胶莱盆地含金建造地球化学特征

胶莱盆地蓬家夼金矿床及宋家沟金矿床均赋存于下白垩统莱阳群一段含金建造中,该含金建造由砾岩、含砾砂岩、碳质泥岩及碳酸盐岩等组成,Au100.2～241.0ng/g,Ag1.50～3.73μg/g,Zn560～1021μg/g,Pb356～364μg/g,Cu60～394μg/g,As11.0～25.4μg/g,同时富硫及有机碳。含金建造K-Rb、K-Ba呈正相关,K-Sr、K-Ca不相关,Sr/Ba<1,B、V关系均显示了陆相淡水沉积特征。La/Y-REE组成显示了沉积特征。围岩、矿石及矿石中黄铁矿及磁铁矿的稀土元素分布模式相似,该含金建造是矿源层也是容矿层,是区内重要的成矿地质条件及找矿标志。     

REE and (э)Nd of clay fractions in sediments from the eastern Pacific Ocean: Evidence for clay sources

Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents ((REE), LREE/HREE ratio and cerium anomaly (бCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio >1, бCe (0.85, (REE (400 μg/g, LREE/HREE ratio (4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio <1, бCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio (6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or (э)Nd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to (э)Nd values. Terrigenous clay minerals of type I with the (э)Nd values of -8 to -6 originate mainly from North American fluvial deposits. Those of type II with the (э)Nd values of -9 to -7 are mainly from the East Asia and North American fluvial deposits. Those of type III with (э)Nd values of -6 to -3 could come from the central and eastern Pacific volcanic islands. Those of type IV with (э)Nd values of -13 to -12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.     

湘中南二叠系孤峰组硅质岩的成因属性及其地球动力学指示意义

华南二叠系底部的硅质岩及同一层位对应于华南重要的地幔强活动期和成矿期，有非常重要的动力学指示意义。研究表明，孤峰组剖面的岩性可划分为三段：泥页岩段、厚层状硅质岩段和薄层状硅质岩段。沿剖面自下而上，Al2O3、K2O和TiO2含量逐渐降低，MnO、TFe等组分逐渐升高；稀土元素显示出一定的铈负异常，∑REE偏低，且向上∑REE逐渐减少而HREE／LREE逐渐增高；一些热水沉积诊断性微量元素如As、Sb、Hg等也显示出一定程度的异常。这些特征均表明硅质岩的成岩过程中包含有正常沉积和热水沉积的共同作用，且自下而上热水沉积作用逐渐增强的趋势。这种成岩作用的演化特征，代表了下扬子地台拉张裂陷盆地对晚古生代伸展背景的沉积响应，对于探讨裂谷盆地阶段性发育的动力学特征有一定的指示意义。     

622铀矿床与虎圩金矿床REE特征对比

本文通过赣杭火山岩带中的铀矿床和金矿床的ＲＥＥ特征对比，认为产铀矿和金矿的火山岩均属ＬＲＥＥ富集型，但前者明显铕亏损，铀矿石与金矿石ＲＥＥ特征差别大，前者ΣＲＥＥ和ＨＲＥＥ大大增高，铕强烈亏损，后者ΣＲＥＥ降低，铕呈弱异常或无异常．结合两矿床各自的矿化特征，认为成矿热液酸碱度等介质条件、围岩蚀变、副矿物种类、矿物共生组合、次生淋滤富集等因素是造成矿石ＲＥＥ特征的原因，ＲＥＥ贫富程度和分布模式可作为矿床评价因素．     

Negative Ce Anomaly in the Indian Banded Iron Formations: Evidence for the Emergence of Oxygenated Deep-Sea at 2.9-2.7 Ga

Abstract: Major and rare earth element contents are reported for Late Archean banded iron formations (BIFs) in the Bababudan Group of the Dharwar Craton, South India. The BIFs are mostly composed of SiO₂ (average1ρ = 54.88.1 wt%) and Fe₂O₃* (44.38.2 wt%). The Al₂O₃ and TiO₂ contents are remarkably low, suggesting that detrital components were starved during the BIF deposition. The BIFs have a LREE-enriched pattern with a relatively high (La/Yb)_N (6.644.07). Total REE concentrations (RE) vary from 5.2 to 65.3 ppm. The REE patterns are characterized by the presence of a very large negative Ce anomaly (Ce/Ce*: 0.13-0.83) and a positive Eu anomaly (Eu/Eu*: 0.96-2.45). The Eu/Eu* decreases and (La/Yb)_N increases with a increase of RE. These correlations of REE indices are similar to those of modern hydrothermal iron-rich sediments near a mid-ocean ridge (MOR). Greenstones associated with the BIFs have MORB-like geochemical features. These geochemical and geological lines of evidence indicate that the depositional site of the BIFs was remote from a continent and/or island arc and that the BIFs were in situ hydrothermal sediments near a MOR. A striking negative Ce anomaly in the BIFs indicates that oxygenated deep-sea environments emerged at 2.9-2.7 Ga. The existence of contemporaneous Mn deposits in the Dharwar Craton supports this assertion. Our scenario of oxygen in the Earth's surface of the Late Archean is different from long-held notion that the atmosphere and ocean were persistently anoxic throughout the Archean.     

