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L. P. Plyusnina G. G. Likhoidov V. P. Molchanov Zh. A. Shcheka 《Russian Journal of Pacific Geology》2007,1(5):464-472
Gold mass transfer with chloride and carbonate-chloride solutions was examined at the 300 and 400°C isotherms and P tot = 1 kbar by means of experimental modeling and theoretical simulations. CO2 was confirmed to suppress Au solubility in fluids. The low Au solubility (mAu < 10?8) determined in the experiments explains the mechanism of its precipitation when serpentinites and listwanites interact with acidic mineralized solutions. Listwanitization, which was genetically related with the emplacement of orogenic granitoids, was determined to have overprinted serpentinites and rodingites and strongly affected Au transport in the oregeochemical system. The characteristics of the metasomatic processes in the Ust’-Dep ophiolites and the gold concentration in the rocks produced by these processes confirm this conclusion. 相似文献
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Diogenes Scipioni Vial Ed DeWitt Lydia Maria Lobato Charles H. Thorman 《Ore Geology Reviews》2007,32(3-4):511
The Morro Velho gold deposit, Quadrilátero Ferrífero region, Minas Gerais, Brazil, is hosted by rocks at the base of the Archean Rio das Velhas greenstone belt. The deposit occurs within a thick carbonaceous phyllite package, containing intercalations of felsic and intermediate volcaniclastic rocks and dolomites. Considering the temporal and spatial association of the deposit with the Rio das Velhas orogeny, and location in close proximity to a major NNW-trending fault zone, it can be classified as an orogenic gold deposit. Hydrothermal activity was characterized by intense enrichment in alteration zones of carbonates, sulfides, chlorite, white mica±biotite, albite and quartz, as described in other Archean lode-type gold ores. Two types of ore occur in the deposit: dark gray quartz veins and sulfide-rich gold orebodies. The sulfide-rich orebodies range from disseminated concentrations of sulfide minerals to massive sulfide bodies. The sulfide assemblage comprises (by volume), on average, 74% pyrrhotite, 17% arsenopyrite, 8% pyrite and 1% chalcopyrite. The orebodies have a long axis parallel to the local stretching lineation, with continuity down the plunge of fold axis for at least 4.8 km. The group of rocks hosting the Morro Velho gold mineralization is locally referred to as lapa seca. These were isoclinally folded and metamorphosed prior to gold mineralization. The lapa seca and the orebodies it hosts are distributed in five main tight folds related to F1 (the best examples are the X, Main and South orebodies, in level 25), which are disrupted by NE- to E-striking shear zones. Textural features indicate that the sulfide mineralization postdated regional peak metamorphism, and that the massive sulfide ore has subsequently been neither metamorphosed nor deformed. Lead isotope ratios indicate a model age of 2.82 ± 0.05 Ga for both sulfide and gold mineralization. The lapa seca are interpreted as the results of a pre-gold alteration process and may be divided into carbonatic, micaceous and quartzose types. The carbonatic lapa seca is subdivided into gray and brown subtypes. Non-mineralized, gray carbonatic lapa seca forms the hanging wall to the orebodies, and is interpreted as the product of extreme CO2 metasomatism during hydrothermal alteration. This dolomitic lapa seca ranges in composition from relatively pure limestone and dolomite to silty limestone and dolomite. The brown carbonatic and micaceous lapa secas are the host rocks to gold. These units are interpreted to correspond to the sheared and hydrothermal products of metamorphosed volcaniclastic and/or volcanic rocks of varying composition from dacitic to andesitic, forming various types of schists and phyllites. The high-grade, massive sulfide orebodies occur at the base of the gray carbonatic lapa seca. Both disseminated mineralization and quartz veins are hosted by micaceous lapa seca. The data are consistent with a model of epigenetic mineralization for the lapa seca, from a hydrothermal fluid derived in part from the Archean basement or older crust material. 相似文献
486.
