K-Ar法地质年龄国家一级标准物质ZBH-25黑云母的研制

ZBH-25黑云母采自北京房山花岗闪长岩体。它的~(40)Ar/~(39)Ar 阶段加热实验结果表明,~(40)Ar~*在矿物晶格中保存均匀稳定,年龄谱平坦,~(39)Ar 析出量高达96%,~(40)K-~(40)Ar~*同位素体系封闭良好,证明该黑云母结晶以后未受过热扰动。坪年龄为133.0±0.3Ma,总气体年龄为132.1±0.6Ma;~(36)Ar/~(40)Ar-~(39)Ar/~(40)Ar 反等时线年龄为133.1±1.3 Ma,~(40)Ar/~(36)Ar 初始值为293.5±1.6,与大气氩丰度比(295.5±0.5)处于同一范围,表明样品不含过剩氩。激光显微探针单颗粒坪年龄为132.8±0.2Ma,年龄谱和 K/Ca 谱线平坦,激光熔样总气体年龄为131.3±0.2Ma(图6)。这几个 Ar-Ar 年龄的一致性,说明样品具有良好的均匀性和稳定性,是理想的 K-Ar 和 Ar-Ar 法年龄标准物质。对均匀性检验数据进行统计学方法检验,在0.05显著性水平下,证明 K 和~(40)Ar~*的 F 分布值小于 F 临界值,说明该样品是均匀的。国内外14个实验室参加了 K 含量的定值分析,15个实验室参加了~(40)Ar~*含量的定值分析,经统计学方法检验,结果显示全部定值数据都服从正态分布并具等精度。在置信概率为0.95时,~(40)Ar~*和 K 含量的相对标准偏差都小于0.5%。两个特性量值定值分析结果的一致值和不确定度分别为:~(40)Ar~*=1.817±0.013×10~(-9)mol/g,K=7.60±0.02%,K-Ar 年龄(标准值)=132.9±1.3Ma(2σ).此标准物质纯度为98.8%,粒度为0.25-0.63mm,总重量为5800g,缩分成最小样品单元共400瓶,每瓶重量为14.5g。可供我国 K-Ar 和 Ar-Ar 法同位素年代学实验室使用120年。     

In situ cosmogenic ~(10)Be dating of the Quaternary glaciations in the southern Shaluli Mountain on the Southeastern Tibetan Plateau

It is generally considered that four-times ice age happened during the Quaternary epoch on the Tibetan Plateau. However, the research on the chronology of the four-times ice age is far from enough. The Shaluli Mountain on the Southeastern Tibetan Plateau is an ideal place for plaeo-glacier study, because there are abundant Quaternary glacial remains there. This paper discusses the ages of the Quaternary glaciations, based on the exposure dating of roche moutonnée, moraines and gla- cial erosion surfaces using in situ cosmogenic isotopes 10Be. It is found that the exposure age of the roche moutonnée at Tuershan is 15 ka, corresponding to Stage 2 of the deep-sea oxygen isotope, suggesting that the roche moutonnée at Tuershan is formed in the last glacial maximum. The expo- sure age of glacial erosion surface at Laolinkou is 130―160 ka, corresponding to Stage 6 of the deep-sea oxygen isotope. The oldest end moraine at Kuzhaori may form at 421―766 kaBP, corre- sponding to Stages 12―18 of the deep-sea oxygen isotope. In accordance with the climate charac- teristic of stages 12,14,16 and 18 reflected by the deep-sea oxygen isotope, polar ice cores and loess sequence, the oldest end moraine at Kuzhaori may form at stage 12 or stage 16, the latter is more possible.     

从PM10的测量推测成都市区汞污染的来源

通过2007年5—6月期间测量成都市若干条剖面上大气可吸入颗粒物（PM10）中的汞含量，来推测成都市大气中汞的来源。结果表明：在12个点的测量范围内，成都市PM10的质量平均浓度为210．8μg／m^3；PM10中汞的质量平均浓度为0．36ng／m^3。公园和郊区PM10浓度和其中汞浓度均较少，可能与植被茂盛有关。由PM10中汞的分布可知，在热电厂、停用的生活垃圾堆放场和寺庙附近出现最高值。说明热电厂和生活垃圾堆放场是大气汞污染的重要次生来源。寺庙附近出现的高汞值，推测与寺庙的礼仪活动如香烛燃烧有关。     

地铁隧洞带水作业施工技术

以在建的北京地铁十号线双井一劲松区间暗挖隧道为例，通过分析北京特殊地层在带水条件下单洞结构单线隧道台阶法的施工工艺，洞悉浅埋暗挖正台阶法施工中超前预加固、开挖时空顺序、台阶长度等工艺对围岩稳定性的影响程度。     

山东大尹格庄金矿蚀变岩中矿体分布稳定性的动力学控制参量探讨

元素品位分布的相依性指标——赫斯特指数(Hurst指数)是矿体分布稳定性的动力学控制参量,重标极差(R/S)分析是相依性分析的有效方法。利用R/S分析对胶东大尹格庄金矿黄铁绢英岩内不同勘探线金元素品位系列的Hurst指数计算发现,Hurst指数主要介于0.59至0.89之间,均值为0.75,标准差为0.09,均大于随机行走经验Hurst指数的均值与标准差;计算结果说明元素品位分布存在正相关性,但由于受多种因素影响,其空间分布的相依性具有一定波动。元素品位分布的正相依性显示在特定的地质背景内,矿体连续分布或者间断出现,发育相对稳定,其与大尹格庄金矿的地质事实相吻合。     

