地壳温压条件下迁安石英岩的非弹性变形

本文通过研究地壳温压条件下迁安石英岩非弹性变形特征和机制,着重阐述了这类岩石产生非弹性变形的能力和温度压力之间的关系,以及对岩石宏观失稳型式的影响。研究表明,温度和压力的升高将导致岩石中石英晶粒逐步转化为塑性组分,转化过程中伴随着岩石宏观非弹性变形的增强。宏观非弹性变形增强幅度和微观转化为塑性组分的石英晶粒含量满足一定的统计关系。当转化的塑性组分达到一定量级时,岩石的宏观力性和失稳型式将产生明显变化,变化的趋势是易于产生非弹性变形而渐进失稳     

Dauphiné twinning and texture memory in polycrystalline quartz. Part 1: Experimental deformation of novaculite

Mechanical Dauphiné twinning in quartz has been of long-standing interest, both in single crystals and polycrystalline aggregates. This study investigates texture development in fine-grained quartz rock novaculite with no initial texture using compression experiments conducted in the Paterson gas apparatus to explore the influence of stress and temperature. Texture patterns are measured with time-of-flight neutron diffraction and hard synchrotron X-rays, analyzing diffraction data with the Rietveld method. Similar texture patterns are observed as described previously but the new results establish a profound influence of temperature and document that twinning initiates at stresses less than 50 MPa. Possibilities of using Dauphiné twinning as a paleopiezometer in quartz-bearing rocks are discussed.     

大庆岭金矿床石英的矿物学特征及其成因找矿意义

通过大庆岭金矿床中石英的成分、结构、热发光、爆裂测温分析,石英红外光谱特征的研究,认为石英中 Cu、Pb、Zn杂质含量高,晶胞参数大,热发光积分强度大,爆裂累计脉冲数高和红外吸收峰波数低时,标志着为富金的石英特征.     

高温高压条件下实验变形石英闪长岩微观结构与熔体特征研究

本文以高温高压条件下石英闪长岩流变实验样品为研究对象,利用偏光显微镜进行微观结构观察,研究了样品在实验温度压力条件下的变形机制与斜长石结构对流变强度的影响;通过透射电镜能谱与电子探针,分析了熔体分布和成分特征,讨论了角闪石脱水熔融的影响因素与脱水熔融对岩石流变的影响。结果表明,随着温度升高,岩石从脆塑性过渡域逐渐向高温位错攀移和动态重结晶为主的塑性域转化。在高温条件下,角闪石出现了脱水与部分熔融,脱水熔融的熔体分布和成分体现出非均匀与非平衡熔融的特点,空间分布上,熔体主要出现在角闪石和黑云母矿物颗粒的边缘以及角闪石和长石颗粒之间的区域内;成分分布上,熔体的成分与参与熔融的矿物成分密切相关。角闪石边缘的熔体和黑云母边缘的熔体具有低硅铝、高铁镁特征,斜长石边缘的熔体具有高硅铝、低铁镁的特征,处于角闪石和斜长石颗粒中间的熔体,其成分间于斜长石与角闪石成分之间。实验中出现的非平衡非均匀部分熔融可以解释混合岩中的浅色体与暗色体的成因,富硅熔体可以形成富硅铝的花岗质岩石,而贫硅富铁镁的熔体可以形成基性岩。角闪石的脱水熔融程度依赖于样品的封闭条件,处于封闭环境的样品,角闪石不易脱水熔融,而处于开放环境时,角闪石脱水熔融显著。拆离断层带及其附近具备这样的开放环境,有利于角闪石发生脱水熔融。实验力学数据和微观结构显示,随机分布的斜长石对岩石强度影响并不明显,但斜长石的长轴方向与最大主应力方向呈大角度相交(近90°)会显著强化岩石的强度,这意味着岩石组构与主应力方向大角度相交或呈垂直方向时,不利于岩石变形和拆离断层的形成,反之,均匀岩石或岩石组构与最大主应力方向小角度相交,有利于岩石的变形,容易发育拆离断层。     

江西银山铅锌矿床闪锌矿与石英流体包裹体的对比研究

赣东北地区是我国重要的铜铅锌金银多金属矿集区,银山铅锌(银)铜(金)多金属矿床是赣东北地区一个重要的大型次火山热液型多金属矿床。银山铅锌矿发育有闪锌矿-方铅矿-石英脉,前人研究认为金属矿物与脉石矿物为伴生关系,但是没有强调它们的成因上的联系。本次研究开展了矿石矿物中闪锌矿和伴生脉石矿物中石英的流体包裹体对比研究。通过详细的岩相学观察、显微测温、显微激光拉曼探针工作,对伴生石英脉和闪锌矿内原生包裹体,伴生石英脉中的晚期微细石英脉和闪锌矿内部次生包裹体进行流体特征的对比研究。研究结果显示,伴生石英脉原生流体包裹体比闪锌矿的原生包裹体的平均均一温度高约30℃,明显富集CH₄、N₂、CH₄、CO₂等挥发份,伴生石英脉中的晚期微细石英脉流体包裹体比闪锌矿次生包裹体的平均均一温度高23℃。闪锌矿原生包裹体与想伴生的早期石英脉在平均均一温度有所差别,气相成分差异明显,均表明矿石矿物与伴生脉石矿物可能形成于不同的地质环境,具有不同的温度和流体成分。     

