西南印度洋中脊49.6°E和50.5°E区玄武岩岩石学及元素地球化学特征

对近年来我国"大洋一号"科考船在西南印度洋中脊(SWIR)多金属硫化物调查区4个站位所获得的玄武岩进行了岩石学及元素地球化学研究。其岩相学特征为以斑状结构为主,斑晶矿物主要由斜长石、辉石和橄榄石组成。基质以间隐结构为主,主要由斜长石、橄榄石和辉石微晶组成。全岩元素地球化学分析结果表明样品属于亏损型洋中脊玄武岩。矿物化学成分表明斜长石主要为倍长石和拉长石,橄榄石为贵橄榄石。研究区玄武岩具低的Na8、K/Ti比值和LREE/HREE以及较高的Fe8值,可整体归入SWIR 49°E-70°E区指示岩浆熔融程度最高、熔融深度最深的区域内。本次研究为探索SWIR洋脊玄武岩和岩浆熔融等相关研究提供了49.6°E和50.5°E区的新资料,也指示了区内岩浆活动或成矿围岩物质来源的复杂性。     

Temporal Change Characteristics of Climatic and Its Relationships with Atmospheric Circulation Patterns in Qinghai Lake Basin

Based on monthly meteorological data from 11 stations(1959-2015)in Qinghai Basin(QHB) and its surrounding area, we analyzed monthly average temperature(Tmean), average maximum(TXam), minimum temperature(TNam) and precipitation variation characteristics as well as the influence of atmospheric oscillation on these parameters using Mann-Kendall trend analysis, mutation analysis, continuous Morlet wavelet transform, Pearson correlation analysis and R/S analysis method. In addition, the future trend of climate change in the regional scale was also discussed. We found that the temperature and precipitation increment were obvious in the region, especially the Tmean in autumn, winter, TXam and TNam in summer and winter precipitation showing significant increase. Temperature and precipitation experienced abrupt changes around 1986 and 2002, respectively. The period of oscillation of each temperature indices was similar featuring 2~3 years,8~10 years short- cycle and 30~32 years middle- cycle, while that for the precipitation featured 3~4 years,6~7 years short- cycle and 30~32 years middle- cycle. The East Asian Summer Monsoon Index(EASMI) anomaly is an important factor for the anomaly of autumn temperature and summer precipitation in QHB, while the Indian Summer Monsoon Index(ISMI) mainly affects the spring temperature and precipitation in the research area. The effects of Arctic Oscillation Index (AO) were relatively strong on temperature variation, especially in autumn and winter, and AO had significant effect on the precipitation in spring, summer and winter, too. The North Atlantic Oscillation Index (NAO) and ENSO have weak influence on the study area, NAO mainly affects summer and winter precipitation, while ENSO mainly affects autumn precipitation. The Hurst index of Tmean and annual precipitation in QHB are higher than 0.5, indicating that the temperature and precipitation in the study area will continue to be the positive trend in the future period.     

Sediment colour reflectance spectroscopy as a proxy for wet/dry cycles at Lake El'gygytgyn,Far East Russia,during Marine Isotope Stages 8 to 12

Marine Isotope Stage 11 has been proposed as an analogue for the present interglacial interval; yet, terrestrial climate records from both this region and time interval are rare. The sediments deposited at Lake El'gygytgyn (67°30′N, 172°5′E) in Far East Russia contain a 3·56 Ma record of climate variability. This study presents a high‐resolution record of sediment colour change from Marine Isotope Stage 8 to 12 (ca 275 to 475 ka) and demonstrates the link between lake catchment processes and climate variability. The hue colour parameter, calculated from data collected via colour reflectance spectroscopy in the visible spectrum (380 to 720 nm), exhibits correspondence with global climate records. Determining the source of sediment colour changes was achieved through detailed mineralogical and sedimentological methods, and linked to colour changes through a series of colour sensitivity tests. Mineralogical data, measured by X‐ray diffraction, reveal fluctuations in concentrations of clay minerals corresponding to colour changes. Further analyses of the clay mineral assemblages show no change in relative clay mineral abundances, yet demonstrate a lake catchment dominated by physical weathering processes. Using measured mineral abundances, reconstructions of sediment colour based on colour reflectance mineral standards link mineral and clay mineral content to overall sediment colour. Colour sensitivity tests demonstrate the ability of iron oxide minerals to stain sediments red. Additionally, colour sensitivity to organic matter content was tested, suggesting that organic content drives variability in the red portion of the spectrum and darkens the overall colour signal. Sediment colour is then ultimately linked to physical weathering of bedrock minerals, with small amounts of chemical weathering producing iron oxides during wet intervals. Fluctuations in the sediment colour reveal a high‐resolution record of wet/dry cycles, and provide new information about wet periods for the Russian Arctic region not yet understood from other lake proxy records.     