中国云南易门式铜矿床的主要类型及成因

系统地概括了易门铜矿田的成矿地质背景及2种矿床类型的地质特征,在此基础上论证了火山热水沉积作用、构造改造作用、岩浆叠加作用、地下热水再造作用与成矿密切相关。易门式铜矿床为"裂谷成矿背景-火山热水沉积-构造改造富集-深源岩浆叠加-地下热水再造"型多因复成矿床,建立了新的成矿模式,为该类矿床深部及外围的找矿预测指明了方向。     

Heat flow map of the European part of the U.S.S.R.

A heat flow isoline map is presented. Low and relatively constant heat flow has been observed in the old shield areas of the East European Platform (25–40 mW/m²). Increased heat flow (>50 mW/m²) has been found in the Dniepr-Donetz depression. The area south of the East European Platform is characterized by highly variable heat flow (55–100 mW/m²). Some geophysical implications are discussed.     

Determination of predevelopment denudation rates of an agricultural watershed (Cayaguás River, Puerto Rico) using in-situ-produced Be in river-borne quartz

Accurate estimates of watershed denudation absent anthropogenic effects are required to develop strategies for mitigating accelerated physical erosion resulting from human activities, to model global geochemical cycles, and to examine interactions among climate, weathering, and uplift. We present a simple approach to estimate predevelopment denudation rates using in-situ-produced cosmogenic ¹⁰Be in fluvial sediments. Denudation processes in an agricultural watershed (Cayaguás River Basin, Puerto Rico) and a matched undisturbed watershed (Icacos River Basin) were compared using ¹⁰Be concentrations in quartz for various size fractions of bed material. The coarse fractions in both watersheds bear the imprint of long subsurface residence times. Fine material from old shallow soils contributes little, however, to the present-day sediment output of the Cayaguás. This confirms the recent and presumably anthropogenic origin of the modern high denudation rate in the Cayaguás Basin and suggests that pre-agricultural erosional conditions were comparable to those of the present-day Icacos.     

Minimum Bedrock Exposure Ages and Their Implications: Larsemann Hills and Neighboring Bolingen Islands, East Antarctica

<正>Considerable controversy exists over whether or not extensive glaciation occurred during the global Last Glacial Maximum(LGM) in the Larsemann Hills.In this study we use the in situ produced cosmogenic nuclide ~(10)Be(half life 1.51 Ma) to provide minimum exposure ages for six bedrock samples and one erratic boulder in order to determine the last period of deglaciation in the Larsemann Hills and on the neighboring Bolingen Islands.Three bedrock samples taken from Friendship Mountain(the highest peak on the Mirror Peninsula,Larsemann Hills;～2 km from the ice sheet) have minimum exposure ages ranging from 40.0 to 44.7 ka.The erratic boulder from Peak 106(just at the edge of the ice sheet) has a younger minimum exposure age of only 8.8 ka.The minimum exposure ages for two bedrock samples from Blundell Peak(the highest peak on Stornes Peninsula,Larsemann Hills;～2 km from the ice sheet) are about 17 and 18 ka.On the Bolingen Islands(southwest to the Larsemann Hills;～10 km from the ice sheet),the minimum exposure age for one bedrock sample is similar to that at Friendship Mountain(i.e.,44 ka).Our results indicate that the bedrock exposure in the Larsemann Hills and on the neighboring Bolingen Islands commenced obviously before the global LGM(i.e.,20-22 ka),and the bedrock erosion rates at the Antarctic coast areas may be obviously higher than in the interior land.     

Periglacial climate at the 2.5 Ma onset of Northern Hemisphere glaciation inferred from the Whippoorwill Formation, northern Missouri, USA

The Whippoorwill Formation is a gleyed diamicton that is present locally within bedrock depressions beneath the oldest glacial till in northern Missouri, USA. Stratigraphy, paleomagnetism, and cosmogenic-nuclide burial ages show that it was deposited between the Matuyama-Gauss magnetostratigraphic boundary at 2.58 Ma and the first advance of the Laurentide ice sheet into Missouri at 2.47 ± 0.19 Ma. High cosmogenic-nuclide concentrations also show that the constituents of the Whippoorwill Formation experienced long exposure at a stable landscape surface with erosion rates of 1-2 m/Ma. However, cosmogenic-nuclide concentrations are invariant with depth below the Whippoorwill Formation surface, indicating active mixing of the soil profile shortly before burial by till. The Whippoorwill Formation retains numerous features indicative of cryoturbation. Therefore, we interpret it as a buried Gelisol, a soil formed under periglacial conditions in the presence of permafrost. At the onset of Northern Hemisphere glaciation, climate cooling established permafrost conditions and accelerated erosion by inducing landscape instability. Thus, weathered regolith materials were mobilized and redeposited by gelifluction shortly before the ice sheet overrode the landscape.