Mineralogical and colour changes of quartz sandstones by heat

Seven German and three Hungarian monumental sandstones have been tested in laboratory conditions to analyse the effect of heat. The studied quartz sandstones have a wide-range of cements and grain-sizes including silica-, carbonate-, clay- and ferrous mineral—cemented varieties of fine-, medium- to coarse-grained types. Cylindrical specimens were heated up to 150, 300, 450, 600, 750 and 900°C in an oven. The mineralogical and textural changes were recorded and compared by using microscopy, XRD, DTA-DTG and SEM. Colours and colour differences (a*, b*, L* values) were also measured and evaluated. Colour changes are related to mineral transformations. The most intense colour change is caused by the oxidation of iron-bearing minerals to hematite that takes place up to 900°C. When temperature increases the green glauconite becomes brownish while the chlorite changes to yellowish at first. The colour of burnt sandstone is not a direct indicator of burning temperature, since there are sandstones in which the burnt specimens are lighter and less reddish than the natural ones. Porosity increase is related to micro-cracking at grain boundaries (above 600°C) and within the grains (at and above 750°C) and mineral transformations. The clay mineral structure collapses at different temperatures (kaolinite up to 600°C, chlorite above 600°C) and leads to a slight increase in porosity. The most drastic change is observed in calcite cemented sandstones where the carbonate structure collapses at 750°C and CaO appears at 900°C. Subsequently it is transformed to portlandite due to absorption of water vapour from the air. This leads to the disintegration of sandstone at room temperature a few days after the heat shock.Special issue: Stone decay hazards     

Deformation and fluid flow in the Huab Basin and Etendeka Plateau,NW Namibia

The Lower Cretaceous Twyfelfontein sandstone formation in the Huab Basin in NW Namibia shows the effects of volcanic activity on a potential reservoir rock. The formation was covered by the Paraná-Etendeka Large Igneous Province shortly before or during the onset of South-Atlantic rifting. Deformation bands found in the sandstone trend mostly parallel to the continental passive margin and must have formed during the extrusion of the overlying volcanic rocks, indicating that their formation is related to South-Atlantic rifting. 2D-image porosity analysis of deformation bands reveals significant porosity reduction from host rock to band of up to 70%. Cementation of the sandstone, linked to advective hydrothermal flow during volcanic activity, contributes an equal amount to porosity reduction from host rock to band when compared to initial grain crushing. Veins within the basaltic cover provide evidence for hot fluid percolation, indicated by spallation of wall rock and colloform quartz growth, and for a later low-temperature fluid circulation at low pressures indicated by stilbite growth sealing cavities. Sandstone samples and veins in the overlying volcanic rocks show that diagenesis of the Twyfelfontein sandstone is linked to Atlantic rifting and was affected by both hydrothermal and low-thermal fluid circulation.     

翁嘎科金矿矿床成因及找矿标志

金矿赋存在西盟群王雅组第四段第一、二亚段地层和次级断裂裂隙中。从地质特征、矿体赋存状态、矿石特征等判断,矿床成因类型为热液充填交代型。而北东向区域断裂中,可能找到新的矿体。     

关于衢州古城墙通仙门凝灰岩砌块相对风化速度的研究

岩石风化速度历来受到工程地质学界和地貌学界的关注, 但由于岩石在自然条件下的风化速度很慢, 通常很难测到定量化的结果。为了研究衢州古城通仙门城台基座的凝灰岩砌块的相对风化速度, 作者利用与之相邻的石英砂岩水平砌块和它之间风化厚度的比较来估算凝灰岩相对于石英砂岩自明代筑城开始至今的相对风化速度, 得出平均风化速度为0.086mmA-1的结论。     

西天山玉希莫勒盖达坂石英闪长岩的微量元素地球化学及同位素年代学研究

玉希莫勒盖达坂石英闪长岩的主量元素组成相对稳定,SiO2、TiO2、Al2O3、Fe2O3T、MgO、CaO、Na2O和K2O的含量分别为57.08%～59.95%、0.70%～0.85%、16.34%～16.81%、6.73%～8.51%、2.82%～3.55%、5.72%～6.91%、3.22%～3.90%和1.44%～1.96%。该类岩的CA/TH指数在1.2左右变化,应属钙碱性系列岩石。主量元素和微量元素地球化学特征显示,玉希莫勒盖达坂石英闪长岩与区域内的大哈拉军山组钙碱性玄武安山岩为同源岩浆岩,它们是富集的尖晶石二辉橄榄岩部分熔融的产物,原始地幔楔的富集受俯冲板块脱水形成流体控制,这种源区富集交代过程导致玉希莫勒盖石英闪长岩具有明显的陆壳混染特征。玉希莫勒盖石英闪长岩明显亏损Nb-Ta、Zr-Hf、Ti等高场强元素,同时富集Pb,显示出与板块俯冲作用有关造山带岩浆岩的特征,形成于活动陆缘岛弧。与大哈拉军山组高钾系列火山熔岩形成于板片撕裂诱发的伸展构造环境不同,石英闪长岩形成于挤压的构造环境。单颗粒锆石U-Pb定年结果显示,石英闪长岩的形成年龄为309.9±2.7Ma,暗示阿吾拉勒东段大哈拉军山组火山岩的形成时代为晚石炭世。