松辽盆地古龙凹陷页岩油储层中的纳孔纳缝及其原位成藏理论初探

古龙凹陷青山口组页岩油的,地质资源量达151亿t,是重要后备的油气资源。用电子背散射(HDBSD)发现了古龙页岩油储层中纳米孔和纳米缝非常发育,电子探针表明这些纳孔纳缝均被沥青充填。纳米孔的直径多在10～50 nm,中位数在20～30 nm,形态多不规则,多呈多角形,主要是一种E-F纳孔,其次为E-E纳孔,多与纳米缝联结。纳缝宽度多在10～50 nm,中位数也在20～30 nm。它们主要是由黏土片(黏土域)的F-F凝聚形成的。黏土的凝聚与有机质密切相关。黏土胶体由于同晶置换会带负电荷,使得其周围会吸附带正电的金属阳离子,形成一个带正电的黏土团。这种带正电的黏土团又会吸附带负电的腐殖酸(有机质)和初步降解的藻,形成一个有机黏土絮凝体。这种有机黏土絮凝体进入生排烃门限后,由于生排烃有机质体积会收缩,体积收缩最高可达87%。生排出的烃会就近充填在这种收缩形成的孔隙中,又由于纳孔纳缝的毛细阻力(约12 MPa)等使得排出的烃无法运移出去便形成了古龙页岩油的特殊连续原位油藏。     

海南流沙港组致密砂岩体积压裂工艺研究及应用

福山凹陷流沙港组致密砂岩是海南福山油田勘探开发的重要目标之一。受复杂构造演化影响,该区致密砂岩具有砂泥薄互层明显、低孔低渗、高温等特征,为了解决以往储层改造中经常出现的施工压力高、缝高失控、砂堵、单井产量低、压裂后产量下降快等问题。借鉴非常规体积压裂技术,采用变排量、人工隔层控缝高、暂堵转向等工艺,同时进一步优化压裂液,应用纳米增效洗油剂,在福山油田致密砂岩开展了4口井次试验。研究结果表明：非常规体积压裂技术可有效降低砂堵风险,提高福山油田致密砂岩储层的改造效果。变排量、人工隔层控缝高、暂堵转向压裂等储层改造工艺的实施,有效控制了缝高,提高了储层的压开程度。纳米增效洗油剂的应用,最大限度地降低了液体对地层和裂缝的伤害,发挥了纳米液滴渗吸洗油作用,增加了油气井的稳产期。     

Evolution and palaeoenvironment of the Bauru Basin (Upper Cretaceous,Brazil)

The Bauru Basin was one of the great Cretaceous desert basins of the world, evolved in arid zone called Southern Hot Arid Belt. Its paleobiological record consists mainly of dinosaurs, crocodiles and turtles. The Bauru Basin is an extensive region of the South American continent that includes parts of the southeast and south of Brazil, covering an area of 370,000 km². It is an interior continental basin that developed as a result of subsidence of the central-southern part of the South-American Platform during the Late Cretaceous (Coniacian–Maastrichtian). This sag basin is filled by a sandy siliciclastic sequence with a preserved maximum thickness of 480 m, deposited in semiarid to desert conditions. Its basement consists of volcanic rocks (mainly basalts) of the Lower Cretaceous (Hauterivian) Serra Geral basalt flows, of the Paraná-Etendeka Continental Flood Basalt Province. The sag basin was filled by an essentially siliciclastic psammitic sequence. In lithostratigraphic terms the sequence consists of the Caiuá and Bauru groups. The northern and northeastern edges of the basin provide a record of more proximal original deposits, such as associations of conglomeratic sand facies from alluvial fans, lakes, and intertwined distributary river systems. The progressive basin filling led to the burial of the basaltic substrate by extensive blanket sand sheets, associated with deposits of small dunes and small shallow lakes that retained mud (such as loess). Also in this intermediate context between the edges (more humid) and the interior (dry), wide sand sheet areas crossed by unconfined desert rivers (wadis) occurred. In the central axis of the elliptical basin a regional drainage system formed, flowing from northeast to southwest between the edges of the basin and the hot and dry inner periphery of the Caiuá desert (southwest). Life in the Bauru Basin flourished most in the areas with the greatest water availability, in which dinosaurs, crocodiles, turtles, fish, amphibians, molluscs, crustaceans, and charophyte algae lived. The fossil record mainly consists of transported bones and other skeletal fragments. In the northeastern and eastern marginal regions fossils are found in marginal alluvial fan deposits, broad plains of braided streams and ephemeral alkaline water lakes. In the basin interior the fossil record is related to deposits in sand sheets with braided streams, small dunes, and shallow lakes. In the great Caiuá inner desert a few smaller animals could survive (small reptiles and early mammals), sometimes leaving their footprints in dune foreset deposits. The aim of this article is to present and link the basin sedimentary evolution, palaeoecological features and palaeontological record.     

