岫岩陨石坑撞击角砾岩的岩相学和冲击变质特征SCIEI北大核心CSCD

撞击角砾岩是陨石撞击过程形成的特有岩石种类,是研究撞击成坑过程、陨石坑定年、矿物岩石冲击变质的理想对象。岫岩陨石坑是一个直径1800m的简单陨石坑,坑内有大量松散堆积的撞击角砾岩。本研究通过光学显微镜、费氏台、电子探针、X射线荧光光谱仪、电感耦合等离子质谱仪等分析测试手段,主要研究了岫岩陨石坑撞击角砾岩的岩相学和冲击变质特征,并在此基础上讨论了撞击角砾岩的形成过程和陨石坑的形貌特征。岫岩陨石坑内产出有三种撞击角砾岩,分别是来自上部的玄武质角砾岩和复成分岩屑角砾岩,以及底部的含熔体角砾岩。组成玄武质角砾岩和复成分岩屑角砾岩的碎屑受到的冲击程度较低,仅有少量石英发育面状变形页理,指示不超过20GPa的冲击压力。而组成含熔体角砾岩的碎屑受到了很强的冲击,发育了熔融硅酸盐玻璃、石英面状变形页理、柯石英、二氧化硅玻璃、击变长石玻璃、莱氏石等冲击变质特征,指示的峰值压力超过50GPa。本研究证实了含熔体角砾岩通常产出在简单陨石坑底部,由瞬间坑的坑缘和坑壁垮塌的岩石碎屑与坑底的冲击熔体混合形成。岫岩坑的真实深度是495m,真实深度与直径的比值为0.275,符合简单陨石坑的尺寸特征。陨石坑内的撞击角砾岩中心厚度为188m,与直径之比为0.104,略低于其它简单坑,可能是受丘陵地貌影响导致改造阶段垮塌到坑内的岩石角砾偏少。     

Granular titanite from the Roter Kamm crater in Namibia: Product of regional metamorphism,not meteorite impact

Accessory minerals with so-called granular texture have risen in importance as geochronological tools for U-Pb dating of meteorite impact events. Grain-scale recrystallization, typically triggered by a combination of high-strain deformation and post-impact heating, can create a polycrystalline microstructure consisting of neoblasts that expel radiogenic Pb, which are thus ideal for isotopic dating. While granular domains in zircon and monazite from shocked rocks have been demonstrated to preserve impact ages, few U-Pb dating studies have been conducted on granular microstructures in titanite (CaTiSiO₅). Here we report the occurrence of granular-textured titanite from ～2020 Ma granite basement rock exposed in the rim of the 4–5 Ma Roter Kamm impact structure in Namibia. Orientation mapping reveals two microstructurally distinct titanite populations: one consisting of strained/deformed grains, and the other consisting of grains that comprise aggregates of strain-free neoblasts. In situ U-Pb geochronology on 37 grains shows that most grains from both titanite populations yield indistinguishable U-Pb dates of ca. 1025 Ma, consistent with the observed microstructures forming during the Mesoproterozoic Namaqua Orogeny. Only four grains preserved older age domains, recording ca. 1875 Ma Paleoproterozoic metamorphism. Two significant observations emerge: (1) none of the analyzed titanite grains yield the 2020 Ma igneous crystallization age previously established from zircon in the same sample, and (2) no age-resetting was detected that could be attributed to the 4 to 5 Ma Roter Kamm impact event. Despite the similarity of the neoblastic microstructure to minerals from other sites with an established impact provenance, the granular texture and near-complete Pb-loss in titanite from Roter Kamm granite instead records a Paleo- to Mesoproterozoic polymetamorphic history, rather than Miocene age shock-related processes. These results highlight the critical importance of grain-scale context for interpretation of U-Pb data in granular titanite, and the potential for misinterpreting inherited (pre-impact) microstructures as impact-related phenomenon in target rocks with a complex geological history.     

电子背散射衍射技术(EBSD)在组构分析中的应用和相关问题

在过去的二十年里,EBSD (Electron Backscattered Diffraction),即电子背散射衍射测试技术,已广泛应用于韧性组构分析,成为变形运动学、流变学分析的常规手段。该方法主要应用于流变条件下矿物晶轴组构定向性分析,以判定流变剪切指向、对比应变强度、估算变形温度。理论上讲,EBSD法适用于所有矿物的全部晶轴定向的分析测试。然而鉴于天然变形的复杂性,笔者建议EBSD分析应以石英,特别是经历了动态重结晶的石英条带为组构分析的主要对象。长期以来,石英晶轴组构的不对称性被视作独立的剪切指向标志。然而,近年来基于天然变形和一般剪切实验的研究结果表明,塑性流变的剪切指向含义应为多重流变剪切指向标志综合判别比对的结果。尽管在提出之初,石英的轴组构开角被视作独立可靠的变形温度计(Kruhl,1998)。然而限于天然变形的复杂性,特别是对变质与变形阶段的对应、耦合的认识;尽管石英变形滑移系及石英晶轴组构开角可为动力变质温度提供重要的参考,但是石英晶轴组构开角并非独立的变形温度计。     

