沉积物粒度分析在厦门市第四纪环境研究和地层划分对比中的应用

采用MS2000型激光粒度分析仪进行测试，利用计算机粒度分析软件对数据进行整理和计算，绘制出样品的频率曲线、概率累积曲线以及粒度众数位值曲线等图件并进行沉积环境分析。厦门地区第四纪环境演化经历了中更新世同安组(含泥中粗砂、含泥细中砂、砂为主)海积一冲积一更新统上部龙海组(含泥粗中砂、含泥细中砂、含泥粗砂、粗砂、细中砂、含细砾中粗砂、中细砂等)冲积一洪冲积一更新世上部东山组(砂、砂砾、含泥中粗砂、粗砂、泥质中细砂、细砂、中粗砂等)冲洪积及部分海积(粉砂、细粉砂、含碳质泥、粘土、淤泥质粘土、粉砂质粘土等)一全新世长乐组(粉砂，淤泥质粘土、粉砂质粘土、碳质粘土、含砂淤泥质粘土，粉砂质亚粘土、粉细砂亚粘土等)海湾沉积。在解释环境变化的同时，说明粒度变化曲线在一定程度上可以作为地层划分的依据之一，并以此对研究区地层进行了详细划分。     

Interpolating paleovegetation data with an artificial neural network approach

To drive an atmospheric general circulation model (AGCM), land surface boundary conditions like albedo and morphological roughness, which depend on the vegetation type present, have to be prescribed. For the late Quaternary there are some data available, but they are still sparse. Here an artificial neural network approach to assimilate these paleovegetation data is investigated. In contrast to a biome model the relation between climatological parameters and vegetation type is not based on biological knowledge but estimated from the available vegetation data and the AGCM climatology at the corresponding locations. For a test application, a data set for the modern vegetation reduced to the amount of data available for the Holocene climate optimum (about 6000 years B.P.) is used. From this, the neural network is able to reconstruct the complete global vegetation with a kappa value of 0.56. The most pronounced errors occur in Australia and South America in areas corresponding to large data gaps.     

中国东部第四纪自然环境演化及庐山“冰碛层”堆积时期的自然环境研究

根据第四纪地层内孢粉组合和动物群等新资料恢复了我国东部各大区域第四纪各个时期的自然环境特征,其温暖期与干冷期的交替与深海沉积O~(18)温度变化趋势大致对应。庐山三次“冰期冰碛层”内孢粉组合表明均为温暖湿润针阔叶混交林景观,而不是寒冷的冰川环境。     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

Late Quaternary contourites and glaciomarine sedimentation in the Fram Strait

Two sites in the eastern Fram Strait, the Vestnesa Ridge and the Yermak Plateau, have been surveyed and sampled providing a depositional record over the last glacial‐interglacial cycle. The Fram Strait is the only deep‐water connection from the Arctic Ocean to the North Atlantic and contains a marine sediment record of both high latitude thermohaline flow and ice sheet interaction. On the Vestnesa Ridge, the western Svalbard margin, a sediment drift was identified in 1226 m of water. Gravity and multicores from the crest of the drift recovered turbidites and contourites. ¹⁴C dating indicates an age range of 8287 to 26 900 years BP (Early Holocene to Late Weichselian). The Yermak Plateau is characterized by slope sediments in 961 m of water. Gravity and multicores recovered contourites and hemipelagites. ¹⁴C ages were between 8615 and 46 437 years BP (Early Holocene to mid‐Weichselian). Downcore dinoflagellate cyst analyses from both sites provide a record of changing surface water conditions since the mid‐Weichselian, suggesting variable sea ice extent, productivity and polynyas present even during the Last Glacial Maximum. Four layers of ice‐rafted debris were also identified and correlated within the cores. These events occurred ca at 9, 24 to 25, 26 to 27 and 43 ka, asynchronous with Heinrich layers in the wider north‐east Atlantic and here interpreted as reflecting instability in the Svalbard/Barents Ice sheet and the northward advection of warm Atlantic water during the Late Weichselian. The activity of the ancestral West Spitsbergen Current is interpreted using mean sortable silt records from the cores. On the Vestnesa Ridge drift the modern mass accumulation rate, calculated using excess ²¹⁰Pb, is 0·076 g cm^?2 year^?1. On the Yermak Plateau slope the modern mass accumulation rate is 0·053 g cm^?2 year^?1.     

Structural characterization of deep-water deposits in a foreland basin, Silla Syncline (Chilean Patagonia), with applications to depositional processes

Based on our detailed structural characterization, we examine possible relationships between thrust faults and strike-slip faults and thrust-cored folds and depositional units in the Silla Syncline, a 4 km wide fold composed of fine-grained mudstone, coarse sandstone and conglomerate deposits of the Cerro Toro Formation in the Magallanes foreland basin, Chilean Patagonia. The syncline is bounded on its western flank by an asymmetric anticline and on its eastern flank by a broad zone of thrust faults and associated folds, which are oriented sub-parallel to the syncline axis. Deposition of the coarse-grained units of the Silla Syncline appears to have taken place in this structurally defined trough controlled primarily by thrust fault related growth structures flanking the syncline.The syncline and surrounding area have also been deformed by two sets of strike-slip faults, one right-lateral and one left-lateral. The strike-slip and thrust faulting operated contemporaneously for much of their active periods, although it appears that thrust faulting, confined within the fine-grained units, initiated slightly earlier than strike-slip faulting. In addition, younger igneous intrusions at high angle to bedding generally localize along the strike-slip faults. The cross-cutting relationships among the intrusions, strike-slip faults, and flexural slip faults show that all these structures were active during the same period, which extends beyond mid-Miocene.These conclusions support the premise that structures in deep-water sediments are important for understanding not only the deformation of a foreland basin, but also its depositional architecture.     

