内蒙古兴和县曹四夭超大型斑岩钼铅锌金成矿系统年代学及其地质意义

曹四夭斑岩钼矿床位于内蒙古兴和县,是华北克拉通北缘最大的钼矿床。该矿床中部发育斑岩型钼矿体,外围和上部产出热液脉型铅锌金矿体。文章选取1件与斑岩钼矿化共生的绢云母样品进行了40Ar-39Ar定年,获得40Ar-39Ar坪年龄为(144.4±1.2)Ma,相应的39Ar/36Ar-40Ar/39Ar等时线年龄为(146.4±2.2)Ma(MSWD=0.31),将等时线年龄认作绢云母的Ar封闭年龄,表明曹四夭斑岩钼矿化发生在约146 Ma前。选取14件脉型铅锌矿石中的闪锌矿、黄铁矿和磁黄铁矿样品开展了Rb-Sr定年,获得4件闪锌矿的Rb-Sr等时线年龄为(145.1±3.0)Ma(MSWD=0.63);5件黄铁矿的Rb-Sr等时线年龄为(145.2±1.3)Ma(MSWD=0.53);4件闪锌矿、5件黄铁矿和1件磁黄铁矿的Rb-Sr等时线年龄为(145.3±1.0)Ma(MSWD=0.43)。硫化物Rb-Sr定年结果表明曹四夭矿床脉型铅锌矿化形成于约145 Ma前。本次绢云母40Ar-39Ar和硫化物Rb-Sr定年结果表明,曹四夭矿床斑岩型钼矿化和脉型铅锌金矿化为同期产物,两者均形成于晚侏罗世末期,属于同一个斑岩成矿系统。曹四夭矿床硫化物的w(Rb)和w(Sr)分别为0.1867×10~(-6)~1.305×10~(-6)和0.3175×10~(-6)~6.935×10~(-6),Sr同位素初始比值(87Sr/86Sr)i介于0.709 919~0.711 951之间,平均值0.710 952,结合前人获得的辉钼矿Re含量,认为曹四夭矿床的成矿物质主要来源于地壳。     

皖南东至兆吉口铅锌矿床成矿时代的厘定及其找矿指示意义

皖南东至兆吉口铅锌矿床是近年来在江南过渡带西段新发现的一个规模达中型的中-低温热液型矿床。目前揭露的铅锌矿体均赋存于东至断裂带及其西侧次级张(扭)性断裂及裂隙中。文章选取了该矿床主要矿石矿物闪锌矿以及与主成矿阶段金属硫化物紧密共生的石英,分别采用流体包裹体Rb-Sr法和40Ar-39Ar法进行同位素地质年龄测定。4件闪锌矿样品获得流体包裹体Rb-Sr等时线年龄为(128±1)Ma;2件石英样品获得流体包裹体40Ar-39Ar坪年龄分别为(128.74±3.02)Ma和(128.19±1.98)Ma,等时线年龄分别为(128.81±5.25)Ma和(128.30±3.47)Ma,反等时线年龄分别为(128.82±5.24)Ma和(128.31±3.47)Ma。同位素地质年龄测试结果基本一致,表明兆吉口铅锌矿床形成于128 Ma左右,成矿时代为早白垩世。该成矿年龄与赋矿闪长玢岩的形成时间((129.0±2.3)Ma~(128.4±2.7)Ma)一致,也与东至断裂燕山晚期的活动年龄((126.3±2.2)Ma)相近,表明该矿床成矿与燕山晚期的构造-岩浆活动密切相关,此时区域构造背景为强烈挤压后的伸展环境。这一矿化事件在成矿时代上明显晚于长江中下游成矿带中的断隆区(如铜陵、安庆-贵池等矿集区)的铜金多金属矿床和皖南成矿带中的钨钼多金属矿床(136 Ma),而与长江中下游成矿带断坳区的玢岩铁矿床的成矿时间(135~127 Ma)相近,指示长江中下游成矿带与皖南成矿带之间的江南过渡带中发育有燕山晚期较晚阶段(128 Ma左右)的铅锌矿化事件,为今后在该区开展铅锌多金属矿床找矿勘探提供了重要依据。     

Rb–Sr dating of sulfides and S–Pb isotopic study of the Bayanbaolege Ag polymetallic deposit,Inner Mongolia,NE China

