Seasonal variation in nature and chemical compositions of spring water in Cuihua Mountain,Shaanxi Province,central China

Two springs (Cuihua Spring, Shuiqiuchi Spring) in Cuihua Mountain of the Qinling Mountains were observed and sampled monthly during 2004 and 2005 to trace their physical properties and chemical compositions with seasons. Although both pH values and cation (Ca²⁺, Mg²⁺, K⁺, and Na⁺) contents of Cuihua Spring are higher than those of Shuiqiuchi Spring, seasonal variations in both springs are obvious. The pH values of both spring waters are between 5.69 and 6.98, lower than that of rainwater during summer and autumn. From January to November, the pH values of both springs similarly vary from high to low and then to high again. Variations in electric conductivities of two spring waters are contrary, although their electric conductivities are positively correlative with the cation content respectively. This can be attributed to different water sources of the two springs or different acidic rocks they passed. The contents of HCO₃ ⁻, Ca²⁺, Mg²⁺, K⁺, and Na⁺ are low, indicating a low silicate weathering that the strata in this district are mainly composed of granite and schist of quartz and mica. Differing from change in spring water in karst regions of South China where abundant precipitation and dilution of rainwater cause low pH and electric conductivity in summer and autumn, the seasonal variations in the pH values and the electric conductivities of two springs in Qinling Mountains are attributed to seasonal changes in CO₂ produced by microorganisms’ activity in soil within respective year, rather than rainfall. The microorganisms’ activity in soil produces more CO₂ during summer and autumn. Therefore, the water nature of springs in silicate regions chiefly reflects the seasonal changes of CO₂ produced by the microorganisms in soil.     

黄龙铺钼矿田含矿碳酸岩地球化学特征及其形成构造背景

陕西黄龙铺钼矿田是东秦岭钼矿带中成矿类型最为独特的矿床,多数矿体产于晚三叠纪（220Ma）的碳酸岩岩脉内。其中,石家湾Ⅱ号矿体碳酸岩的Sr和REE含量异常高,δ¹³C_PDB为 -6.75‰~ -6.92‰,δ¹⁸O_SMOWO为8.69‰~9.48‰,显示典型的火成碳酸岩的特征。在世界范围内,碳酸岩来自地幔低程度部分熔融或交代作用,稀土配分模式为陡倾斜的轻稀土富集型,但石家湾碳酸岩HREE含量异常高,稀土配分模式平坦,不同于世界其它地区的碳酸岩,这要求源区必须相对亏损LREE,相对富集HREE。显然,如此源区与俯冲洋壳部分熔融之后的残留相榴辉岩的特征一致。因此,我们认为,勉略洋壳在三叠纪向北俯冲至秦岭-华北联合陆块之下,通过变质脱水熔融而形成岩浆弧,随后,在弧后扩张带发生残余榴辉岩的低程度部分熔融或交代而形成碳酸岩岩浆,导致黄龙铺矿田形成。如此以来,秦岭地区在220Ma左右仍有B型俯冲作用,碰撞造山作用并没有结束。     

大兴安岭原始森林覆盖区化探异常查证方法研究与实践

文章综述了原始森林覆盖区勘查技术方法研究历史、现状及意义.通过对区内某1:20万化探异常进行追踪、查证方法的实验性研究,初步确定适合原始森林覆盖区的物探方法和化探方法.对具有成矿远景的1:20万异常的查证方法、过程为:①1:5万网格法水系沉积物或1:5万土壤测量;②配合以适量的1:1万或1:2万剖面土壤测量,最终达到分解异常、缩小找矿靶区的目的;③1:1万～1:2万地质简测,结合地表工程确定是否为矿致异常,初步确定矿化类型;④选用高精度磁测、双频激电测量方法进行1:2.5万或1:1万的面积性物探测量;⑤运用槽探、坑探、浅井及钻探等探矿手段寻找工业矿体.对二根河、洛古河、阿南林场3个1:20万异常查证证明该方法是适宜森林覆盖景观区的快捷且行之有效的异常查证方法.     