Migration of the Ganga river and its implication on hydro-geological potential of Varanasi area, U.P., India

Borehole data reveals that during Late Quaternary, the Ganga river was non-existent in its present location near Varanasi. Instead, it was flowing further south towards peripheral craton. Himalayan derived grey micaceous sands were being carried by southward flowing rivers beyond the present day water divide of Ganga and mixed with pink arkosic sand brought by northward flowing peninsular rivers. Subsequently, the Ganga shifted to its present position and got incised. Near Varanasi, the Ganga river is flowing along a NW-SE tectonic lineament. The migration of Ganga river is believed to have been in response to basin expansion caused due to Himalayan tectonics during Middle Pleistocene times. Multi-storied sand bodies generated as a result of channel migration provide excellent aquifers confined by a thick zone of muddy sediments near the surface. Good quality potable water is available at various levels below about 70 m depth in sandy aquifers. Craton derived gravelly coarse-to-medium grained sand forms the main aquifer zones of tens of meter thickness with enormous yield. In contrast, the shallow aquifers made up of recycled interfluve silt and sandy silt occur under unconfined conditions and show water-level fluctuation of a few meters during pre-and post-monsoon periods.     

Multiple discriminant analysis of the Drava River alluvial plain sediments

Three discriminant function models are raised and cross-compared in order to distinguish geochemical patterns characteristic for the Drava River floodplain sediments. Based on data representing total element concentrations in samples collected from alluvium (A), terrace (T), and unconsolidated bedrock (B) at the border of a floodplain, four element clusters emerged accounting for discrimination between the referred groups of sediments. The most prominent is contaminant/carbonate cluster characteristic for alluvium. The other two are: silicate cluster typical for unconsolidated geological substrate (Neogene sedimentary rocks); and naturally dispersed heavy metal cluster separating terrace from the former two groups. Models introducing depth intervals and single profiles as grouping criteria reveal identical sediment-heavy metal matrices. The second important issue of this paper is possibility of reclassification of samples originally assigned to one of the a priori defined groups of sediments, based on established geochemical pattern. The mapped geological units can be reconsidered by the post hoc assignments to a different group if geological border between alluvium and terrace or between terrace and bedrock can not be established geologically with absolute certainty.     

Geomorphological hazards related to deep dissolution phenomena in the Western Italian Alps: Distribution, assessment and interaction with human activities

Deep dissolution affects great part of soluble rocks (e.g. gypsum and anhydrite) of the Western Italian Alps. The related superficial phenomena (sinkholes, gravity-induced processes and a local worsening of geomechanical rock properties) are not limited to typical karsts landscape and cause slope instability also affecting populated sites and infrastructures. The paper aims to describe general characteristic of dissolution phenomena, to interpret their conditioning factors and evolutionary stages and to assess possible hazards due to their superficial effects.The search for evidences of deep dissolution leads to the selection of representative sites in the central part of the Western Italian Alps (Piemonte and Valle d'Aosta Region). Detailed geological and geomorphological studies have been used to classify the selected sites by type, size and variable state of activity. Very different evolutionary stages of dissolution phenomena have been interpreted by comparison of case-studies: some are early “embryonic”; others are more evolved, up to typical sinkholes, or even remodelled by other phenomena. Some cases show an extreme complexity in the interactions between corrosion phenomena and other geomorphic processes: slope deformations, from one side, and karst, fluvial and glacial phenomena, to the other. A wide range of movement rates on slope instabilities induced by deep dissolution have been estimated by topographic and geomorphic data. Geochemical data on removed rocks by dissolution indicate 0.4 mm/year values for local subsidence. Historical and technical data indicate low frequency of major dissolution-induced collapses, but highlight widespread damages to tunnels, roads and buildings, especially along slopes.     

冈底斯新近纪钾质火山作用:消减沉积物折返的地球化学与Sr-Nd-Pb同位素证据

在冈底斯岩浆岩带的羊八井地区,林子宗火山岩系上部出现小规模的粗面质火山岩.岩石学与地球化学研究表明粗面岩与时空密切相关的大体积安山质-英安质-流纹质火山岩属于不同的火山岩系:碱性钾质系列与钙碱性系列.详细的地球化学研究证明林子宗晚期小体积钾质岩具有独立的岩浆源区,而非早期钙碱性系统低压岩浆过程演化的产物.粗面质熔岩SiO2含量为62.91%～64.63%,具有高K2O(7.52%～8.05%)、Al2O3(16.64%-17.35%)、低TiO2(0.59%～0.68%)与MsO(0.15%～0.77%).钾质熔岩富集LILE与LREE,亏损HFSE,具有高Rb/Sr(1.1～2.3)、Th/La(0.59～0.80)、Th/U(6.3～10.9)和低Ce/Pb(4.1～6.2)与Ba/Th(4.3～14.5)比值,其同位素组成变化范围分别是87Sr/86Sr(I)=0.7068～0.7075、143Nd/144Nd(I)=0.51241～0.51252、206Pb/204Pb=18.87～18.95、207Pb/204Pb=15.63～15.70和208Pb/204Pb=39.24～39.68.粗面岩的地球化学与同位素特征表明冈底斯新近纪钾质火山岩来源于角闪岩相的消减沉积物熔融.因此,羊八井新近纪钾质火山熔岩提供了印度-亚洲大陆碰撞早期消减沉积物折返的证据.