Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.     

Changes to cadmium associations in canal sediments on drying and oxidation

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.     

Subsidence due to peat oxidation and impact on drainage infrastructures in a farmland catchment south of the Venice Lagoon

Large agricultural areas reclaimed in the past century, south of the Venice Lagoon, have experienced significant land subsidence due to oxidation of peat organic soils. This has exposed the region to flood hazard particularly during severe storms and has contributed to increase the marginal management cost of the infrastructures (ditches, levees, pumping stations) designed to operate the drainage system. Direct measurements and indirect evidence from the channel network suggest a land settlement between 1.5 and 2 m over the past 70 years. This paper provides an overview of the problem with important information on its most recent evolution.     

A Comparison of Sediment Varves (1950–2003 AD) in Two Adjacent Lakes in Northern Sweden

Koltjärnen and Nylandssjön are two closely situated lakes (<2 km apart) in northern Sweden. During the past century, distinct varved sediments have formed in these lakes. Nylandssjön has two varved, deep basins. Since lake and catchment characteristics superficially appear very similar for the two lakes and they are exposed to the same climate, one would expect the sediment varves to be similar. This investigation compares the varves in the two deep basins of Nylandssjön, and in the two lakes. The comparison of basins of Nylandssjön shows that varve thickness, water content and annual accumulation rates of organic matter and nitrogen are correlated for the period (1970–2003). The grey-scale curves are only clearly similar in about 50% of the varves. In the between-lake comparison varve thickness, water content and annual accumulation rates of organic matter and nitrogen are correlated for the period (1950–1996). However, the annual accumulation rates of dry mass, minerogenic matter and biogenic silica differ between the lakes, as well as within-varve successions in grey-scale. A general explanation to the differences is that the prerequisites for varve formation are not totally similar because of differences in catchment size, catchment- to-lake material fluxes, lake productivity and land-use influence. This study illustrates the complex relationships that exist between a lake, its catchment, in-lake productivity and formation of sediment varves. As a consequence, we must not apply a too simplistic view of the potential of varves as past climatic indicators, especially if the lakes are affected by land-use.     

Application of membrane technology for water treatment： Ultrasound-associated cleaning of fouled microfiltration membranes

The use of membranes is a widely employed, versatile, and effective separation process. One of the limiting aspects in applying microfiltration （MF） for wastewater treatment is that of problems with membrane fouling and consequent flux reduction. Membrane fouling occurs by the irreversible deposition of retained particles, colloids, macromolecules, salts, etc. at the membrane surface and/or inside the membrane. The predominant fouling mechanisms observed with MF membranes are classified as three categories： the build-up of a cake layer on the membrane surface, blocking of membrane pores, and adsorption of fouling material on the membrane surface or in the pore walls. Although many techniques have been developed to overcome fouling, studies on membrane cleaning still seem to be insufficient for practical membrane filtration systems. Current membrane cleaning technologies include hydraulic, chemical, and mechanical methods. Ultrasound （US） has been widely used as a method of cleaning materials because of the cavitation phenomenon. In this study, US cleaning technique was applied to removing the fouling of polyvinglidenefluoride （PVDF） MF membrane, which was used to treat yeast cell and isolated soybean protein （ISP） solution, respectively. The US employed 40 kHz frequency and the output power of 1.43-2.85 W/cm^2. The evolution of the cleaning effect is followed by the measurements of the flux recovery rate （FRstat） and the cleaning time cycle. Results showed that the membrane property, which was fouled by yeast cell solution, could be recovered by water cleaning with US irradiation. And the cleaning time with the same FRstat decreased with the increase of US intensity.     

基于点重要度的地形LOD简化算法及精度

在分析、讨论目前关于3维地形模型简化与误差控制方法的基础上,提出了一种基于点重要度进行连续LOD模型简化的算法.并以5种典型地貌的实验数据作为运行实例,给出了点重要度与地貌类型之间的精度关系.这为今后连续LOD模型的合理建立提供了一种新思路和方法,也为模型的简化提供了科学依据.     

青藏高原东缘龙门山晚新生代剥蚀厚度与弹性挠曲模拟

龙门山是青藏高原东缘边界山脉,具有青藏高原地貌、龙门山高山地貌和山前冲积平原三个一级地貌单元。利用数字高程模式图像和裂变径迹年代测定方法研究和计算龙门山晚新生代剥蚀厚度与剥蚀速率,结果表明:3.6 Ma以来龙门山的剥蚀厚度介于1.91-2.16 km之间,剥蚀速率介于0.53-0.60 mm/a之间。在此基础上,开展了该地区岩石圈的弹性挠曲模拟,结果表明龙门山的隆升机制具有以构造缩短隆升和剥蚀卸载隆升相叠合的特点。3.6 Ma之前,龙门山的隆升与逆冲推覆构造负载有关,以构造缩短驱动的构造隆升为特色;3.6 Ma之后,龙门山的隆升与剥蚀卸载驱动的抬升有关,并以剥蚀卸载隆升为特色,进而提出了龙门山晚新生代以来的隆升机制以剥蚀成山作用为主的认识。     

现阶段地表油气化探技术难题与发展对策

虽然地表油气化探方法技术已取得显著的应用效果, 但是由于成功率计算标准不同及方法技术本身的缺陷, 导致人们对方法的认同度较低。当前, 地表油气化探技术的发展, 一方面要以可靠的实验依据、严谨的数理推导及理论模型应对来自方法技术本身的挑战, 另一方面也要利用其快速、廉价和直接的优势, 加强与地质、遥感、非震物探等方法综合应用。     

吐哈盆地十红滩铀矿床水文地球化学特征

本文根据水化学资料的研究,探讨了十红滩铀矿床含矿含水层高矿化度地下水的成因,分析了高矿化度水对铀溶解迁移的影响及碳酸盐的形成机理.     

环境矿物材料治理镉（Cd^2＋）污染研究进展

近年来,环境矿物材料以其经济、有效、无二次污染等特点,在重金属废水处理和土壤修复方面显示出了众多优势,可替代传统的镉污染处理方法。本文综述了国内外环境矿物材料在处理镉污染方面的研究进展,并对今后应用环境矿物材料治理镉污染提出了一些建议。