循化-化隆盆地晚白垩世以来盆山耦合过程: 来自物源与磷灰石裂变径迹年代学分析的证据

循化-化隆盆地新生代沉积及盆地基底和周缘山系磷灰石裂变径迹年代学分析揭示了青藏高原东北缘晚白垩世以来经历过3期隆升剥露事件: (1)盆地基底及拉脊山和西秦岭北缘构造带磷灰石裂变径迹年龄分析普遍记录了晚白垩世-始新世中期相对快速的区域性的隆升剥露事件, 西秦岭北缘快速抬升的起始时间为84Ma, 受控于向北的逆冲抬升; 向北到循化-化隆盆地中部的拉目峡抬升的起始时间为69Ma; 更北的拉脊山一带快速抬升期主要为40~50Ma, 从而反映晚白垩世-始新世中期的快速抬升由南向北逐渐扩展.这一期构造隆升事件导致循化-化隆盆地和临夏盆地缺失了北部西宁-民和盆地古近纪所具有的西宁群沉积.隆升剥露结束于31Ma左右, 此时化隆-循化盆地向东与同时期的临夏盆地相连为一个统一的大型西秦岭山前盆地, 两者具有相同的构造、沉积演化史, 因此循化-化隆盆地他拉组底部地层年龄最老不会超过临夏盆地最老地层的古地磁年龄, 即29Ma.(2)渐新世晚期约26Ma拉脊山开始双向逆冲隆升, 并可能延续到中新世早期约21Ma, 隆升作用使循化-化隆盆地成为挟持于拉脊山逆冲带和西秦岭构造带之间的山前挤压型前陆盆地, 循化-化隆盆地开始大规模沉积巨厚的他拉组冲积扇相粗碎屑岩.(3)通过循化-化隆盆地咸水河组和临夏组的沉积相分析、古流方向和砾石成分分析, 揭示出拉脊山构造带在中新世8Ma左右发生的最大规模的双向逆冲隆升事件, 这次事件直接导致循化-化隆盆地由前陆挤压盆地转变为山间盆地, 形成现今青藏高原东北缘的盆山地貌基本格局.      

西秦岭北缘断裂带西端晚第四纪活动特征及其西延问题

西秦岭北缘断裂是青藏高原东北缘的一条以左旋走滑运动为主的大型活动断裂。 通过卫片解译和野外地质调查, 认为断裂西端活动性仍很强烈, 并发现切龙沟一带全新世活动特征明显。 结果表明, 全新世以来西秦岭北缘断裂西端至少有2次古地震事件, 说明断裂经过土房村以后活动并没有停止, 而是继续向西延伸, 最后终止于甘加盆地。     

南秦岭旬阳盆地东部晚泥盆世岩浆成因钠长岩及其构造意义

南秦岭旬阳盆地的钠长岩此前被认为是热水沉积或热液交代作用的产物。本文对南秦岭旬阳盆地东端黄石板地区侵入于下志留统梅子亚组浅变质岩中的钠长岩体进行了地球化学和锆石U-Pb LA-ICP-MS年代学研究,结果表明钠长岩具有富钠贫钾、铝不饱和、亏损大离子亲石元素K和Rb、高场强元素(Nb、Ta、Th、Hf)显著富集的地球化学特点,主体属于钙碱性系列岩石,反映幔源成因的特征。钠长岩中获得最年轻的锆石U-Pb年龄为364~376Ma,该年龄代表岩体的形成年龄,反映晚泥盆世时南秦岭旬阳盆地处于强烈的伸展构造环境。此项研究结果表明,在旬阳盆地的志留系中,岩浆成因与热水沉积成因的钠长岩可能是共存的。黄石板岩浆成因钠长岩岩体中含有大量前寒武纪和早古生代的捕获锆石,在捕获锆石中测得迄今为止在研究区及其邻区获得的最古老的锆石U-Pb年龄(3291Ma)。这些捕获锆石的测年数据说明,研究区所在的南秦岭地区可能从古太古代开始就与扬子地块具有明显的亲缘性。     

Petrogenesis and geodynamic setting of the Triassic granitoid plutons in West Qinling,China: insights from LA-ICP-MS zircon U–Pb ages,Lu–Hf isotope signatures and geochemical characteristics of the Zhongchuan pluton

West Qinling is one of the most important parts of the Qinling orogenic belt and includes acidic–intermediate plutons and many types of ore deposits. In this article, we collected geochemical and geochronological data for the Triassic granitoid plutons of West Qinling and found that nearly all plutons share the similar features with the Zhongchuan pluton. We present new laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb ages, major and trace element geochemistry, and zircon Hf isotope systematics for the granites of the Zhongchuan pluton to elucidate the evolution of granitoid plutons in West Qinling during the Triassic. LA-ICP-MS zircon U–Pb dating indicates that the Xujiaba and Guandigou units formed at 220.1 ± 1.2 and 215.9 ± 0.85 Ma, respectively, reflecting the time of the Late Triassic. The rocks of the Zhongchuan pluton are metaluminous to weakly peraluminous and have a high-K calc-alkaline to shoshonite series with high SiO₂ (63.59–76.22%) and low P₂O₅ (0–0.2%) concentrations, a high K₂O/Na₂O ratio (1.18–17.92), a high differentiation index (78.45–93.04) and a medium A/CNK ratio (0.98–1.69). The zircon Hf isotope dating indicates that the Xujiaba and Guandigou units have an inhomogeneous ε_Hf(t) (?4.425 to 1.067 for Xujiaba and ?4.920 to 2.042 for Guandigou) and two-stage Hf model ages (1123–1531 Ma for Xujiaba and 1115–2342 Ma for Guandigou). The geochemical and isotopic data imply that the granites of each unit share the same origin. They probably derived from the partial melt of metagreywackes and then mixed with the mantle-derived magma. Based on the regional geological history, petrographic characteristics and new geochemical and isotopic data of the Zhongchuan pluton, we suggest that the Triassic magma was derived from the partial melts of metagreywackes and was influenced by the mantle-derived melt during the collision of the Yangtze and Qinling plates.     

