REE/trace element characteristics of sandstone-type uranium deposits in the Ordos Basin

1 Introduction The Ordos Basin is the second largest sedimentary basin in China. During the last 10 years, a great progress has been achieved in the aspects of tectonic evolution, dynamics process, inner and outer geological processes during Mesozoic-Cen…     

REE characteristics of the Fanshan alunite deposit in Zhejiang Province, China

1 Introduction Alunite [KAl3(SO4)2(OH)6] is a very important non-ferrous metal resource, so many countries throughout the world have made great investments in research on the mechanism of its formation, its geological characteristics and applications. O…     

胶莱盆地含金建造地球化学特征

胶莱盆地蓬家夼金矿床及宋家沟金矿床均赋存于下白垩统莱阳群一段含金建造中,该含金建造由砾岩、含砾砂岩、碳质泥岩及碳酸盐岩等组成,Au100.2～241.0ng/g,Ag1.50～3.73μg/g,Zn560～1021μg/g,Pb356～364μg/g,Cu60～394μg/g,As11.0～25.4μg/g,同时富硫及有机碳。含金建造K-Rb、K-Ba呈正相关,K-Sr、K-Ca不相关,Sr/Ba<1,B、V关系均显示了陆相淡水沉积特征。La/Y-REE组成显示了沉积特征。围岩、矿石及矿石中黄铁矿及磁铁矿的稀土元素分布模式相似,该含金建造是矿源层也是容矿层,是区内重要的成矿地质条件及找矿标志。     

华北陆块北缘西段中元古代与裂谷作用有关的铁、稀土、多金属矿床特征及成因

华北陆块北缘西段狼山—白云鄂博裂谷系中元古代形成的大型多金属矿床 ,是我国重要的铁、稀土、铜、铅、锌矿产地。矿床为产于沉积岩中热水沉积型多金属矿床。其形成受地层、构造控制 ,与裂谷作用有着密切的关系。裂谷系内外分支的地质环境及矿床矿种不同 ,导致矿床特征及成因具有一定差异。白云鄂博铁、稀土矿床为钾、钠、磷等含量较高的热水沉积型 ,霍各乞铜、铅、锌多金属矿床为与中基性火山岩有关的过渡热水沉积型 ,东升庙和甲生盘等铅、锌多金属矿床为热水沉积型。文中将对上述矿床分别进行论述。     

Laser Ablation ICP-MS Analysis of Geological Materials Prepared as Lithium Borate Glasses

A simple, rapid and precise method is described for determining trace elements by laser ablation (LA)-ICP-MS analysis in bulk geological materials that have been prepared as lithium borate glasses following standard procedures for XRF analysis. This approach reliably achieves complete sample digestion and provides for complementary XRF and LA-ICP-MS analysis of a full suite of major and trace elements from a single sample preparation. Highly precise analysis is enabled by rastering an ArF excimer laser (λ= 193nm) across fused samples to deliver a constant sample yield to the mass spectrometer without inter-element fractionation effects during each analysis. Capabilities of the method are demonstrated by determination of twenty five trace elements (Sc, Ti, V, Ga, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Hf, Ta, Pb, Th and U) in a diverse range of geological reference materials that includes peridotites, basalts, granites, metamorphic rocks and sediments. More than 90% of determinations are indistinguishable from published reference values at the 95% confidence level. Systematic bias greater than 5% is observed for only a handful of elements (Zr, Nb and U) and may be attributed in part to inaccurate calibration values used for the NIST SRM 612 glass in the case of Zr and Nb. Detection limits for several elements, most notably La, are compromised at ultra-trace levels by impurities in the lithium borate flux but can be corrected for by subtracting appropriate procedural blanks. Reliable Pb analysis has proved problematic due to variable degrees of contamination introduced during sample polishing prior to analysis and from Pt-crucibles previously used to fuse Pb-rich samples. Scope exists for extending the method to include internal standard element/isotope spiking, particularly where integrated XRF analysis is not available to characterise major and trace elements in the fused lithium borate glasses prior to LA-ICP-MS analysis.     

乳山金矿煌斑岩的Sm-Nd同位素研究

乳山金矿区发育多种与金矿脉在时空上密切伴生的煌斑岩脉。煌斑岩的稀土元素含量和配分曲线与胶东群残留体和昆嵛山花岗岩的均较相似；三者的εNd(t)、INd(t)和tDM亦甚为相近。胶东群的分异熔融作用，可较好地解释煌斑岩与花岗岩和胶东群残留体在成因上的渊源关系。     

五台山西部狐狸山含金韧性剪切带的地球化学研究

狐狸山金矿区，在无蚀变作用参与的韧性变形过程中，岩石化学成分发生了明显的变化。但大多数微量元素含量变化不大，稀土元素配分模式基本不变，它们可以反映原岩的特点。蚀变糜棱岩型矿体与围岩相比，稀土配分模式、亲硫元素Ａｕ、Ａｇ、Ｃｕ和两性元素Ａｓ、Ｓｂ含量差别显著，尤其是Ａｕ含量，前者是后者的百倍～几万倍，金的成矿作用主要与韧性变形后期富金流体的蚀变作用关系密切。     

八卦庙大型金矿床稀土元素地球化学研究

八卦庙大型金矿床是秦岭造山带中的一种与碳酸盐岩有关的中温热液矿床。本系统总结了该矿床的稀土元素地球化学特征，对矿石、围岩、含金石英脉、酸性岩脉、铁的硫化物中的稀土元素组成、关系及成因进行了分析研究，论证了这个金矿床的形成与围岩、酸性岩脉、地壳深部金的矿源层有关。在此基础上应用简化了的Ｇｒｅｓｅｎｓ方程－Ｇｒａｎｔ方法讨论了热液蚀变过程中稀土元素地球化学行为，并分析了样品中出现Ｃｅ和Ｅｕ异常的原因，     

新疆乌伦古富碱侵入岩成因探讨

对沿乌伦古深断裂分布的钠闪石花岗岩、钾长花岗岩、闪长岩、碱性正长岩等富碱侵入体进行了较系统的岩石化学、微量元素、稀土元素地球化学及Ｏ、Ｐｂ、Ｓｒ、Ｎｄ同位素组成研究，确认它们为一类幔源重熔分异型富碱侵入岩类。在分析其物质来源、形成构造环境和成岩条件等特征基础上，用部分熔融、多阶段分离结晶和分离结晶－地壳混染等模型探讨了其成岩机理。     

湘南地区稀土矿产资源开发经济意义探讨

湘南地区风化壳型稀土资源丰富，对其开发的采、选工艺和流程简单，投入资金较少，产出颇丰、经济、社会效益明显，是湘南盆困山区脱贫致富的重要途径。本文就开发湘南稀土矿的成本、效益等进行了初步测算，可供参考。