北黄海盆地东部坳陷勘探突破对我国近海残留“黑色侏罗系”油气勘探的启示

最新的勘探和研究证实,北黄海盆地东部坳陷发育了中、上侏罗统2套有效烃源岩并以上侏罗统为主力烃源岩层,在其供烃范围内形成了上侏罗统-下白垩统"下生上储式"和中-上侏罗统"自生自储式"2类成藏组合,取得了我国东部海域以侏罗系为唯一源岩的含油气盆地勘探突破。为进一步探索我国近海盆地残留"黑色侏罗系"的资源潜力和勘探前景,本文采用地震-地质综合解释、烃源岩地球化学分析、盆地模拟等方法,综合分析了我国近海主要盆地残留"黑色侏罗系"的分布和地球化学特征。结果表明,我国近海残留侏罗系暗色泥岩烃源岩非均质性较强,多属"中等"级别,局部发育"中等-好"、"中等-差"级别烃源岩,侏罗系烃源岩大多存在早（J₃-K₁）、晚（E₂末-N₁）2期生、排烃高峰,生烃总量达1.4×10¹¹ t,资源前景乐观,预测可形成侏罗系"自生自储式"和侏罗系-白垩系（或新生界）"下生上储式"2类源储组合。     

涠西南凹陷流沙港组烃源岩生产力及发育模式

涠西南凹陷是中国近海北部湾盆地已证实的富烃凹陷,始新统流沙港组是该凹陷主要烃源岩层系.为深入认识涠西南凹陷流沙港组烃源岩的生产力和发育特征,采用有机地球化学与地球生物学相结合、定性分析与定量计算相结合的方法正演恢复了涠西南凹陷不同次洼流沙港组不同层段烃源岩的古生产力、有机质埋藏效率和有机碳埋藏生产力,进而建立了研究区流沙港组烃源岩形成的地球生物学模式.结果表明,涠西南凹陷流沙港组烃源岩的古生产力、有机质埋藏效率及有机碳埋藏生产力在横向不同次洼和纵向不同层段上均存在差异,横向上以B次洼最优,纵向上以流二段最高;涠西南凹陷流沙港组烃源岩发育超营养湖高埋藏效率高埋藏生产力、富营养湖中等埋藏效率中等埋藏生产力及富营养湖低埋藏效率低埋藏生产力3种代表性的地球生物学模式.     

珠江口盆地的沉积充填与珠江的形成演变

沉积物元素地球化学分析表明,南海北部地区沉积物渐新统与中新统明显不同,两者之间存在物源突变事件。这一沉积地质事件在时间上与南海扩张轴发生跳跃、滇西高原以及东喜马拉雅构造结的快速隆升等一系列地质构造事件十分吻合,是珠江以及珠江口盆地搬运—沉积—充填演化史上一次重大的转变。Ca/Si、CIA以及Al₂O₃等参数变化显示,珠江侵蚀区极有可能由渐新世近源硅酸盐为主的华南沿海地区拓展为中新世远达青藏高原东麓的云贵高原碳酸盐为主的地区,流域范围突然扩大。同时伴随沉积物供给增大,造成珠江口盆地从渐新世富砂为主的沉积堆积体系转变为中新世以来以泥为主的沉积堆积体系,显示出珠江的发育演化以及中新世以来的青藏高原隆升在南海北部的沉积充填演变中扮演了重要角色,对南海北部地区油气藏的形成影响深远。     

南堡凹陷东营组层序地层格架与沉积体系

通过对地震、岩心、钻、测井资料综合分析,将东营组划分为1个二级层序、3个三级层序。并根据初次湖泛面和最大湖泛面特征将每个层序进一步划分为低位域、湖侵域和高位域等三个体系域。层序格架和展布受凹陷结构和断裂活动影响,高柳断层以北地区东营组沉积厚度薄,且后期剥蚀严重。南部滩海地区的各层序完整,厚度相对稳定。在层序格架内分析了南堡凹陷东营组的沉积体系,东北部陡坡带以发育水下扇、扇三角洲为主,西北部和南部缓坡带发育三角洲、扇三角洲和辫状河三角洲。层序界面、准层序（组）叠加样式以及沉积体系空间展布均受到构造活动的控制,强构造活动期形成退积式叠加模式,而弱构造活动期对应进积式叠加模式。对层序发育和油气成藏条件分析认为层序1低位域的扇三角洲砂体和层序2中的浊积砂体为寻找岩性油气藏的有利部位。     

Early Cenozoic paleontological assemblages and provenance evolution of the Lishui Sag,East China Sea