The large-scale Bayanbaolege Ag polymetallic deposit is situated in the Tuquan–Linxi Fe-Sn-Cu-Pb-Zn-Ag metallogenic sub-belt in eastern slopes of the southern Great Xing’an Range, NE China. The sulfide-quartz vein-type orebodies in the deposit are hosted primarily in the Early Cretaceous granodiorite porphyry and Late Permian strata. Three primary paragenetic stages of veining have been identified: (I) arsenopyrite- pyrite-quartz stage, (II) pyrite-sphalerite-quartz stage, and (III) galena-silver minerals (pyrargyrite, argentite, and pearceite)-calcite stage. The Rb–Sr dating of sulfides yielded an isochron age of 129.9 ± 2.9 Ma (MSWD = 2.1) for the sphalerite, which constrains the mineralization age to the Early Cretaceous. Rb and Sr concentrations in the sulfides ranged from 0.0940 to 1.0294 ppm and 0.0950–3.3818 ppm, respectively. The initial ⁸⁷Sr/⁸⁶Sr value of the sphalerite was 0.70852 ± 0.00018, indicating that the mineralized materials were derived from the mixed crust-mantle source area. S isotope analysis showed that the δ³⁴S values of the sulfide samples varied in a narrow range, from −1.5‰ to +1.3‰ (mean −0.65‰), indicating a magmatic S source. Pb isotopic ratios of the sulfides (²⁰⁶Pb/²⁰⁴Pb = 18.306–18.416, ²⁰⁷Pb/²⁰⁴Pb = 15.524–15.605, ²⁰⁸Pb/²⁰⁴Pb = 38.095–38.479) and the granodiorite porphyry (²⁰⁶Pb/²⁰⁴Pb = 18.341–18.933, ²⁰⁷Pb/²⁰⁴Pb = 15.539–15.600, ²⁰⁸Pb/²⁰⁴Pb = 38.134–38.944) reflect that the ore-forming materials originated from contemporaneous magma with Early Cretaceous granodiorite porphyry. This study of the Bayanbaolege deposit and other hydrothermal deposits in the area provides compelling evidence that the widespread Mesozoic magmatism and mineralization in the southern Great Xing’an Range occurred in an intracontinental extensional tectonic setting, which was associated with the westward subduction of the paleo-Pacific plate.     

四川甘洛铅锌矿集区闪锌矿Rb-Sr等时线年龄及其地质意义

四川甘洛铅锌矿集区位于扬子地块西南缘的川滇黔铅锌成矿带北段,是四川主要的铅锌产地,具有重要经济价值。为研究该矿集区铅锌成矿时代、成矿大地构造背景和成矿机制,以支撑区域找矿勘查,在区内选择赤普和尔呷地吉两个典型铅锌矿床开展闪锌矿Rb-Sr同位素体系研究,获得Rb-Sr等时线年龄246 ± 17 Ma（MSWD= 2.3）,表明区内铅锌矿化作用发生于早三叠世,与古特提斯洋闭合时限吻合;闪锌矿(87Sr/86Sr)i值变化于0.71061~0.71393,高于幔源87Sr/86Sr值0.70355及峨眉山玄武岩87Sr /86Sr值0.704979~0.706938,低于基底岩石87Sr /86Sr值0.7243~0.7288,暗示成矿物质主要来源于地壳。综合前人研究,认为在古特提斯洋闭合背景下,强烈造山运动诱发盆地卤水深循环并萃取基底地层中的成矿物质,在峨眉山玄武岩岩浆活动的热动力条件下,含矿流体沿马拉哈断裂进一步迁移沉淀形成了赤普和尔呷地吉铅锌矿床。马拉哈深大断裂及造山作用派生的层间或断层破碎带、碳酸盐岩地层是甘洛地区主要的控矿要素。     

Genesis of lithium pegmatites from the leinster granite margin,southeast ireland: Geochemical constraints

