赛什塘矿区侵入岩的地球化学特征及构造环境分析

青海赛什塘地区岩体分布普遍,是多期次侵入的结果。岩体主要以高钾、过铝质、同属钙碱性系列为特征,具有较低含量的稀土元素丰度值,轻稀土富集,重稀土亏损,铕异常不明显,属I型花岗岩。岩体有Y/Tb值高低不同的两个源区,一是由柴达木地块东南缘岩石圈地幔构成的地幔楔形体,另一个是受其它物源污染的岩浆,是岛弧形成过程中不同阶段的产物。矿区内发现埃达克岩,岩体富含成矿元素,为成矿提供了物质条件。     

贵州簸箕田金矿单矿物稀土元素和同位素地球化学特征

簸箕田金矿位于灰家堡背斜东头倾覆端,是灰家堡卡林型金矿田重要的组成部分。金矿床具有低温成矿特征,出现硅化、白云石化、黄铁矿化等围岩蚀变和特征的Au-As-Hg元素组合。成矿期方解石具有MREE富集和正Eu异常特点,显示矿热液是一种MREE相对富集以及具有正Eu异常的还原性流体,来源于深部或至少经历过对富含斜长石源区的水-岩反应。成矿期方解石的δ~(13)C为-6‰～-0.1‰,成矿期后方解石的δ~(13)C为0.2‰～3.2‰,显示成矿期碳来源于地幔碳和地层碳的混合,成矿期后碳主要来自于地层。矿床硫同位素变化于0.73‰～5.86‰,组成均一化较高,具有接近幔源硫的特征,反映了成矿物质可能主要来自于深源岩浆。总之我们推测成矿物质主要来源于深部,在燕山期区域构造作用下沿深大断裂上涌,当成矿流体运移至背斜核部时,由于成矿条件的聚变,金被快速富集沉淀,形成簸箕田金矿床。     

四川汉源永定桥水库坝区岩溶渗漏的水文地球化学特征研究

在坝区水文地质调查及岩溶发育研究的基础上,对区域中地表水、地下水的宏量组份、稀土元素含量、碳酸盐的碳、氧同位素组成的调查结果表明:雨季前后地下水水化学的变化表明存在断裂带或岩溶通道深部埋藏水向地表排泄的特征;稀土元素含量的变化证实了坝址上游和下游均具有河水补给泉水现象的存在;碳、氧同位素组成的测定为进一步划分出相关的地下水系统提供了依据。本研究结果为坝区岩溶渗漏的工程处理方案提供理论依据。     

贵州织金含稀土磷矿床稀土元素赋存状态研究

利用等离子质谱仪ICP-MS、扫描电镜配合能谱分析、电子探针分析方法,研究了贵州织金含磷岩系剖面稀土含量变化。结果表明,剖面上稀土含量与磷灰石含量变化呈正相关关系,说明稀土主要赋存于磷灰石矿物中;利用扫描电镜、电子探针分析方法对生物碎屑、白云石和胶磷矿进行单矿物微量元素分析研究表明,胶磷矿中稀土含量最高,生物碎屑和白云石稀土含量较低,说明织金含稀土磷矿床稀土元素赋存状态是以类质同象的形式存在于胶磷矿中;利用稀土元素化学物相分析研究同样表明只有少量的稀土元素被磷块岩中粘土矿物所吸附,大量的稀土元素以类质同相形式存在于胶磷矿中。     

贵州大坪电气石岩的发现及其找矿意义

在贵州从江大坪多金属矿区东部地质填图过程中发现电气石岩层,对其进行了岩矿鉴定和粉晶衍射(XRD)、电子探针(EPMA)、电感耦合等离子体质谱(ICP-MS)等分析,结果表明电气石岩的矿物组成为电气石40%～60%、石英约35%～55%,其他约5%为各低含量组分(绿泥石、稀土矿物、锆石等)之和;电气石化学组成中FeO/(FeO+MgO)(Fe#)和MgO/(FeO+MgO)(Mg#)分别为0.64～0.67和0.33～0.36,表明该电气石属于黑电气石-镁电气石固溶体系列;电气石岩的稀土元素特征为稀土元素总量低(ΣREE=21.43×10-6～26.82×10-6),轻稀土元素(LREE)富集,中稀土元素(MREE)亏损,并具有弱的Eu、Ce异常;成矿元素W、Sn、Zn、As、Bi等较高程度富集,指示W、Sn、Zn等具有很大的成矿潜力。电气石岩的发现对该区寻找W、Sn多金属矿床具有重要的指示意义。     

Speciation analysis of metals （Tl, Cd and Pb） in Tl-containing pyrite and its cinder from Yunfu Mine, China, by ICP-MS with sequential extraction