Characterisation of deformation and flow mechanics around porphyroclasts in a calcite marble ultramylonite by means of EBSD analysis

This paper studies the flow heterogeneity around porphyroclasts associated with greenschist facies deformation of a calcite marble shear zone. Microstructural data from electron backscatter diffraction analyses (EBSD) are used to constrain the flow mechanics of this dominantly non-coaxial type of deformation. The microstructure of the undisturbed ultramylonite (grain-size range 5–100 μm, mean 40 μm) is interpreted to represent steady-state (time-independent) flow conditions with flow planes parallel to the shear zone boundary. Single calcite porphyroclasts (grain-size 1–3 mm) caused flow perturbation in the fine-grained marble ultramylonite. It is the shape, in particular, of these rigid porphyroclasts that controls their rotational behaviour during deformation and, therefore, the development of specific flow fabrics. The flow planes around elongated-rhomboidal, stable porphyroclasts change the orientation to become roughly parallel to the porphyroclast margin, whereas the geometry of flow planes around nearly equant, rotating porphyroclasts describes a δ-type flow pattern. We infer that to some extent decoupling at the clast–matrix interface has occurred to guarantee a stable orientation of elongated porphyroclasts, but was not sufficient to reduce the rotation rate of equant clasts to zero. According to the flow deflection, the general crystallographic preferred orientation (CPO) with its single c-axis maximum perpendicular to the flow plane is rotated about an axis which is (sub)parallel to the kinematic rotation axis of the shear zone. Ultramylonite microstructures, CPOs and misorientation data are best explained by the dual operation of grain-size-insensitive (dislocation creep with recovery and recrystallization) and grain-size-sensitive (diffusion creep) mechanisms. The limited grain-size reduction around porphyroclasts suggests that the grain-size-insensitive mechanisms controlled rheology.     

Development of crystallographic preferred orientations by nucleation and growth of new grains in experimentally deformed quartz single crystals

Deformation experiments have been carried out to investigate the effect of dynamic recrystallisation on crystallographic preferred orientation (CPO) development. Cylindrical samples of natural single crystals of quartz were axially deformed together with 1 vol.% of added water and 20 mg of Mn₂O₃ powder in a Griggs solid medium deformation apparatus in different crystallographic orientations with compression direction: (i) parallel to <c>, (ii) at 45° to <c> and 45° to <a> and (iii) parallel to <a>. The experiments were performed at a temperature of 800 °C, a confining pressure of 1.2 GPa, a strain rate of  10^− 6 s^− 1, to bulk finite strains of  14–36%. The deformed samples were analysed in detail using optical microscopy, electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Two different microstructural domains were distinguished in the deformed samples: (i) domains with undulatory extinction and deformation lamellae, and (ii) domains with new recrystallised grains. Within the domains of undulatory extinction, crystal-plastic deformation caused gradual rotations of the crystal lattice up to  30° away from the host orientation. New recrystallised grains show a strong CPO with c-axis maxima at  45° to the compression direction. This is the case in all experiments, irrespective of the initial crystallographic orientation. The results show that c-axes are not continuously rotated towards the new maxima. The new grains thus developed through a mechanism different from subgrain rotation recrystallisation. New grains have a subeuhedral shape and numerous microcavities, voids, fluid channels and fluid inclusions at their grain boundaries. No host control is recorded in misorientation axes across their large angle grain boundaries. New grains might have been created by nucleation from solution in the μm-scale voids and microfractures. The CPO most likely developed due to preferred growth of the freshly precipitated grains with orientations suitable for intracrystalline deformation at the imposed experimental conditions.     

华北南缘古元古代末岩墙群侵位的磁组构证据

华北克拉通南缘的中条山及邻区广泛发育元古宙放射状基性岩墙群,与五台山-恒山和大同地区的北北西向基性岩墙群以及熊耳中条拗拉谷的火山岩在时空分布和地球化学方面均具有密切的相关性。中条山及邻区放射状基性岩墙群的宏观和微观流动构造(包括捕虏体、冲痕构造、矿物线理和定向斑晶)指示岩墙群以一定的仰角向北西侵位。通过该区岩墙群磁化率各向异性(AMS)测量得到磁组构的最大磁化率长轴优势方位分布图和磁组构各向异性特征分析进一步指示华北南缘古元古代末岩墙群从熊耳中条拗拉谷的底部向北西侵位。岩墙群的流动构造和磁组构的统计成果夯实了华北克拉通古元古代末基性岩墙群与熊耳中条拗拉谷的成生联系。     