山西高家山铝土矿稀土元素地球化学特征及意义

山西沁源县高家山铝土矿床是山西省地质调查院于2013年发现的大型铝土矿床。本文通过对高家山铝土矿的研究,分析并研究铝土矿样品的稀土元素含量和地球化学特征,探讨稀土元素对于本区铝土矿成因和环境的指示意义。研究表明:该区铝土矿体的ΣREE总量较大,轻稀土元素相对富集,具有明显的Eu负异常;利用稀土元素图解大致反映出底板碳酸盐岩是本区铝土矿床的主要物质来源,铝土矿形成于被动大陆边缘地带海相或海陆过渡相环境。ΣREE与Al2O3含量相关性不大。本区矿床稀土元素含量达到或超过综合利用标准,具有巨大的潜在经济价值。     

辽吉东部层状混合岩的成因

辽吉东部的层状混合岩与上、下围岩始终保持整合接触,反映它的体系基本上是封闭的,没有外来组份的加入。其组构、岩石化学、微量元素和稀土资料等表明层状混合岩不足岩浆型的,而是重熔岩浆型的,其原岩是沉积变质岩。     

滇西勐兴铅锌矿床热液方解石碳氧同位素、稀土元素特征及其指示意义

勐兴铅锌矿床是滇西保山地块内系列低温热液矿床中的典型代表,但地质科研工作相对薄弱。由于方解石是该矿床中分布广泛且与热液活动息息相关的重要脉石矿物,其形成贯穿整个成矿过程,故对其C-O同位素及稀土元素组成特征进行系统研究,以便探讨矿床成矿流体来源及演化。结果显示,该矿床两阶段方解石的δ~(13)C_(PDB)和δ~(18)O_(SMOW)值与海相碳酸盐岩较为接近,且从阶段Ⅰ→阶段Ⅱ呈微弱下降趋势,表明成矿流体中的C主要来源于围岩碳酸盐岩的溶解,阶段Ⅱ成矿流体在与围岩反应之前可能已经发生CO2热液去气作用;阶段Ⅰ方解石的稀土总量、特征参数及配分模式与结晶灰岩较为一致,而阶段Ⅱ方解石与生物碎屑灰岩较为相似,表明阶段Ⅰ方解石中的REE主要来源于结晶灰岩,而后生物碎屑灰岩对阶段Ⅱ方解石中的稀土贡献较大。以上数据及其矿床地质特征均显示该矿床为MVT型铅锌矿床,结合区域构造演化,认为勐兴矿床的形成与中特提斯洋闭合后腾冲地块与保山地块陆陆碰撞挤压密切相关。     

皖北奥陶系碳酸盐岩稀土元素地球化学特征及其古岩溶意义

依据安徽北部刘桥二矿奥陶系碳酸盐岩隐伏剖面 (下奥陶统顶部 ) 17个碳酸盐岩样品的稀土元素 (15个项目 )的测试资料 ,针对不同岩性 ,分类阐述了它们的REE总量和配分模式、LREE和HREE、δEu和δCe的地球化学特征及其剖面变化特点。在此基础上 ,详细讨论了碳酸盐岩稀土地球化学特征成因机理与古岩溶发育环境的关系 ,为在岩溶岩地球化学特征与其形成环境及溶蚀程度间建立定量识别标准提供了依据。     

安徽女山单斜辉石巨晶的地球化学

本文研究了安徽女山14个单斜辉石巨晶。它们属于铝普通辉石、透辉石和铁钠造辉石。主要元素、稀土和微量元素及同位素特征表明：它们是同一碱性玄武岩浆在幔源条件下不同程度结晶分异的产物，相对于寄主岩均属捕虏晶，可能自中生代即已开始形成。