珠江口八大口门径、潮作用动力过程研究

根据2006—2007年期间在珠江口八大口门进行的丰水期大、中、小潮3个航次、平水期和枯水期各1个航次的全潮同步水文观测资料,分析了八大口门的潮流特性、涨落潮通量等特征,并建立了逐时潮差与流量的相关关系。在丰水期小潮期间,八大口门受强热带风暴"碧利斯"带来的强降雨的影响,潮流特性、断面流量等水文特征出现较大的变化,逐时潮差与流量的相关关系与其他航次相比表现出不同的规律。在无强径流影响下,逐时潮差与流量的相关关系用线性方程拟合,相关性较好;但在强径流影响下,则采用二次多项式拟合较为合适,且拟合曲线的左右侧表现出涨、落潮过程的区别。     

The scavenging of free radical and oxygen species activities and hydration capacity of collagen hydrolysates from walleye pollock (Theragra chalcogramma) skin

Fish skin collagen hydrolysates (FSCH) were prepared from walleye pollock (Theragra chalcogramma) using a mixture of enzymes, namely trypsin and flavourzyme. The degree of hydrolysis of the skin collagen was 27.3%. FSCH was mainly composed of low-molecular-weight peptides and the relative proportion of <1000Da fraction was 70.6%. Free radical and oxygen species scavenging activities of FSCH were investigated in four model systems, including diphenylpicrylhy-drazyl radical (DPPH), superoxide anion radical, hydroxyl radical and hydrogen peroxide model, and compared with that of a native antioxidant, reduced glutathione (GSH). FSCH was also evaluated by water-absorbing and water-holding capacity. The results showed that FSCH was able to scavenge free radical and oxygen species significantly and to enhance water-absorbing and water-holding capacity remarkably. Therefore, FSCH may have potential applications in the medicine and food industries.     

Stochastic evaluation of fluvial to marginal marine sealing facies

Hydrocarbon top seal analyses are particularly difficult in fluvial and marginal marine settings. Although these settings often contain beds comprised of a low-permeability, clay-rich lithology associated with high quality seals, their presence does not guarantee an effective seal because individual beds within the stratal unit may be laterally discontinuous. Lateral facies changes, truncation of fine-grained beds, or the presence of crevasse splays may provide cross-stratal migration pathways, reducing the effective sealing capacity to a magnitude less than the closure height.     

Kinetic and equilibrium studies of copper-dissolved organic matter complexation in water column of the stratified Krka River estuary (Croatia)

An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (K_i^equ), total ligands concentration (L_iT) and association/dissociation rate constants (k_i¹,k_i^- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K₁^equ: 11.2–13.0, log K₂^equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k₁¹:6.1–20 × 10³ (M s)^− 1, k₂¹: 1.3–6.3 × 10³ (M s)^− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µM_C, i.e. 1 mg_CL^− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).     

Fuzzy comprehensive evaluation model for water resources carrying capacity in Tarim River Basin, Xinjiang, China

This paper explores the method of comprehensive evaluation of water resources carrying capacity and sets up an evaluation model applying the fuzzy comprehensive evaluation method. Based on the data of nature, society, economics and water resources of the Tarim River Basin in 2002, we evaluated the water resources carrying capacity of the basin by means of the model. The results show that the comprehensive grades are 0.438 and 0.454 for Aksu and Kashi prefectures respectively, where the current water resources exploitation and utilization has reached a relative high degree and there is only a very limited water carrying capacity, 0.620 for Kizilsu Kirgiz Autonomous Prefecture, where water resources carrying capacity is much higher, and in between for Hotan Prefecture and Bayingolin Mongolian Autonomous Prefecture. As a whole, the comprehensive grade of the Tarim River Basin is 0.508 and the current water resources exploitation and utilization has reached a relative high degree. Thus, we suggest that the integrated management of the water resources in the basin should be strengthened in order to utilize water resources scientifically and sustainably.     

基于非线性动力学模型的旅游生态容量分析

近年来,大量增加的游客给景区的旅游生态容量带来了较大的压力,矛盾日渐突出。为了实现景区的环境保护与可持续发展,研究游客活动量与景区旅游生态容量之间的关系是十分必要的。本文从非线性动力学观点出发,构建二者非线性动力学模型,并进行平衡态分析。研究结果表明:(1)系统要达到可持续发展,必须建立在景区环境的自我更新能力及人工恢复程度之和大于外界污染水平,且游客的增长率必须保持在较低水平的基础上;(2)景区旅游生态容量的承载力是有限的,所能容纳的游客也是有限的,超过一定的限度就会引起生态系统失衡。采取严格控制游客量,加强对景区内外环境的保护和改善、提升游客素养等措施,对于系统的协调发展至关重要。     

基于公平性的水环境容量分配研究——以沱江流域为例

公平与效益是容量分配的两个重要原则.在我国目前采用的水环境容量无偿分配方式下,公平原则是需遵循的首要原则,在公平的基础上追求效益.以沱江流域为对象,综合考虑涉及区域的社会、经济、自然等客观因素,筛选指标确定系数对流域容量进行分配.应用经济学中衡量收入公平的基尼系数概念,对分配结果的公平性进行评估,给出综合体现社会性、经济性和历史性的水环境容量分配方案.