东天山黄山南镁铁-超镁铁质岩体锆石U-Pb年龄及岩浆演化过程探讨

黄山南镁铁-超镁铁质岩体位于东天山造山带觉罗塔格构造带内,与构造带内一系列镁铁-超镁铁质岩体构成了东天山镁铁-超镁铁质岩带。黄山南岩体锆石U-Pb同位素定年得到293.7±3.1Ma的加权平均年龄,显示其形成年龄为早二叠世。岩石样品镁铁比值m/f比值介于4.45~6.37之间,属于铁质超基性岩;利用橄榄石最高Fo值计算得到黄山南岩体母岩浆的Mg~#值为0.70,表明其母岩浆成分与原生岩浆较为接近,具有高镁拉斑玄武岩质岩浆的性质,且演化程度较低或母岩浆有过剩橄榄石堆晶的加入。Ba/La、Ba/Nb、Ba/Th、Rb/Nb、Th/Nb和Sm/Yb等微量元素比值表明黄山南岩体的岩浆源区可能为一被俯冲板片沉积物和流体改造过的较富集的岩石圈地幔。主量元素变化特征显示了岩浆结晶分异作用的一般特征;较高的Ba/Nb比值,相对高的La/Nb和低La/Ba值以及Ni-Ta-(Ti)元素的负异常表明岩浆上升过程中可能经历了地壳物质的混染作用。黄山南岩体年龄及岩石地球化学特征综合表明其能够代表东天山地区地幔岩浆演化早期阶段的产物,具有较好的成矿潜力。     

北秦岭西段黄牛铺岩体锆石U Pb年代学、岩石地球化学特征及其地质意义

对北秦岭西段黄牛铺岩体进行了LA ICP MS锆石U Pb年代学与岩石地球化学分析。结果显示,黄牛铺岩体的锆石U Pb年龄为(4493±49) Ma,表明其形成时代为晚奥陶世。黄牛铺岩体属于准铝质高钾钙碱性系列,在成因类型上具有I型花岗岩的岩石矿物学与地球化学特征,其稀土元素配分曲线呈轻稀土元素富集、重稀土元素亏损(LREE/HREE=983~1155)、铕弱负异常(δEu=082~095)的右倾型,微量元素Rb、Th、U、Sm等富集,Ta、Nb、Ti、Hf等明显亏损,表现为岛弧岩浆岩的地球化学特征。结合区域地质资料,认为黄牛铺岩体形成于晚奥陶世商丹洋俯冲过程中的岛弧环境,是壳幔岩浆混合作用的产物,这为进一步研究北秦岭的构造演化过程提供了更加充分准确的岩浆活动证据。     

Geochemistry, Geochronology and Lu-Hf Isotopes of Peraluminous Granitic Porphyry from the Walegen Au Deposit, West Qinling Terrane

Walegen Au deposit is closely correlated with granitic intrusions of Triassic age, which are composed of granite and quartz porphyries. Both granite porphyry and quartz porphyry consist of quartz, feldspar and muscovite as primary minerals. Weakly peraluminous granite porphyry(A/CNK=1.10–1.15) is enriched in LREE, depleted in HREE with Nb-Ta-Ti anomalies, and displays subduction-related geochemistry. Quartz porphyry is strongly peraluminous(A/CNK=1.64–2.81) with highly evolved components, characterized by lower TiO_2, REE contents, Mg~#, K/Rb, Nb/Ta, Zr/Hf ratios and higher Rb/Sr ratios than the granite porphyry. REE patterns of quartz porphyry exhibit lanthanide tetrad effect, resulting from mineral fractionation or participation of fluids with enriched F and Cl. LAICP-MS zircon U-Pb dating indicates quartz porphyry formed at 233±3 Ma. The ages of relict zircons from Triassic magmatic rocks match well with the detrital zircons from regional area. In addition, ε_(Hf)(t) values of Triassic magmatic zircons from the granite and quartz porphyries are -14.2 to -9.1(with an exception of +4.1) and -10.8 to -8.6 respectively, indicating a crustal-dominant source. Regionally, numerous Middle Triassic granitoids were previously reported to be formed under the consumption of Paleotethyan Ocean. These facts indicate that the granitic porphyries from Walegen Au deposit may have been formed in the processes of the closing of Paleotethyan Ocean, which could correlate with the arc-related magmatism in the Kunlun orogen to the west and the Qinling orogen to the east.