,现存的玛依勒枕状熔岩和超镁铁质岩代表了志留纪海山或洋岛残片.     

Genesis of the Maka Pb-Zn-W deposit in southeastern Yunnan" Constraints from sphalerite Rb-Sr dating,cassiterite U-Pb dating and in -situ S,Pb isotopes of sulfideSCIEI北大核心CSCD

马卡铅锌钨矿床地处云南省马关县与麻栗坡县的南温河交界处,位于燕山晚期老君山复式花岗岩体北缘。野外地质调查发现,该矿床主要发育矽卡岩型、石英脉型铅锌矿化和萤石石英脉型白钨矿化,但它们的形成机制仍缺乏系统研究。本文通过闪锌矿Rb-Sr、锡石原位U-Pb同位素定年和硫化物原位S、Pb同位素分析,厘定了马卡矿床不同类型铅锌矿化年龄,并探讨了其成矿物质来源及成因机制。矽卡岩型和石英脉型铅锌矿石中闪锌矿分别获得了88.9±1.9Ma(MSWD=4.5)和85.18±0.72Ma(MSWD=1.2)的Rb-Sr等时线年龄,同时获得石英脉型铅锌矿石中锡石LA-ICP-MS U-Pb年龄为84.3±4.7Ma(MSWD=0.66)。结果指示锌、锡矿化时代为晚白垩世,矽卡岩型和石英脉型铅锌矿化分别与该区广泛出露的老君山花岗岩(-90Ma)和花岗斑岩年龄(80-86Ma)一致。矿石硫化物原位硫同位素测试结果显示,δ34S值范围为2.53‰-9.65‰,均值为4.7‰,与老君山花岗岩中硫化物硫同位素组成(4.07‰)相似,表明硫主要来源于老君山花岗岩,少部分源自沉积地层;原位铅同位素组成特征也表明矿石铅主要源自老君山花岗岩。综合研究认为,老君山花岗岩体南北缘地区具有相似的成矿地质条件。马卡矿床的形成主要与燕山晚期老君山复式花岗岩体有关,可能经历了与花岗岩有关的矽卡岩型矿化和与花岗斑岩有关的热液充填、交代成矿过程。     

苏鲁超高压变质带南部浅变质岩的全岩Rb-Sr同位素年龄

提供了苏鲁超高压变质带南部震旦纪浅变质千枚岩的全岩Rb Sr同位素年龄测试数据 ,获得了 2 2 1± 14Ma的等时线年龄。对测试结果的分析认为 :该年龄为浅变质岩的变质年龄。区域调查对比表明 ,低绿片岩相变质作用在造山带组成岩石中普遍存在 ,并叠加于超高压变质岩石 ,因而上述年龄代表在印支期存在普遍的退变质作用年龄。浅变质岩中印支期同位素年龄的获得 ,对正确认识超高压变质带的演化具有重要意义。     

湖南东坡矿田金船塘、红旗岭锡多金属矿床Rb-Sr、Sm-Nd同位素年代学研究

与千里山岩体有密切时空联系的东坡矿田是我国主要钨锡多金属矿产资源基地之一。在前人对千里山复式岩体成岩时代和金船塘与千里山岩体第一期似斑状花岗岩侵入活动有关的成矿作用研究的基础上,笔者选择金船塘及红旗岭矿床含矿石英脉中的石英和金船塘矿床矽卡岩矿石中的单矿物,进行石英流体包裹体Rb-Sr和矽卡岩矿物(包括符山石和石榴石)Sm-Nd同位素年代学研究,得出金船塘及红旗岭矿床石英流体包裹体Rb-Sr等时线年龄分别为133.4±5.9 Ma(MSWD=1.3)和143.1±8.7 Ma(MSWD=47),金船塘矿床矽卡岩矿物Sm-Nd等时线年龄为141±11 Ma(MSWD=0.27)。同位素年代学研究表明金船塘矿床至少存在164 Ma±、133~141 Ma两期成矿作用,在测定误差范围内,它们分别与千里山岩体第一期似斑状花岗岩(152 Ma)和第二期等粒黑云母花岗岩(136~137Ma)的侵入活动有关,而红旗岭矿床的成矿作用与千里山岩体第二期岩浆侵入活动有关。     

大别山高级变质岩云母Rb-Sr等时线年龄测定及其地质意义

应用云母Rb-Sr等时线法对大别山高级变质岩的后期改造历史进行了初步的探讨.采用重液变温技术将云母按比重的区别,分成若干组分,然后用常规的Rb-Sr方法测定.应用这种技术对大别山黄土岭太古代麻粒岩相岩石中的黑云母和产于超高压变质带内的石马含石榴石片麻岩的白云母进行了Rb-Sr等时线年龄测定.黄土岭太古代麻粒岩相片麻岩中的黑云母-全岩Rb-Sr等时线年龄为127±9 Ma,与该区片麻岩中的角闪石的K-Ar和Ar-Ar年龄,及燕山期花岗岩的Rb-Sr年龄一致,说明这一太古代下地壳岩石受到了燕山期深熔-岩浆事件的影响;大别山东南部石马含石榴石片麻岩(榴辉岩相)中的白云母Rb-Sr等时线年龄为191±10 Ma,反映了印支-早燕山期区域性低级变质事件的时代.研究表明,大别山区的不同构造单元中产出的不同类型的高级变质岩自中生代以来有不同的后期演化历史.     

