High resolution OSL and post-IR IRSL dating of the last interglacial–glacial cycle at the Sanbahuo loess site (northeastern China)

Northeastern China is located in the East Asian monsoon region; it is sensitive to both high and low latitude global climate systems. Loess deposits in the region have considerable potential as sensitive archives of past climate changes. However, research into loess deposition and climate change in this region is restricted by the lack of independent age control. In this study, coarse-grained quartz SAR OSL and K-feldspar post-IR infrared (IR) stimulated luminescence (post-IR IRSL; pIRIR₂₉₀) methods have been used to date the Sanbahuo loess site in northeastern China. The quartz OSL characteristics are satisfactory. The measured pIRIR₂₉₀ D_e's do not vary significantly with IR stimulation temperatures between 50 °C and 260 °C; a first IR stimulation temperature of 200 °C was adopted. Dose recovery tests were performed by adding different laboratory doses to both laboratory bleached (300 h SOL2) samples and natural samples; the results are satisfactory up to ∼800 Gy. Resulting quartz OSL and feldspar pIRIR₂₉₀ ages are in good agreement at least back to ∼44 ka; beyond this feldspar pIRIR₂₉₀ ages are older. The feldspar ages are consistent with the expected age of the S1 palaeosol (MIS 5). There appears to have been a period of fast loess deposition at ∼62 ka, perhaps indicative of winter monsoon intensification with a very cold and dry climate that lead to a serious desertification of dunefields in northeastern China.     

北美五大湖区晚更新世劳伦泰德冰盖演化年代学综述及石英光释光测年的初步尝试

北美五大湖区的安大略湖北岸Don Valley Brickyard、Scarborough Bluffs、Bowmanville Bluffs剖面共同构成了北美东北部最长也是最厚的陆地第四纪沉积记录, 较完整地记录了晚更新世劳伦泰德冰盖(the Laurentide Ice Sheet)的演化. 晚更新世劳伦泰德冰盖演化的重建有赖于这些经典剖面中重要沉积地层单元的准确年代学控制. 传统的地层年代学主要是依靠少量¹⁴C年代, 将主要的混杂堆积单元(diamicton)解释为气候变冷环境下的冰川扩张, 并与指示全球冰量变化的深海氧同位素曲线一一比对建立起来的. 这样建立起来的年代学存在很大的不确定性. 20世纪80-90年代的少量热释光年代也不相吻合, 最近的13个长石红外释光定年则只集中于Bowmanville Bluffs的一个分层, 并未建立整个剖面的地层年代学, 使这些经典沉积剖面的年代学一直没有得到系统的建立. 应用石英光释光SAR-SGC法测试了Bowmanville Bluffs剖面Glaciofluvial Sand单元的2个冰水沉积样品, 年代结果分别为(41.6±3.8) ka、(48.1±4.4) ka, 分析表明这一年代结果偏老, 石英颗粒可能晒褪不完全. 由于大测片无法识别晒褪不完全的颗粒, 因此, 测试更多的剖面序列的光释光年代并尝试采用粗颗粒小测片或单颗粒技术解决样品颗粒晒褪不完全的问题将是必要的.     

Actively forming Kuroko-type volcanic-hosted massive sulfide (VHMS) mineralization at Iheya North,Okinawa Trough,Japan

Modern seafloor hydrothermal systems provide important insights into the formation and discovery of ancient volcanic-hosted massive sulfide (VHMS) deposits. In 2010, Integrated Ocean Drilling Program (IODP) Expedition 331 drilled five sites in the Iheya North hydrothermal field in the middle Okinawa Trough back-arc basin, Japan. Hydrothermal alteration and sulfide mineralization is hosted in a geologically complex, mixed sequence of coarse pumiceous volcaniclastic and fine hemipelagic sediments, overlying a dacitic to rhyolitic volcanic substrate. At site C0016, located adjacent to the foot of the actively venting North Big Chimney massive sulfide mound, massive sphalerite-(pyrite-chalcopyrite ± galena)-rich sulfides were intersected (to 30.2% Zn, 12.3% Pb, 2.68% Cu, 33.1 ppm Ag and 0.07 ppm Au) that strongly resemble the black ore of the Miocene-age Kuroko deposits of Japan. Sulfide mineralization shows clear evidence of formation through a combination of surface detrital and subsurface chemical processes, with at least some sphalerite precipitating into void space in the rock. Volcanic rocks beneath massive sulfides exhibit quartz-muscovite/illite and quartz-Mg-chlorite alteration reminiscent of VHMS proximal footwall alteration associated with Kuroko-type deposits, characterized by increasing MgO, Fe/Zn and Cu/Zn with depth. Recovered felsic footwall rocks are of FII to FIII affinity with well-developed negative Eu anomalies, consistent with VHMS-hosting felsic rocks in Phanerozoic ensialic arc/back-arc settings worldwide.Site C0013, ∼100 m east of North Big Chimney, represents a likely location of recent high temperature discharge, preserved as surficial coarse-grained sulfidic sediments (43.2% Zn, 4.4% Pb, 5.4% Cu, 42 ppm Ag and 0.02 ppm Au) containing high concentrations of As, Cd, Mo, Sb, and W. Near surface hydrothermal alteration is dominated by kaolinite and muscovite with locally abundant native sulfur, indicative of acidic hydrothermal fluids. Alteration grades to Mg-chlorite dominated assemblages at depths of >5 mbsf (metres below sea floor). Late coarse-grained anhydrite veining overprints earlier alteration and is interpreted to have precipitated from down welling seawater as hydrothermal activity waned. At site C0014, ∼350 m farther east, hydrothermal assemblages are characterized by illite/montmorillonite, with Mg-chlorite present at depths below ∼30 mbsf. Recovered lithologies from distal, recharge site C0017 are unaltered, with low MgO, Fe₂O₃ and base metal concentrations.Mineralization and alteration assemblages are consistent with the Iheya North system representing a modern analogue for Kuroko-type VHMS mineralization. Fluid flow is focussed laterally along pumiceous volcaniclastic strata (compartmentalized between impermeable hemipelagic sediments), and vertically along faults. The abundance of Fe-poor sphalerite and Mg-rich chlorite (clinochlore/penninite) is consistent with the lower Fe budget, temperature and higher oxidation state of felsic volcanic-hosted hydrothermal systems worldwide compared to Mid Ocean Ridge black smoker systems.     