新疆西天山阿希金矿床流体包裹体地球化学特征 总被引:3,自引:1,他引:3
本文在系统总结前人关于矿床地质特征和流体成矿作用研究成果的基础上,补充开展了热液成矿期石英-碳酸盐阶段石英、方解石和重晶石中流体包裹体的均一法和冷冻法测温,并对石英样品进行了气相色谱测量,对石英流体包裹体中的稀土和微量元素进行了测试。结果表明,矿床具有典型的浅成低温热液金矿的特点,成矿流体总体上盐度很低,多数都集中于0.53~1.57wt%NaCl。成矿流体的主要成分为H_2O、CO_2和CH_4。流体包裹体微量元素与容矿围岩具有继承性,流体中Cu、Ni、Co、Mo、Zn、Pb、V、Sb和Li等的含量较高,可能说明了Cu、Zn、Co、Ni、Bi和Ba等元素在水岩反应过程中更容易进入流体当中。石英流体包裹体中∑REE为13825×10~(-12)~149935×10~(-12),LREE/HREE为2.63~50.83,δEu为0.70~0.91,表现为Eu的弱亏损。成矿流体的REE配分型式与火山岩具有相同的Eu亏损和右倾配分曲线,表明成矿流体在演化过程中可能继承了早期火山岩的REE特征;但成矿流体的LREE/HREE值比火山岩大,前者的REE配分曲线比后者更加右陡倾斜,这可能与后期变质水和大气降水的混入引起的成矿流体物质组分发生有关。 相似文献
487.
Geology and Metallogenesis of the Sawayaerdun Gold Deposit in the Southwestern Tianshan Mountains, Xinjiang, China 总被引:2,自引:0,他引:2
Fuquan Yang Jingwen Mao Yitian Wang Frank P. Bierlein Huishou Ye Mengwen Li Caisheng Zhao Jinhua Ye 《Resource Geology》2007,57(1):57-75
The Sawayaerdun gold deposit, located in Wuqia County, Southwest Tianshan, China, occurs in Upper Silurian and Lower Devonian low‐grade metamorphic carbonaceous turbidites. The orebodies are controlled by a series of NE‐NNE‐trending, brittle–ductile shear zones. Twenty‐four gold mineralized zones have been recognized in the Sawayaerdun ore deposit. Among these, the up to 4‐km‐long and 200‐m wide No. IV mineralized zone is economically the most important. The average gold grade is 1–6 g/t. Gold reserves of the Sawayaerdun deposit have been identified at approximately 37 tonnes and an inferred resource of 123 tonnes. Hydrothermal alteration is characterized by silicification, pyritization, arsenopyritization, sericitization, carbonatization and chloritization. On the basis of field evidence and petrographic analysis, five stages of vein emplacement and hydrothermal mineralization can be distinguished: stage 1, early quartz stage, characterized by the occurrence of quartz veins; stage 2, arsenopyrite–pyrite–quartz stage, characterized by the formation of auriferous quartz veinlets and stockworks; stage 3, polymetallic sulfide quartz stage, characterized by the presence of auriferous polymetallic sulfide quartz veinlets and stockworks; stage 4, antimony–quartz stage, characterized by the formation of stibnite–jamesonite quartz veins; and stage 5, quartz–carbonate vein stage. Stages 2 and 3 represent the main gold mineralization, with stage 4 representing a major antimony mineralization episode in the Sawayaerdun deposit. Two types of fluid inclusion, namely H2O–NaCl and H2O–CO2–NaCl types, have been recognized in quartz and calcite. Aqueous inclusions show a wide range of homogenization temperatures from 125 to 340°C, and can be correlated with the mineralization stage during which the inclusions formed. Similarly, salinities and densities of these fluids range for each stage of mineralization from 2.57 to 22 equivalent wt% NaCl and 0.76 to 1.05 g/cm3, respectively. The ore‐forming fluids thus are representative of a medium‐ to low‐temperature, low‐ to medium‐salinity H2O–NaCl–CO2–CH4–N2 system. The δ34SCDT values of sulfides associated with mineralization fall into a narrow range of ?3.0 to +2.6‰ with a mean of +0.1‰. The δ13CPDB values of dolomite and siderite from the Sawayaerdun gold deposit range from ?5.4 to ?0.6‰, possibly reflecting derivation of the carbonate carbon from a mixed magmatic/sedimentary source. Changes in physico‐chemical conditions and composition of the hydrothermal fluids, water–rock exchange and immiscibility of hydrothermal fluids are inferred to have played important roles in the ore‐forming process of the Sawayaerdun gold–antimony deposit. 相似文献
488.