The speciation of heavy metals such as thallium, cadmium and lead existing in pyrite and pyrite cinder was analyzed by ICP-MS with a sequential extraction procedure. The distribution patterns of these metals including exchangeable, reducible, oxidizable and residual fractions were obtained. Tl, Cd and Pb in pyrite and pyrite cinder samples from each extraction step were determined by inductively coupled plasma mass spectrometry (ICP-MS). Under the optimized instrumental conditions, detection limits of Tl, Cd and Pb in different matrices were within the range of 0.006–0.07 μg/L, and the relative standard deviations ranged from 0.8% to 1.2%. The accuracy of Tl, Cd and Pb determination was checked by analyzing two certified reference materials. The results demonstrate that trace Tl, Cd and Pb in the samples can be accurately determined. The sequential extraction results revealed that the percent contents of Tl, Cd and Pb in exchangeable, reducible and oxidizable fractions in pyrite cinder are different from those in pyrite and in pyrite cinder. Tl, Cd and Pb mostly are distributed in residual fraction. Therefore, the mobility of metals in pyrite is higher than that in pyrite cinder. Although distributions of Tl, Cd and Pb in the non-residual fraction are not dominant in pyrite cinder, the total concentrations of them could not be ignored. Consequently, attention must be paid to the risk of potential pollution by pyrite cinder.     

北京粉尘沉降物的物理化学特征及其物源初探

对北京上空不同高度不同时间段采集的粉尘样品的物理化学特征进行了研究。认为不同的风动力作用导致北京上空粉尘不同来源的物质高度混合,且高度越高远源物质越多,高度越低近源物质越多。由于物质来源不同,粉尘的物理化学特征呈现出不同的特点。通过研究发现,Si/Al比值能近似地反映粉尘在空中的分布特征,可以作为粉尘扬起高度的间接指标。     

淮北花沟西井田煤中微量元素及其环境意义分析

通过对30件煤样微量元素含量的测定,分煤层、分类型(稀土元素、环境意义微量元素)讨论了煤中微量元素的分布特征。研究发现各样品的稀土元素主要赋存于矿物质中,稀土元素含量均呈正常质量分数水平分布,各煤层的稀土元素分布表现为轻稀土富集、重稀土亏损。受陆源影响的煤,ΣREE含量高,稀土元素主要由陆源物质继承而来。受海水影响的煤,ΣREE含量低,分布模式具有海水性质。形成后受河流冲刷的煤,灰分增加,煤中稀土元素含量增加。该研究成果为煤炭资源的合理开发和利用提供基础资料。     

http://www.sciencedirect.com/science/article/pii/S1674987110000125

<正>Carbonatites are commonly related to the accumulation of economically valuable substances such as REE.Cu,and P.The debate over the origin of carbonatites and their relationship to associated silicate rocks has been ongoing for about 45 years.Worldwide,the rocks characteristically display more geochemical enrichments in Ba,Sr and REE than sedimentary carbonate rocks.However,carbonatite's geochemical features are disputed because of secondary mineral effects.Rock-forming carbonates from carbonatites at Qinling.Panxi region,and Bayan Obo in China show REE distribution patterns ranging from LREE enrichment to flat patterns.They are characterized by a Sr content more than 10 times higher than that of secondary carbonates.The coarse- and fine-grained dolomites from Bayan Obo H8 dolomite marbles also show similar high Sr abundance,indicating that they are of igneous origin.Some carbonates in Chinese carbonatites show REE(especially HREE) contents and distribution patterns similar to those of the whole rocks.These intrusive carbonatites display lower platinum group elements and stronger fractionation between Pt and Ir relative to high-Si extrusive carbonatite.This indicates that most intrusive carbonatites may be carbonate cumulates.Maoniuping and Daluxiang in Panxi region are large REE deposits.Hydrothermal fluorite ore veins occur outside of the carbonatite bodies and are emplaced in wallrock syenite.The fiuorite in Maoniuping has Sr and Nd isotopes similar to carbonatite.The Daluxiang fiuorite shows Sr and REE compositions different from those in Maoniuping.The difference is reflected by both the carbonatites and rock-forming carbonates,indicating that REE mineralization is related to carbonatites.The cumulate processes of carbonate minerals make fractionated fluids rich in volatiles and LREE as a result of low partition coefficients for REE between carbonate and carbonatite melt and an increase from LREE to HREE.The carbonatite-derived fluid has interacted with wallrock to form REE ore veins.The amount of carbonatite dykes occurring near the Bayan Obo orebodies may support the same mineralization model,i.e.that fluids evolved from the carbonatite dykes reacted with H8 dolomite marble,and thus the different REE and isotope compositions of coarse- and fine-grained dolomite may be related to reaction processes.     

江西相山火山—侵入杂岩及其包体希土元素地球化学

本文综合性地报道了江西相山中生代中、酸性火山－侵入杂岩的稀土元素地球化学研究，以探讨基底变质岩、火山岩、次火山岩及闪长质包体之间的成因联系和差异性。认为此套火山－侵入杂岩具同源演化关系，推测它们均来源于前震旦系结晶基底，成因上属于陆壳重熔型。这与前人对此研究的主流观点是一致的，同时更具有完整性和系统性。