西北某喷流沉积型铁铜矿工艺矿物学研究

西北某铁铜多金属矿床规模大,具有铁、铜、金、铅锌等多金属矿化,属于海底喷流沉积型矿床。笔者采用工艺矿物学研究方法,查明了矿石工艺矿物学特性。研究结果表明,矿石的组成矿物种类较为复杂,铁矿物主要是磁铁矿、半假象―假象赤铁矿和菱铁矿,其次为赤铁矿,铜矿物主要包括黄铜矿和斑铜矿。矿石中铁矿物和铜矿物均具不均匀细粒―微细粒嵌布特征;通过选矿可获得铜精矿和铁精矿。     

角闪石族和辉石族矿物的系统矿物学分类命名

角闪石族和辉石族矿物是链状硅酸盐矿物的重要组成部分,它们中的许多矿物种属于造岩矿物和/或工业矿物,具有重要的成因矿物研究意义和工业应用开发价值。国内学者对它们的分类命名和基本系统认识主要源自于王璞等(1984)编著的《系统矿物学》。随着科学技术发展和矿物学研究的不断深入,原有的矿物基础资料和分类命名都在不断更新与完善,迄今已有专业学术机构和学者在不同年代陆续发表了不同版本对该两类矿物的修订或修改意见,但一直没有统一整合,导致在涉及该两类矿物的应用研究中,在分类命名上与国际标准不统一。根据本课题组在国家公益性行业科研专项项目(新编《系统矿物学》)所承担的研究任务和当前国内外研究进展,本文系统归纳、梳理并综述了角闪石族和辉石族矿物的分类方案和命名原则,使分类命名统一标准、原则和认识并与国际接轨,这有利于该两类矿物的理论研究与开发应用,更好地支撑地质学及相关学科的研究与发展。     

The origin of tin deposits in the Mount Wells region,Pine Creek Geosyncline,Northern Territory

Tabular steeply dipping cassiterite‐bearing lodes in the Mount Wells region are hosted by lower greenschist fades metasediment of the Pine Creek Geosyncline within the contact aureole of late orogenic granitoids. The latter are predominantly I‐type, but S‐type phases are developed near the sediment‐granitoid contact.

Quartz, cassiterite, pyrite, arsenopyrite, chalcopyrite and pyrrhotite are the main minerals. Two types of lodes are present: (i) Sn‐quartz lodes containing 5–10 vol% sulphide minerals; and (ii) Sn‐sulphide lodes containing ～ 70 vol% sulphide minerals. At the surface, the former appear as normal quartz veins and the latter as hematite‐quartz breccia resulting from the collapse of original sulphide‐rich lodes as a consequence of volume reduction due to oxidation and leaching.

Two stages of quartz veining are recognized in both types of lodes. Cassiterite is present in stage I while stage II is composed of barren quartz with minor pyrite. Late stage III carbonate veinlets are present in Sn‐sulphide lodes. The lode‐wallrock contact is sharp with weak alteration effects confined to the fringe of the lodes. The alteration minerals include sericite, quartz, tourmaline, chlorite, pyrite and minor K‐feldspar.

Four types of fluid inclusions are present in vein quartz and cassiterite: Type A (CO₂ ± H₂O ± CH₄); Type B (H₂O+～ 20% vapour); Type C (H₂O+ < 15% vapour) and Type D (H₂O+ < 15% vapour + NaCl). Early ‘primary’ inclusions represented by Types A and B are present in stage I only and have a well‐defined temperature mode at ～300°C and a salinity range of 1–20 wt% eq NaCl. Types C and D inclusions are ‘secondary’ in stage I and primary in stage II and have a temperature mode at 120–160°C and salinities from about 1 to more than 26 wt% eq NaCl. Variable H₂O‐CO₂ ratios of Type A inclusions and homogenization in CO₂ or H₂O phase at near identical temperature indicate entrapment at the H₂O‐CO₂ solvus and define a pressure of ～ 100 MPa. The melting sequence of frozen inclusions suggests that the ore fluids were mainly H₂O‐CO₂‐CH₄‐Na‐Ca‐Cl brines. This is also confirmed by Raman Laser Spectrometry.