Extensive and economically-important lithium pegmatites have been described from the eastern flank of the large S-type peraluminous Leinster Granite batholith in southeast Ireland. This flank area is also the locus of a major dip-slip ductile shear zone which was active during emplacement of the Tullow Lowlands pluton of the batholith. All the known bedrock occurrences of lithium pegmatite are contained within this marginal deformation zone. Most previous studies have suggested derivation of the lithium pegmatites by fractionation from the Leinster Granite itself, though none are conclusive. More recently, an anatectic model has been proposed whereby the pegmatites were derived by melting of Li-rich sediments adjacent to the batholithic contact. Our investigation has been concerned with a detailed study of the Rb-Sr isotope systematics and trace element geochemistry of the pegmatites and their host granitoids in an attempt to resolve the problem of pegmatite genesis. The results suggest a strong geochemical and temporal coherence between the Leinster Granite and the lithium pegmatites. A model is proposed in which Li enrichment in residual magmas may be linked to the development of muscovite instead of biotite in the Leinster Granite itself. The Li excluded from entry to biotite then accumulates in highly mobile, low-viscosity pegmatitic fluids which migrate into the marginal shear zone of the Tullow Lowlands pluton where they crystallize at considerably lower temperatures.     

湘南新田岭白钨矿床He,Ar同位素特征及Rb-Sr测年

新田岭白钨矿床是湘南W-Sn多金属矿集区中的一个大型矽卡岩型矿床,产于骑田岭岩体北接触带.本文对矽卡岩矿石中1件黄铁矿样品进行了流体包裹体He、Ar同位素测定,获得3He/4He值为4.08 Ra,40Ar/36Ar为342,反映了在矽卡岩矿床的成矿流体中亦有地幔流体的显著参与;运用石英Rb-Sr法获得成矿等时线年龄为(157.4±3.2)Ma(2σ)(MSWD=1.6),87Sr/86Sr初始值为0.71044±0.00012,该年龄值与柿竹园超大型钨多金属矿床及芙蓉大型锡矿等的成矿年龄在测试误差范围内基本一致,表明中侏罗世是湘南地区钨锡成矿的高峰期.     

江西金山金矿含金黄铁矿的Rb-Sr年龄

前人对江西金山金矿的成矿时代有许多不同的认识,笔者通过对江西金山蚀变岩型矿石中的含金黄铁矿Rb-Sr年龄的测定得出,含金黄铁矿的Rb-Sr等时线年龄为(838±110)Ma,initial87Sr/86Sr=0.7045±0.0020。由此可以推测晋宁期是蚀变岩型金矿体形成的主要时期。黄铁矿Rb-Sr所得的Sr同位素初始比(87Sr/86Sr)i小于陆源硅酸盐的值(0.720),而与玄武岩的值(0.704)接近,结合前人有关的同位素及稀土、微量元素研究,笔者认为金山金矿变质岩型矿体的成矿物质源于变质围岩,成矿流体为来源于深部的变质水。     

硅岩的Rb-Sr同位素组成特点及其地质意义

通过对扬子地台和东昆仑山地区的不同时代、不同成因、成分上差异较大的硅岩Rb-Sr同位素组成的对比研究，探讨其物源和形成环境，利用所测Rb-Sr等时线年龄，有效的解决硅岩的地层年代，开创硅岩测年的应用前景。     

山西铝土矿Rb-Sr同位素定年

采用Rb Sr全岩与粘土矿物等时线年龄方法测得山西五台剖面 (RS0 1) ,临县剖面 (RS0 2 )和孝义剖面 (RS0 3)的 3个含矿粘土岩的Rb Sr同位素年龄分别为 :316 .9± 1.2Ma ,87Sr/86Sr为 0 .710 5 4± 14 ;315 .5± 1.3Ma ,87Sr/86Sr为 0 .710 86±18;317.3± 1.1Ma ,87Sr/86Sr为 0 .710 5 0± 14。它们代表了铝土矿和含矿系列成矿的同位素年龄 ,相当于晚石炭世早期     

威宁宣威组底部硅质页岩Rb-Sr古混合线年龄及其地质意义

在滇黔相邻地区,二叠纪宣威组下部发育一层硅质页岩和碳质页岩。页岩层位稳定、分布广泛,与下伏峨眉山玄武岩组上部凝灰岩层呈假整合接触关系。用迭代法恢复硅质页岩的Rb-Sr同位素古混合线,得到硅质页岩的年龄为(255±12)Ma。这个年龄不仅支持地层古地磁研究结果,而且符合地层年代学研究结果,表明Rb-Sr同位素古混合线年代学方法在中生代地层能够适用。这个年龄与普遍认为的峨眉山玄武岩主喷发期258Ma从时代关系上相符,而且有效地约束了峨眉山玄武岩喷发的上限。