The East China Sea Shelf Basin generated a series of back-arc basins with thick successions of marine- and terrestrial-facies sediments during Cenozoic. It is enriched with abundant oil and gas resources and is of great significance to the petroleum exploration undertakings. Therein, the Lishui Sag formed fan delta, fluvial delta and littoral-to-neritic facies sediments during Paleocene–Eocene, and the research on its sedimentary environment and sediment source was controversial. This study analyzed the paleontological combination characteristics, and conducted a source-to-sink comparative analysis to restore the sedimentary environment and provenance evolution of the Lishui Sag during Paleocene–Eocene based on the integration of detrital zircon U-Pb age spectra patterns with paleontological assemblages. The results indicated that Lishui Sag was dominated by littoral and neritic-facies environment during time corroborated by large abundance of foraminifera, calcareous nannofossils and dinoflagellates. Chronological analysis of detrital zircon U-Pb revealed that there were significant differences in sediment sources between the east and west area of the Lishui Sag. The western area was featured by deeper water depths in the Paleocene–Eocene, and the sediment was characterized by a single Yanshanian peak of zircon U-Pb age spectra, and mainly influenced from Yanshanian magmatic rocks of South China Coast and the surrounding paleo-uplifts. However, its eastern area partly showed Indosinian populations. In particular, the upper Eocene Wenzhou sediments were featured by increasingly plentiful Precambrian zircons in addition to the large Indosinian-Yanshanian peaks, indicating a possible impact from the Yushan Low Uplift to the east. Therefore, it is likely that the eastern Lishui Sag generated large river systems as well as deltas during time. Due to the Yuquan Movement, the Lishui Sag experienced uplifting and exhumation in the late stage of the late Eocene and was not deposited with sediments until Miocene. Featured by transitional-facies depositions of Paleocene–Eocene, the Lishui Sag thus beared significant potential for source rock and oil-gas reservoir accumulation.     

Controlling factors on the charging process of oil and gas in the eastern main sub-sag of the Baiyun Sag,Zhujiang River (Pearl River) Mouth Basin

The eastern main sub-sag (E-MSS) of the Baiyun Sag was the main zone for gas exploration in the deep-water area of the Zhujiang River (Pearl River) Mouth Basin at its early exploration stage, but the main goal of searching gas in this area was broken through by the successful exploration of the W3-2 and H34B volatile oil reservoirs, which provides a new insight for exploration of the Paleogene oil reservoirs in the E-MSS. Nevertheless, it is not clear on the distribution of “gas accumulated in the upper layer, oil accumulated in the lower layer” (Gas_upper-Oil_lower) under the high heat flow, different source-rock beds, multi-stages of oil and gas charge, and multi-fluid phases, and not yet a definite understanding of the genetic relationship and formation mechanism among volatile oil, light oil and condensate gas reservoirs, and the migration and sequential charge model of oil and gas. These puzzles directly lead to the lack of a clear direction for oil exploration and drilling zone in this area. In this work, the PVT fluid phase, the origin of crude oil and condensate, the secondary alteration of oil and gas reservoirs, the evolution sequence of oil and gas formation, the phase state of oil and gas migration, and the configuration of fault activity were analyzed, which established the migration and accumulation model of Gas_upper-Oil_lower co-controlled by source and heat, and fractionation controlled by facies in the E-MSS. Meanwhile, the fractionation evolution model among common black reservoirs, volatile reservoirs, condensate reservoirs and gas reservoirs is discussed, which proposed that the distribution pattern of Gas_upper-Oil_lower in the E-MSS is controlled by the generation attribute of oil and gas from source rocks, the difference of thermal evolution, and the fractionation controlled by phases after mixing the oil and gas. Overall, we suggest that residual oil reservoirs should be found in the lower strata of the discovered gas reservoirs in the oil-source fault and diapir-developed areas, while volatile oil reservoirs should be found in the deeper strata near the sag with no oil-source fault area.     

河套盆地吉兰泰凹陷中生代构造层划分及意义

2017年河套盆地临河坳陷油气勘探取得重要发现,基于区域中生代以来大地构造演化系统梳理,以钻井与地震对照、研究区与邻近盆地类比为研究方法,划分河套盆地临河坳陷南部吉兰泰凹陷中生代构造层,并绘制其分布范围,探讨其赋存特征与意义。结果表明：研究区中生界除三叠系外发育齐全,厚度巨大,且白垩系自上而下可细分为K1 ^I、K1 ^II和K1^III三个构造层;除K1I构造层全区广覆式发育外,其它构造层呈楔状—缓楔状,长轴沿主控断裂NNE向延伸;研究区自中生代以来盆地性质经历了早中侏罗世断陷、早白垩世早期断陷、早白垩世中期断拗转换和早白垩世晚期拗陷的演化过程;F ₃和F ₇断层之间的K1 ^II和K1 ^III构造层、F ₇断层东部的J构造层均具良好的油气勘探前景。