Oxygen and sulphur isotope data are consistent with a magmatic origin of the ore fluids. The δD values are up to 20%0 higher than those expected for magmatic fluids and probably resulted from interaction of the latter with the carbonaceous strata. This interpretation is supported by δ¹³C data on the fluid inclusion CO₂.

Fluid inclusions, stable isotope and mineralogical data are used to approximate the physico‐chemical parameters of the ore fluids which are as follows: T 300°C, m Cl～2, fO₂ ～ 10^‐35, mSS ～ 0.01, Sn ～ 1 ppm, Cu ～ 1 ppm and pH ～ 5.5.

It is suggested that fluids of granitic parentage interacted with the enclosing sediment and picked up CO₂, CH₄ and possibly Ca. The granitic phases became reduced due to this interaction and developed S‐type characteristics. Tin was probably partitioned into the CH₄‐bearing reduced fluids. At some stage the fluid overpressure exceeded the lithostatic lode enforcing failure of the carapace and the intruded rocks by hydraulic fracturing causing CH₄ and CO₂ loss resulting in the precipitation of the ore minerals.     

中国南阳伏牛山世界地质公园地质灾害评价

中国南阳伏牛山世界地质公园位于豫西南山区。地貌类型以中、低山为主,地表多出露变质岩及侵入岩,岩体风化强烈,多赋存基岩裂隙水,地质构造发育,人类工程活动强烈,园区地质环境条件复杂。通过野外调查及评价,园区处于地质灾害高易发区,主要地质灾害有崩塌、滑坡和泥石流。针对地质公园这一特色旅游,提出地质灾害防治对策,保障当地旅游经济可持续发展。     

基于Web平台的岩石矿物数据处理软件新进展

基于Web(WordwideWeb万维网 )平台的岩石矿物数据处理软件是按照浏览器 服务器的模式工作 ,即用户以客户端浏览器为计算平台 ,而计算的应用程序及数据库在服务器端运行。本文介绍了当前岩石矿物数据处理软件的发展现状和趋势及成功开发基于Web平台的岩石数据处理程序的范例 ,探讨了开发基于Web平台的岩石矿物数据处理软件的实现方法及优越性 ,从而论证了建立基于Web平台的岩石矿物数据处理软件的必要性和可行性     

Lithostratigraphic position and petrographic characteristics of R.A.T. (“Roches Argilo-Talqueuses”) Subgroup, Neoproterozoic Katangan Belt (Congo)

The Neoproterozoic Katangan R.A.T. (“Roches Argilo-Talqueuses”) Subgroup is a sedimentary sequence composed of red massive to irregularly bedded terrigenous-dolomitic rocks occurring at the base of the Katangan succession in Congo. Red R.A.T. is rarely exposed in a continuous section because it was affected by a major layer-parallel décollement during the Lufilian thrusting. However, in a number of thrust sheets, Red R.A.T. is in conformable sedimentary contact with Grey R.A.T which forms the base of the Mines Subgroup. Apart from the colour difference reflecting distinct depositional redox conditions, lithological, petrographical and geochemical features of Red and Grey R.A.T. are similar. A continuous sedimentary transition between these two lithological units is shown by the occurrence of variegated to yellowish R.A.T. The D. Strat. “Dolomies Stratifiées” formation of the Mines Subgroup conformably overlies the Grey R.A.T. In addition, a transitional gradation between Grey R.A.T. and D. Strat. occurs in most Cu–Co mines in Katanga and is marked by interbedding of Grey R.A.T.-type and D. Strat.-type layers or by a progressive petrographic and lithologic transition from R.A.T. to D. Strat. Thus, there is an unquestionable sedimentary transition between Grey R.A.T. and D. Strat. and between Grey R.A.T. and Red R.A.T.The R.A.T. Subgroup stratigraphically underlies the Mines Subgroup and therefore R.A.T. cannot be comprised of syn-orogenic sediments deposited upon the Kundelungu (formerly “Upper Kundelungu”) Group as suggested by Wendorff (2000). As a consequence, the Grey R.A.T. Cu–Co mineralisation definitely is part of the Mines Subgroup Lower Orebody, and does not represent a distinct generation of stratiform Cu–Co sulphide mineralisation younger than the Roan orebodies.     