湖北铜绿山矿床石英闪长岩的矿物学及Sr-Nd-Pb同位素特征

铜绿山是长江中下游鄂东南矿集区最重要的、大型夕卡岩型Cu-Fe(Au)矿床。本文对该矿区中与成矿密切的石英闪长岩进行了详细的矿物成分、地球化学及Sr-Nd-Pb同位素研究。结果表明:岩石中斜长石主要为更长石(An=21～31);角闪石贫Ti(0.2),高Mg/(Mg+Fe)(0.5),属于富镁角闪石;而黑云母为镁质黑云母。岩石的地球化学具有高硅(58.86%～67.71%),富碱(Na2O+K2O=5.67%～9.63%),富集轻稀土元素(LREE)和大离子亲石元素(LILE),并强亏损元素Nb、Ta、Ti等特征。岩石的(87Sr/86Sr)i为0.7055～0.7069,εNd(t)为-7.65～-3.44;(206Pb/204Pb)i=17.66～18.00,(207Pb/204Pb)i=15.49～15.56,(208Pb/204Pb)i=37.73～38.19。矿物成分、地球化学和同位素特征说明,铜绿山岩体与阳新岩体为同源岩浆的产物,源区为深度大于40km的富集地幔,经下地壳的混染及分离结晶作用形成。岩浆熔体形成的温度应大于889℃。角闪石和黑云母的温度计估算岩浆结晶温度分别为650～800℃和500～630℃,黑云母开始结晶温度略低于角闪石结晶结束温度,压力为1.49kbar,对应侵位深度约4.9km。岩浆具有利于Cu、Fe、Au等成矿元素进入熔体的条件,可能与板块俯冲作用相关。     

河南西南部典型白垩纪剖面的岩石磁组构特征及其构造意义

对河南西南部西峡盆地阳城-丹水上白垩统岩石磁学、磁组构的研究表明,该陆相沉积地层磁性矿物以及特征剩磁载体以赤铁矿为主,并含少量磁铁矿,且磁铁矿与赤铁矿相对含量比例随剖面由老到新显示出逐渐增加的趋势。岩石磁组构主要受顺磁性矿物以及反铁磁性矿物的控制。全剖面磁化率椭球结果显示在原生沉积组构基础上叠加了最早期阶段的弱变形组构;同时,全剖面以及各岩石地层单元磁化率椭球体主轴方向的变化揭示了两个不同方向及大小的构造挤压作用导致磁化率最大轴从NNW-SSE向转至NW-SE向,后又到NNW-SSE向的变化模式,一方面是由于华南、华北板块NE-SW向的构造挤压导致;另一方面是由两板块构造挤压而引起的桐柏-大别造山带上地壳物质相对下地壳发生东向构造逃逸和挤出过程中与东部块体物质间发生的挤压作用引起,这两种不同的挤压应力作用在盆地发展的不同阶段各占主要地位。     

迁安铁矿变形岩石的EBSD组构分析

迁安铁矿是我国大型沉积变质型铁矿之一,该矿区含矿变质岩系为前寒武纪老变质岩石,时代老,变质程度深,现存岩石的内部矿物发生过多次变形、变质和重结晶等变化,宏观上表现为该区岩石矿物组构的复杂性。为了更深入、清晰地了解该区变形岩石的组构,采用电子背散射衍射(EBSD)技术对该区岩石样品做了分析,通过EBSD系统的配套软件(HKL公司开发的Channel 5),对采集数据进行处理绘制成相应磁铁矿和石英的极图,经分析后重点总结出变形岩石内部石英的组构特点,由此进一步反映出本区构造变形时主要为中温-中高温的变形温度环境,少量组构图反映叠加了中低温变形。     

Fluid inclusion characteristics of hematite-bearing quartz vein from the Daenam mine, Republic of Korea

The Daenam mine, which produced over 9250 tons of iron oxide ore from 1958 to 1962, is situated in the Early Cretaceous Yeongyang subbasin of the Gyeongsang basin. It consists of two lens-shaped, hematite-bearing quartz veins that occur along faults in Cretaceous leucocratic granite. The hematite-bearing quartz veins are mainly composed of massive and euhedral quartz and hematite with minor amounts of pyrite, pyrrhotite, mica, feldspar and chlorite.Fluid inclusions in quartz can be divided into three main types: CO₂-rich, CO₂–H₂O, and H₂O-rich. Hydrothermal fluids related to the formation of hematite are composed of either H₂O–CO₂–NaCl ± CH₄ (homogenization temperature: 262–455 °C, salinity <7 eq. wt.% NaCl) or H₂O–NaCl (homogenization temperature: 182–266 °C, and salinity <5.1 eq. wt.% NaCl), both of which evolved by mixing with deeply circulating meteoric water. Hematite from the quartz veins in the Daenam mine was mainly deposited by unmixing of H₂O–CO₂–NaCl ± CH₄ fluids with loss of the CO₂ + CH₄ vapor phase and mixing with downward percolating meteoric water providing oxidizing conditions.