伊利石多型——斑岩铜矿化的指示剂

德兴矿区内普遍存在伊利石 ,其多型特征表明 ,矿化围岩与区域围岩 (>2km)中伊利石的矿物结构与矿化流体有关。经长期埋藏变质作用 ,区域围岩中形成了结晶程度完好的 2M1伊利石 ,K櫣ｂｌｅｒ指数为 0 .1 6°,Ir=1 ,无膨胀层 ,是浅变质作用的产物。与发育热液成因 1M伊利石的花岗闪长斑岩一样 ,矿化围岩发育了具有较高K櫣ｂｌｅｒ指数 (平均值为 0 .5 5°)、含少量的膨胀层 (1 %～ 5 % )、1M型伊利石 ,它是热液流体作用下伊 /蒙矿物逆向退化的结果 ,且受热液流体量及水 /岩比制约。在此 ,斑岩铜矿中伊利石多型可能成为有效的矿化晕指示剂。     

Étude expérimentale des transformations de phase dans un gradient thermique : application au granite de Soultz-sous-Forêts,France

The circulation of an injected fluid in the deep granite of the Soultz-sous-Forêts HDR (‘Hot Dry Rock’) site causes important textural and mineralogical modifications. In order to determine the potential crystallization sequences along the fluid pathway, several experiments under thermal gradient were conducted at 600 bar (between 300 and 200 °C). After 40 days, the observed sequences of the newly formed products along the thermal gradient are always as follows, from high to low temperatures: quartz, feldspars, and finally interstratified clays, this implying a significant mobility of aluminium in the solution. To cite this article: A. Baldeyrou et al., C. R. Geoscience 335 (2003).     

Strontium,SO42−/Cl− and Mg2+/Ca2+ ratios as tracers for the evolution of seawater into coastal aquifers: the example of Castell de Ferro aquifer (SE Spain)

The strontium content and the SO₄^2?/Cl^? and Mg²⁺/Ca²⁺ ratios were used as natural tracers of the residence time of seawater intrusion into the Castell de Ferro aquifer. Analysis of these parameters indicated the existence of two principal flowpaths in the aquifer. The first flows through the eastern part of the aquifer, through the karstified Castell de Ferro massif; it accommodates a larger and more rapid flow, so that the residence time is shorter, leading to lower SO₄²⁺/Cl^? ratios, lower Sr²⁺ content and higher Mg²⁺/Ca²⁺ ratios. The second flowpath is in the western sector, and flows exclusively through alluvial deposits; the flow here is slower, particularly that flowing towards the sea. Thus the residence time of the water here will be longer and there is scant flushing of the intruded seawater; this is manifested in the high Sr²⁺ content, high SO₄²⁺/Cl^? and low Mg²⁺/Ca²⁺ ratios. To cite this article: P. Pulido-Leboeuf et al., C. R. Geoscience 335 (2003).     

Répartition de l'uranium et du thorium dans les apatites : implications pour la thermochronologie UTh/He

The UTh/He thermochronology technique assumes a homogeneous distribution of U and Th within the analysed crystals. Cathodoluminescence imaging reveals a strong chemical heterogeneity within apatite a mineral widely used for UTh/He dating. This heterogeneity is then susceptible to induce large errors when calculating the UTh/He age. Chemical analysis using laser ablation ICP–MS of the various zones shown by cathodoluminescence display a link between the Ce, U and Th concentration and the luminescence intensity allowing the UTh/He age to be corrected for zonation. To cite this article: M. Jolivet et al., C. R. Geoscience 335 (2003).     

Datation UPb sur zircons des dolérites tholéiitiques pyrénéennes (ophites) à la limite Trias–Jurassique et relations avec les tufs volcaniques dits « infra-liasiques » nord-pyrénéens

The tholeiitic doleritic magmatism (ophites) in the Aspe valley of the Pyrenees has been dated on the Triassic–Jurassic boundary (199±2 Ma) by the UPb method on zircon (SHRIMP). Emplacement of the ophites was probably synchronous with that of the earliest ‘Infraliassic’ Ségalas tuffs. The ophites are thus related to the Central Atlantic Magmatic Province (CAMP) whose emplacement linked with the fracturing of Pangea, preceded the opening of the Atlantic Ocean. To cite this article: P. Rossi et al., C. R. Geoscience 335 (2003).     

Magnetic phase diagrams of Mg-, Fe-, (Cu + Ti)- and Cu-substituted braunite Mn<Superscript>2+</Superscript>Mn<Subscript>6</Subscript><Superscript>3+</Superscript>SiO<Subscript>12</Subscript>

 The magnetic behavior of the Jahn-Teller structure braunite, (Mn²⁺ _1−yM _y )(Mn³⁺ _{6− x} M_x)SiO₁₂, is strongly influenced by the incorporation of elements substituting manganese. Magnetic properties of well-defined synthetic samples were investigated in dependence on the composition. The final results are presented in magnetic phase diagrams. To derive the necessary data, ac susceptibility and magnetization of braunites with the substitutional elements M = Mg, Fe, (Cu+Ti) and Cu were measured. Whereas the antiferromagnetic ordering temperature, T _N , of pure braunite is hardly affected by the substitution of nonmagnetic Mg, it is rapidly suppressed by the substitution of magnetic atoms at the Mn positions. Typically for a concentration (x, y) ≥ 0.7 of the substituted elements, a spin glass phase occurs in the magnetic phase diagrams. Additionally, for the braunite system with Fe³⁺ substitutions, we observe in the concentration range 0.2 < x< 0.7 a double transition from the paramagnetic state, first to the antiferromagnetic state, followed by a transition to a spin glass state at lower temperatures. The unusual change of the magnetic properties with magnetic substitution at the Mn positions is attributed to the peculiar antiferromagnetic structure of braunite, which has been resolved recently. Received: 19 April 2001 / Accepted: 6 September 2001     

西藏雄村铜（金）矿水环境影响分析及对策

分析了矿山区域水环境特征,采场、废石堆、尾矿库等水环境状况,研究了矿业活动对水环境的影响及水环境的演化趋势,提出了针对性防治措施。     

瞬变电磁法和激电法在西藏墨竹工卡哈海岗铜多金属矿区找矿中的应用

根据墨竹工卡哈海岗矿区矿化岩石和围岩间存在明显地球物理差异的特征,选用瞬变电磁法（TEM）及激电法（IP）组合进行测量,发现了一条长2000多米,宽约200m的瞬变电磁异常带和低阻高极化激电异常,由于这两种方法的异常可相互验证,再结合矿区的地质研究,推断该异常带为铜铅锌矿体所引起,并得到了工程的验证。     

楚雄盆地砂岩铜矿容矿岩石胶结物与铜矿化

砂岩铜矿的含铜矿物较简单,为典型的溶蚀交代岩石组构。含铜砂岩中胶结物主要有碳酸盐类、硅质、泥质和铁质四种,胶结类型有孔隙式、接触式、基底式三种;与矿化关系密切的是碳酸盐类胶结物;矿化强度与铁白云石和孔隙式、接触式胶结类型关系密切。     

东川白沙包陡山沱组铜矿

晋宁运动形成的昆阳群古侵蚀面上存在大小不一的沉积凹地,成为陡山沱组重要的聚矿构造。昆阳群大型铜矿为陡山沱组白沙包铜矿提供丰富成矿物质来源。断裂构造是白沙包铜矿进一步改造富集的重要因素。