湖北狮子立山锶(铅锌)矿区石英闪长玢岩锆石SHRIMP U-Pb定年及其意义

湖北狮子立山锶(铅锌)矿床是我国重要的超大型锶矿床之一,产出于鄂东矿集区北部铁山岩体东缘的狮子立山岩体(主要为石英闪长玢岩)与三叠纪蒸发岩地层(嘉陵江组)的接触带或附近。本文对矿区内的石英闪长玢岩与成矿作用之间的关系和该岩体的年代学开展了详细的研究工作。结果表明,狮子立山岩体与锶矿成矿作用可能存在密切的联系,矿床中的部分Sr可能来自于石英闪长玢岩的强烈蚀变。锆石SHRIMP U-Pb的定年工作得到2个石英闪长玢岩样品的形成时代分别为138.6±0.8Ma和138.9±1.2Ma,二者在误差范围内基本一致,这些数据与前人获得的铁山岩体的成岩时代基本一致,暗示本次测得的石英闪长玢岩的样品年龄可靠性较高,且很可能与铁山岩体是同一地质背景下的产物,即形成于区域晚侏罗-早白垩世岩石圈由挤压到伸展的转换环境。狮子立山岩体的侵位地层及矿床中硫同位素组成的特征与程潮和金山店矽卡岩型铁矿具有明显的相似性,暗示在狮子立山矿床附近具有寻找矽卡岩型铁矿床的潜力。     

Optical Dating Equivalent Dose (De) Comparison of Global Standardised Growth Curve (gSGC) and Single-aliquot Regenerative-dose (SAR) Methods for Quartz Grains

Optical dating is a method of measuring the time since the sample was buried from last thermal event or light exposure. Samples such as quartz and feldspar grains are the most commonly used sediment of measurement. Single-Aliquot Regenerative-dose (SAR) method has become the most acceptable procedure for obtaining the equivalent Dose (D_e) of a sample. The Standardised Growth Curve (SGC) method provides a possible procedure for measuring a large number of samples; the limitation is that the growth curve fitted by different samples or even different aliquots is divergent. The global Standardised Growth Curve (gSGC) method improves the shortage by normalizing the dose response curves using one regenerative dose OSL signal. The gSGC provides a possible method for obtaining the D_e value of the sample efficiently and quickly. However, due to the radiation dose rate, operating procedures and instrument error and the selected regenerative-dose normalized dose value, etc., each laboratory should develop their own gSGC which has unique parameters. This study established the gSGC curve and measurement process of our laboratory, and then compared the consistency of the equivalent Dose (D_e) values from gSGC and SAR methods. In gSGC procedure, the D_e value of an aliquot can be estimated from the nature signal, one regenerative dose signal and their corresponding test dose signal. It will speed up the optical dating measurement rate of our laboratory and provide reference to establish gSGC in other laboratories. It is found that in the low dose range (0~100 Gy) the obtained D_e values were well consistent by gSGC and SAR methods. There were obviously differences in the higher dose range (>100 Gy) compared to the SAR results. It may be due to the insufficient number of older samples used to fit gSGC in this study. It is necessary to gradually accumulate more samples to improve the gSGC parameters in the future work. For some aliquots, individual quartz grains do not follow the global standardised growth curve, which leads to some deviations of D_e from gSGC. However, these two methods could obtain the similar average De value when multiple aliquots measuring.     