The Qolqoleh gold deposit is located in the northwestern part of the Sanandai‐Sirjan Zone, northwest of Iran. Gold mineralization in the Qolqoleh deposit is almost entirely confined to a series of steeply dipping ductile–brittle shear zones generated during Late Cretaceous–Tertiary continental collision between the Afro‐Arabian and the Iranian microcontinent. The host rocks are Mesozoic volcano‐sedimentary sequences consisting of felsic to mafic metavolcanics, which are metamorphosed to greenschist facies, sericite and chlorite schists. The gold orebodies were found within strong ductile deformation to late brittle deformation. Ore‐controlling structure is NE–SW‐trending oblique thrust with vergence toward south ductile–brittle shear zone. The highly strained host rocks show a combination of mylonitic and cataclastic microstructures, including crystal–plastic deformation and grain size reduction by recrystalization of quartz and mica. The gold orebodies are composed of Au‐bearing highly deformed and altered mylonitic host rocks and cross‐cutting Au‐ and sulfide‐bearing quartz veins. Approximately half of the mineralization is in the form of dissemination in the mylonite and the remainder was clearly emplaced as a result of brittle deformation in quartz–sulfide microfractures, microveins and veins. Only low volumes of gold concentration was introduced during ductile deformation, whereas, during the evident brittle deformation phase, competence contrasts allowed fracturing to focus on the quartz–sericite domain boundaries of the mylonitic foliation, thus permitting the introduction of auriferous fluid to create disseminated and cross‐cutting Au‐quartz veins. According to mineral assemblages and alteration intensity, hydrothermal alteration could be divided into three zones: silicification and sulfidation zone (major ore body); sericite and carbonate alteration zone; and sericite–chlorite alteration zone that may be taken to imply wall‐rock interaction with near neutral fluids (pH 5–6). Silicified and sulfide alteration zone is observed in the inner parts of alteration zones. High gold grades belong to silicified highly deformed mylonitic and ultramylonitic domains and silicified sulfide‐bearing microveins. Based on paragenetic relationships, three main stages of mineralization are recognized in the Qolqoleh gold deposit. Stage I encompasses deposition of large volumes of milky quartz and pyrite. Stage II includes gray and buck quartz, pyrite and minor calcite, sphalerite, subordinate chalcopyrite and gold ores. Stage III consists of comb quartz and calcite, magnetite, sphalerite, chalcopyrite, arsenopyrite, pyrrhotite and gold ores. Studies on regional geology, ore geology and ore‐forming stages have proved that the Qolqoleh deposit was formed in the compression–extension stage during the Late Cretaceous–Tertiary continental collision in a ductile–brittle shear zone, and is characterized by orogenic gold deposits. 相似文献
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玲珑金矿作为胶东地区一个规模最大且最典型的石英脉型金矿,历经多年的开采,其保有储量已不足以支持持续生产,深部及边部找矿迫在眉睫。本文基于成因矿物学理论,通过矿物地球化学方法对矿区内的黄铁矿化学成分标型特征研究,结果表明:1)胶东玲珑金矿中黄铁矿为亏硫型,根据其N(S)/N(Fe)值变化趋势,显示其形成温度由成矿前期至成矿期最后到成矿后期逐渐降低。2)胶东玲珑金矿中黄铁矿为富As特征,可作为找矿标志之一;Fe、Cu、Pb三种元素整体上呈迁入状态,随着流体的进一步运移,热液中的HS-等组分逐渐流失,进而导致Au(HS)2-络合物失稳而分解,Fe2+、Fe3+被消耗形成黄铁矿,与此同时Au开始逐渐聚集并沉淀。3)黄铁矿的NiCo图解及As-Co-Ni三角相图显示,绝大部分黄铁矿都属于岩浆热液成因,黄铁矿w(Co)/w(Ni)均值为2.79,说明Au沉淀时的温度为中温。综上并结合区域地质、矿区地质特征及蚀变带特征,认为玲珑金矿床为"岩浆核杂岩"隆起-拆离带中的岩浆期后热液矿床。上述研究成果对玲珑金矿下一步的深部及边部找矿具一定的参考价值。 相似文献