硫化物Rb-Sr同位素定年研究进展

针对金属矿床成矿年代确定混乱的问题,国内外许多矿床学家和同位素地球化学家对金属矿物常规同位素定年方法进行了有益的探索研究,尤其是对于矿石矿物以闪锌矿、方铅矿和黄铁矿为主的铅锌矿床,硫化物矿物Rb-Sr同位素定年方法显示出了其独特的优势。结合近几年开展的工作,总结国内外硫化物Rb-Sr同位素定年研究取得的成果、闪锌矿中Rb、Sr的赋存状态与定年机理以及定年适应性问题。采用闪锌矿Rb-Sr同位素组成数据拟合成等时线源自热液流体与闪锌矿之间Rb和Sr的不同分异作用,但并不是所有的闪锌矿均适合该定年技术。要成功获得年龄,需结合野外地质特征采集代表性的矿石样品,并在镜下鉴定基础上挑选合适的单矿物;在分析测试过程中,需尽可能去除次生包裹体和粘土矿物。     

Geochronologies of the Huaixi copper-gold deposit and the Caomen alkaline granite,SE China: implications for tectonic evolution

The Huaixi copper-gold polymetallic deposit of SE Zhejiang Province, China, is a typical hydrothermal-vein ore body. The Caomen K-feldspar granite porphyry, the dominant intrusion in the mining district, has been dated by laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses of zircon, which yielded a weighted mean ²⁰⁶Pb/²³⁸U age of 101.6 ± 0.9 Ma (MSDW?=?1.3). Rb-Sr dating of fluid inclusions in auriferous quartz from ore bodies yielded an isochron age of 101 ± 2 Ma. These results indicate that intrusion of the Caomen pluton and Cu-Au mineralization was contemporaneous and corresponds to the third episode of Mesozoic magmatism and metallogenesis in South China. Calculated δ¹⁸O values of fluid inclusions from ore-bearing quartz range from??0.89 to??1.98‰ and δD from??42.60 to??60.20‰, suggesting that the ore-forming fluids are derived from a mixed source of magmatic and meteoric waters. δ¹⁸S values of 8 pyrites range from??2.14 to?+4.14‰ with a mean of?+1.67‰, similar to magmatic sulphur. These isotope data support a genetic relationship between the Huaixi copper-gold deposit and the Caomen alkaline granite and probably indicate a common deep source. Petrography and chemical compositions show that the Caomen alkaline granite crystallized from shoshonitic magmas characterized by high SiO₂ (75.64–78.00%) and alkali (K₂O?+?Na₂O?=?7.96–8.82%) but low FeO^T (1.34–3.31%), P₂O₅ (0.05–0.13%) and TiO₂ (0.12–0.18%). The granitic rocks are enriched in Ga, Rb, Th, U, and Pb but depleted in Ba, Nb, Sr, P, and Ti. REEs are characterized by marked negative Eu anomalies (Eu/Eu*?=?0.06–0.13) and exhibit right-dipping ‘V’ patterns with LREE enrichment. These are similar to the Late Cretaceous alkaline granites in the coastal areas of Zhejiang and Fujian provinces, implying that the Caomen granite formed in a post-collisional extensional tectonic setting. Combined with previous studies, we interpret the Huaixi copper-gold deposit and the associated Caomen alkaline granite as related to back-arc extension due to high-angle subduction of the palaeo-Pacific plate, caused by northward movement of the Indian plate.     

Petrogenesis of post – orogenic Lower Permian andesites in southern Europe: insights into the collapse of the Variscan range

In the post-Variscan Early Permian deposits of southwestern Europe, andesites belong to successions characterized by the constant occurrence of a basal rhyolite ignimbrite, followed by andesites, and by abundant dacite-rhyodacite products, interbedded with lacustrine sediments. The subalkaline andesite to K-andesite volcanism developed within intramontane basins following the collapse of the Variscan orogen. The compositional features, including trace element ratios and initial Sr (and Nd) of post-Variscan intermediate products allow excluding continental or island arc settings. The andesite composition of Lower Permian lavas was reproduced starting from two potential primary magmas: picrobasaltic and enriched MORB compositions. In particular, the picrobasalt was modified, by adding incremental amounts of a felsic granulite, from the lower continental crust. Mixing and fractional crystallization (MFC) were modelled by the MELTS software in a closed system under isobaric, isenthalpic conditions (P = 0.3 GPa). The computed residual liquid evolves to match closely the composition of Lower Permian andesite lavas after ~34 % crystallization by adding ~27 % of contaminant to the parental magma.     

Rb-Sr isochron study of the Thorr and Main Donegal Granites,Ireland

A Rb-Sr whole-rock isochron study indicates that the entire Donegal granite suite was emplaced into orthotectonic Caledonian (Dalradian) rocks over a short interval during mid-Silurian to earliest-Devonian times. The Thorr pluton, probably the earliest member of the suite, yields an age of 418 ± 26 Myr and initial ⁸⁷Sr/⁸⁶Sr ratio of 0·7055 ± 4, while the latest member, the Main Donegal pluton has an age of 407 ± 23 Myr and initial ⁸⁷Sr/⁸⁶Sr ratio of 0·7063 ± 5 (Λ⁸⁷Rb = 1·42 ± 10⁻¹¹ yr⁻¹). Errors on both the age and initial Sr isotope ratios incorporate both a priori and geological scatter components and are quoted at the 2-sigma level. The low and restricted range of initial Sr isotope ratios suggests small but significant differences in the composition of the parental granitic magmas which were derived from a low Rb/Sr, low ⁸⁷Sr/⁸⁶Sr source.