云南维西格坡洛斑岩型锑矿矿床成因

锑矿化集中于喜马拉雅期石英斑岩内接触带,存在矿源层形成、充分分异及近地表成矿三个阶段。可作为滇西碱性岩锡矿床典型。     

Two-stage collision-related extrusion of the western Dabie HP–UHP metamorphic terranes, central China: Evidence from quartz c-axis fabrics and structures

The western Dabie orogen (also known as the Hong'an block) forms the western part of the Dabie–Sulu HP–UHP belt, central China. Rocks of this orogen have been subjected to pervasive ductile deformation, and include numerous quartz schists and felsic mylonites cropping out in ductile shear zones. Quartz textures in these mylonites contain important clues for understanding the movement sense of late-collisional extrusion and exhumation of high-pressure–ultrahigh-pressure (HP–UHP) rocks from the lower crustal level to the upper crustal level during Middle Triassic and Early Jurassic. The orientation and distribution of quartz crystallographic axes were used to confirm the regional shear sense across the orogen. The asymmetry of c-axis patterns consistently indicates top-to-the-southeast thrusting across the orogen in early structural stages. Later stages of deformation show different senses of movement in northern and southern parts of the orogen, with top-to-the-northwest sinistral shearing recorded in rocks north of the Xinxian HP–UHP eclogite-facies belt, and top-to-the-southeast dextral shearing south of the same unit.Based on our study on quartz c-axis fabrics and marco- to micro-scale structures, simultaneous southeastward shearing within a large part of the orogen and normal faulting north of the Xinxian HP–UHP unit is explained by upward extrusion in early stages of deformation. The extrusion process has been attributed to syn- and late-collisional processes, accounting for some earlier deformation in the western Dabie orogen such as metamorphic sequences around the core of the Xinxian HP–UHP eclogite-facies unit. Much higher pressure of deformation is also indicated in the aligned glaucophane and omphacite from blueschist and eclogite in the field. An orogen-parallel eastward extrusion of the Xinxian HP–UHP eclogite-facies unit, however, occurred diachronously in later stages of deformation. Therefore, a tectonic model combining an early upward extrusion with a later eastward extrusion is presented. Two different stages and types of extrusion for exhumation of HP–UHP rocks are suitable to all of east central China. Geochronological data shows that the first, upward extrusion occurred during Middle Triassic, the second, eastward extrusion occurred during Late Triassic to Early Jurassic. These two extrusions are correlative with two stages of rapid exhumation of the Dabie HP–UHP rocks, respectively. These two-stage late-collisional (Middle Triassic to Early Jurassic) extrusion events bridge the gap between syn-collisional (Early to Middle Triassic) vertical extrusion and post-collisional (Cretaceous) eastward-directed lateral escape and provide vital clues to understanding the more detailed processes of exhumation of HP–UHP rocks.     

On natural and laboratory generated dose response curves for quartz of different grain sizes from Romanian loess

One of the most important foundations of luminescence dating is the assumption that the growth of the luminescence signal in nature can be reproduced under laboratory conditions by performing irradiations with a calibrated beta or gamma source. When optically stimulated luminescence (OSL) of quartz with a dominant fast component is measured using the single aliquot regenerative dose (SAR) protocol, laboratory dose response curves that display continuing growth at high doses are increasingly reported in literature. In this study we investigate fine (4–11 μm) and coarse (63–90 μm) quartz extracted from 25 samples taken from L1, S1 and L2 units from the loess-palaeosol section at Costineşti in Romania. Our results indicate that the growth of the OSL signal in nature does not correspond to the laboratory generated laboratory dose response curve. The growth of the signal in nature is consistent with a single saturating exponential function, with the signal of coarse grains starting to saturate at 100–200 Gy, and for fine grains at 200–300 Gy, respectively. Laboratory dose response curves continue to grow for high doses (>300 Gy) for both quartz fractions. The differences observed between the natural and the laboratory dose response for the two quartz fractions are believed to be a cause for the different chronologies previously reported using the two grain sizes of quartz on Romanian loess. In addition, we have applied the single aliquot regeneration and added dose (SARA) procedure to both fine and coarse grains from the youngest sample. Our findings question the reliability of obtaining high equivalent doses for quartz samples displaying laboratory dose response curves obtained by the SAR protocol for which a single saturating exponential model does not describe the data.     

The chemical composition including the Rare Earth Elements of the three major glass types of Europe and the Orient used in late antiquity and the Middle Ages

Sets of 20 soda ash glasses, 16 soda lime glasses and 23 wood ash glasses mainly from excavations in Europe (additional soda ash glasses from Egypt) were analysed on 61 chemical elements. Average SiO₂ is about 62% in soda glasses and 50% in wood ash glasses. The three groups of glasses contain on average 13% Na₂O, 18% Na₂O and 13% K₂O as fluxes to lower the melting temperature of quartz at their production. The starting materials beside quartz were halophytic plant ash for soda ash glass, trona (Na₃H(CO₃)₂·2H₂O) and lime (clamshells) for soda lime glass and beech ash for wood ash glass. Each of the three major glass types contains specific Rare Earth Element (REE) concentrations mainly contained in quartz and its intergrown minerals. 50 Paleozoic and Mesozoic sandstones from Central Europe represent the quartz composition. The REE pattern of these glasses apparently indicates major compositional stages of the Continental Earth's Crust. The boron to lithium and sodium to potassium ratios as in seawater suggest reactions of materials for soda glass with seawater. Negative Ce anomalies in the three glasses are caused by reactions of quartz with seawater.