利用扫描电镜-电子探针研究四川杨柳坪镍铜硫化物矿床铂钯的赋存状态及沉淀机制

本文利用电子探针和配备能谱分析功能的扫描电镜对四川杨柳坪镍-铜硫化物矿床中铂钯的赋存状态进行了研究。结果表明,铂以独立矿物相砷铂矿和自然铂存在;钯以碲化物、碲铋化物、碲锑化物、锑化物及自然钯独立矿物相存在,也以类质同象形式分布在碲镍矿中(钯含量约10%),另外还以锑铋钯碲矿、六方锑碲钯矿、碲钯矿独立矿物相存,并以类质同象形式分布在Vavrinite(钯含量5%)和砷铂矿(钯含量1%~5%)中。杨柳坪矿床中铂钯元素沉淀与贱金属矿物(BMS)及晚期热液蚀变矿物蛇纹石、方解石密切相关,其沉淀经历了3个阶段:1早期高温阶段(1200~900℃),铂钯元素沉淀并包裹在BMS中;2中期中高温阶段(650~250℃),分离结晶作用使铂钯元素沉淀并分布BMS矿物的边部,同时该阶段热液来源的铂钯元素沉淀于BMS粒间;3晚期热液蚀变阶段(500~300℃),热液蚀变作用引起铂钯元素沉淀在蚀变矿物中或嵌布在BMS裂隙。本文研究成果为认识该矿床及同类型镍-铜硫化物矿床的铂钯成矿过程提供了新的依据。     

鲁西隆起北侧博兴洼陷新生界碎屑重矿物的物源示踪分析

利用碎屑重矿物对鲁西隆起北侧博兴洼陷的新生界沉积岩开展了碎屑物源示踪分析。通过研究区重矿物聚类分析、源区岩石类型分析并结合薄片和探针分析结果,发现研究区源岩类型多样,既有以绿帘石为代表的亲鲁西变质岩,也有以富含石榴石为代表的亲苏鲁变质岩,同时也有火山岩和沉积岩;从古近纪沙河街组三段沉积期开始源岩中亲苏鲁变质岩不断减少,亲鲁西变质岩和基性火成岩不断增加,至新近纪明化镇组沉积期洼陷内几乎无富含石榴石类型源岩,表明博兴洼陷自古近纪以来一直存在来自鲁西、胶东(超高压带)的物源记录,从古近纪沙河街组三段沉积期开始,胶东的物源供给逐渐减少,而到明化镇组沉积时由于鲁西的快速隆升,胶东与博兴洼陷的物源联系被切断。     

独立分量分析改进的图像去噪方法

针对传统去噪算法在复杂噪声污染图像处理中能力较弱的问题,该文基于信号高阶统计量的独立分量分析,通过其自适应变换,分离出源信号中的统计独立的分量,在分析对比传统图像去噪方法的基础上,讨论了独立分量分析的基本模型及原理;提出了一种结合中值滤波与wiener滤波的最大似然估计的图像去噪改进方法。仿真实验表明改进的独立分量分析去噪方法具有较大的优越性。     

1:25万多目标区域地球化学调查样品的分析测试质量监控方法

在1：25万多目标区域地球化学调查样品分析的质量监控方法中，提出以准确度与精密度并重，标准物质监控与重复样监控相结合。利用“多目标化探样品计算机管理软件”，实现对调查样品分析质量监控的自动化管理。应用该系统软件，只要建立好相应的分析数据库，就可自动获得分析报告、报出率、内检样检查、标样检查、标样监控图等监控数据。     

Bromide as a conservative tracer for soil-water studies

The assumption that potassium bromide is a conservative tracer for soil-water studies was tested in a series of batch sorption experiments. Sorption experiments were conducted on soil samples collected from the O, E, and A horizons of the Albemarle soil series near Charlottesville, VA. The experiments were conducted under conditions of differing bromide concentration and filter treatments. Bromide concentrations in soil-solution mixtures were measured through time using an Orion bromide-specific electrode. An analysis of variance of results showed no significant sorption of bromide through time under any concentration level or filter treatment (α = 0·01). No sorption of bromide between different soil horizons could be determined. This work clearly indicates that bromide is conservative under the conditions examined.     

地形作用下有限振幅Rossby波的稳定性分析

本文用微分方程定性理论方法分析了地形对有限振幅Rossby波的稳定性影响。结果表明:地形北坡有利于波动出现不稳定,南坡使波动稳定;西坡使导式波动不稳定但使曳式波动稳定,东坡使导式波动稳定但使曳式波动不稳定。     

区域地理信息系统在农业中的应用——以福建省浦城县为例

本文应用系统分析的理论和方法，建立了浦城县地理信息系统，分析了信息系统的结构、功能及信息管理过程，并在系统的支持下对浦城县农业发展战略进行决策研究，提出了一系列分析意见，开辟了地理信息系统应用的新领域。     

Palaeogeography and tectonic structure of allochthonous units in the German part of the Rheno-Hercynian Belt (Central European Variscides)

New information on palaeogeography, orogenic evolution, tectonic structure, and boundaries of allochthonous units in the Rheno-Hercynian Belt is based on provenance analyses of clastic sediments and field studies. ⁴⁰K/⁴⁰Ar dating of detrital muscovites proved to be a particularly useful method because Cadomian, Caledonian and Early Variscan provenances of detrital material can be distinguished. Cadomian muscovite cooling ages are restricted to allochthonous units whereas Caledonian ages dominate within par-autochthonous and shortly displaced allochthonous units. The largest and uppermost preserved nappe, the Gießen-Harz Nappe, is derived from an oceanic flysch basin, which was not reached by Caledonian detritus. The other allochthonous units form a duplex-like structure sandwiched between the Gießen-Harz Nappe and par-autochthonous units at its base. The thick and heterogeneous roof- and floor-thrusts of this structure were previously often misinterpreted as olistostromes. The northern margin of allochthonous units is the steeply dipping Hörre-Gommern Zone. It consists of three sub-units derived from deep-water areas between the shelf at the southern margin of the Old Red Sandstone Continent and an oceanic basin to the south. The southeastern part of the duplex-structure (Harzgerode Zone) shows close affinities to Armorican terranes.     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.