云南斑岩型多金属金矿的嵌布特征及赋存状态研究

云南西部有大量低品位金矿资源,且具有嵌布粒度不均匀、矿石结构复杂、解离不完全等特点,传统工艺矿物学分析不易快速、准确测定金赋存状态及载金矿物的嵌布特征。本文利用矿物自动分析系统(MLA)、化学分析等方法对滇西多金属金矿进行系统的工艺矿物学研究,查明了该矿的矿物组成、嵌布粒度、连生及包裹关系,同时阐明了载金矿物的工艺矿物学性质对金回收率的影响。结果表明:金主要以游离态自然金的形式存在,嵌布粒度极细,主要集中在0.01~0.02 mm粒度级别;小于0.074 mm粒级的金占原矿总金量的50.08%,其余金以微细包裹体分散于黄铁矿、磁铁矿、黄铜矿等载金矿物中。但载金矿物粒度较细,解离性差,嵌布不均匀,因此提高载金矿物解离度是提高金回收率的一个重要参考方向。     

广西平乐硅灰石矿工艺矿物学研究

对广西平乐硅灰石矿的化学成分和矿物组成进行了分析确定，对硅灰石及其伴生矿物的结构构造特征进行了查定，主要对硅灰石中碳质物的赋存特征进行了研究，发现硅灰石矿石中的碳质物分别与硅灰石、方解石、石英等多种矿物以多种形式紧密伴生，认为要提高平乐硅灰石粉的白度，除了要尽可能除去透辉石、石榴石等矿物杂质及含铁、锰等的氧化物杂质外，关键还要使碳质物单体解离，并除去碳质物杂质。     

黄沙坪夕卡岩型多金属矿石中锡的工艺矿物学研究

运用化学分析、X射线衍射分析、化学物相分析、扫描电镜、光学显微镜等手段对黄沙坪夕卡岩型多金属矿石中锡的工艺矿物学特征特别是其赋存状态进行了研究。结果表明:矿区锡主要含在石榴子石夕卡岩型磁铁矿石和夕卡岩型钼矿石中;钙铁榴石和磁铁矿是锡的主要载体矿物,二者晶胞参数随锡含量增大而增大,锡在二者晶体结构中可能以Sn4+置换八面体中的Fe3+;锡的化学物相以石榴子石和磁铁矿结合锡为主,夕卡岩型钼矿石中以"胶态锡"为主,锡石含量较少,粒度较小,解离困难,不具选矿回收价值。     

Goethite Morphology and Composition in Banded Iron Formation, Orissa, India

Iron ore deposits are generally described in terms of size, grade and chemical composition rather than the mineralogical and microstructural characteristic of different ore types. It is essential, however, to know the morphology, microstructure and chemical composition of individual minerals for optimum mineral processing. Goethite is reported to occur as a ubiquitous phase in many iron ore types and is particularly abundant in the Precambrian banded iron ore formation of north Orissa, India. Goethite from the Bonai–Keonjhar Belt in Orissa has been examined in terms of its morphology and microstructure in relation to chemical composition. Electron microscopy indicated several goethite morphotypes including botryoidal, nodular, spheroidal, platy, stalactitic and flaky. These different morphotypes display intergranular, intragranular, wedge, reniform, comb, prismatic, cavity-line and bead microstructures. In situ analysis using electron probe microanalyzer indicated a wide compositional variation among the different morphotypes and microstructures. Goethite replacing hematite is generally devoid of deleterious elements while re-precipitated goethite generally contains adsorbed alumina, silica and/or phosphorus. Nodular goethite commonly has a high phosphorus level while botryoidal, spheroidal and platy goethite often contains increased combined alumina and silica. Goethite having a reniform, wedge, intergranular or intragranular microstructure is highly water bearing and cryptocrystalline in nature. During dehydration, bead, comb, cavity-lined or prismatic goethite develop, which are more crystalline and which have a higher iron concentration. Goethite with a wedge, prismatic or bead-type microstructure has a higher adsorption of silica (2–4%), while goethite having an intergranular, bead or prismatic microstructure invariably contains appreciable phosphorus, generally at levels deleterious to processing.     

新疆巴里坤膨润土矿的矿物学及地质特征研究

对新近发现的新疆巴里坤大型膨润土矿进行了矿物学和地质特征研究,对该矿区791件膨润土样品进行了化学分析及数理统计,运用X射线衍射分析技术对其矿物组成进行了研究,查明新疆巴里坤大型膨润土矿蒙托石相对含量高,化学成分与国内其它膨润土矿相比差异明显,其中Na2O含量比较高,一般在4.20%~5.19%之间,Si和Al相对含量的变化是控制蒙脱石含量主要因素。从成矿地质背景分析,认为该矿床属火山沉积型矿床。     

青藏高原冷暖气候变化趋势的R/S分析及Hurst指数试验研究

利用青藏高原1953-2002年77个气象台站的常规地面观测资料,选择不同类型变化趋势的部分台站。选取年平均气温(■)、年平均最低气温(min)、年平均最高气温(■max)、年极端最低气温(tmin)、年极端最高气温(Tmax)5项气候要素,运用R/S分析法研究并预测了青藏高原未来冷暖气候变化趋势,研究表明:青藏高原未来冷暖气候变化趋势与过去50年以来的变化有着很好的自相似性。今后青藏高原总体将继续变暖,用分形理论的原理,设计了一种Hurst指数试验。对青藏高原北部和南部的年平均气温、年平均最低气温进行了试验研究。结果表明:依据青藏高原北部和南部的区域平均气候倾向率,未来10年,■将升高0.2~0.4℃;min将升高0.3~0.5℃;min将升高0.7~0.8℃;■max将升高0.3~0.4℃;■max将升高0.4~0.6℃。其中年平均气温、年平均最低气温升高趋势的持续性很强,期间没有转折,没有冷暖变化的突变点。     

锡铁山铅锌矿床银的工艺矿物学研究

锡铁山铅锌矿矿床除了主元素铅、锌、硫外,还伴生有金、银、镉等稀有和贵金属。为了更好地综合利用矿产资源,对锡铁山铅锌硫化物矿石中伴生银的赋存状态进行了研究,查明了矿石中银的主要矿物种类、分布状态、工艺特征,以及提高伴生银回收率的途径和可能提高的幅度,为选矿工艺研究提供了重要的基础资料。