长白山天池火山的岩石矿物学特征——对结晶分异过程和岩浆混合作用的启示

本文对天池火山玄武岩盾,粗面质-碱流质层状锥体以及顶部的粗面质-碱流质碎屑岩类及熔岩的岩石矿物成分做了系统分析,发现在玄武岩类中的主要矿物组合为斜长石、富钙辉石以及富镁橄榄石,而粗面岩-碱流岩类的主要矿物组合为碱性长石、富铁的辉石及橄榄石,并开始出现石英、独居石以及大量的铁钛氧化物,符合结晶分异的演化趋势。同时在玄武岩类及粗面-碱流岩类中均存在不平衡矿物,再结合矿物环带的成分变化、矿物的熔蚀现象及不同特征的岩石条带等,认为天池火山在黑石沟玄武岩、第一、三造锥阶段粗面岩以及千年大喷发的浮岩中均存在岩浆混合作用。根据岩石学及年代学等特征,认为不同时期的玄武质岩浆来自同一地幔源区,经不同程度的结晶分异作用形成,前造锥阶段及造锥阶段的岩石由不同阶段的玄武岩演化而来,全新世的碱流岩类则由造锥阶段粗面岩类演化而来。     

长江中下游地震同青藏高原北部地震的相关性

本文对比了1910—1987年发生的长江中下游地震和青藏高原北部地震,发现两者有比较好的对应关系。一般是,青藏高原北部先发生M≥6级地震,而后长江中下游地区发生M≥19/4级地震。对1910年以来的21次地震进行了统计分析,得到复相关系数R=0.74,能够在很高的显著性水平上通过F检验。地震活动在时间、空间、强度上的相关,现代构造运动及应力场等事实表明,长江中下游地震活动可能主要受青藏高原向东的横向推移运动的影响。     

Cosmic-ray exposure histories of two Antarctic meteorites from Chinese collections and the Guangmingshan and Zhuanghe chondrites

In this paper, we report cosmic-ray exposure ages (3He, 21Ne, 38Ar) and gas retention ages (4He, 40Ar) of two Antarctic meteorites, and the Guangmingshan and Zhuanghe ordinary chondrites. The Antarctic meteorites (GRV98002 and GRV98004) were collected on …     

Rock Magnetic Investigation of Historical Lavas Used in Palaeointensity Studies

Five samples from historical lava flows on Mt. Etna, which had previously been used in a palaeointensity study, were examined using a combination of rock magnetic and microscopic techniques to elucidate the causes of failure of palaeointensity determination. The samples were characterised using a combination of low-temperature susceptibility (LT-), Bitter pattern imaging and scanning electron microscope (SEM). High-temperature susceptibility curves and hysteresis loops had been previously measured by Calvo et al. (2001). Of the five samples only one gave an accurate palaeointensity. This sample was deuterically oxidised and consisted of large exsolved ore grains. It was only possible to distinguish this sample either optically or magnetically from a similar sample by the LT- warming curves; the unsuccessful sample displayed alteration in the LT- warming curves, which was not readily observed in the high temperature susceptibility curves. It is proposed that the measurement of LT- curves before and after heating could be a more sensitive method of determining suitability for palaeointensity determination than previous rock magnetic pre-selection techniques.