A New Interpretation of Centimetre-scale Variations in the Progress of Infiltration-driven Metamorphic Reactions: Case Study of Carbonated Metaperidotite, Val d'Efra, Central Alps, Switzerland

Progress () of the infiltration-driven reaction, 4olivine +5CO₂ + H₂O = talc + 5magnesite, that occurred during Barrovianregional metamorphism, varies at the cm-scale by a factor of3·5 within an 3 m³ volume of rock. Mineral and stableisotope compositions record that X_CO2, ¹⁸O_fluid, and ¹³C_fluidwere uniform within error of measurement in the same rock volume.The conventional interpretation of small-scale variations in in terms of channelized fluid flow cannot explain the uniformityin fluid composition. Small-scale variations in resulted insteadbecause (a) reactant olivine was a solid solution, (b) initiallythere were small-scale variations in the amount and compositionof olivine, and (c) fluid composition was completely homogenizedover the same scale by diffusion–dispersion during infiltrationand subsequent reaction. Assuming isochemical reaction, spatialvariations in image variations in the (Mg + Fe)/Si of the parentrock rather than the geometry of metamorphic fluid flow. Ifinfiltration-driven reactions involve minerals fixed in composition,on the other hand, spatial variations in do directly imagefluid flow paths. The geometry of fluid flow can never be determinedfrom geochemical tracers over a distance smaller than the oneover which fluid composition is completely homogenized by diffusion–dispersion. KEY WORDS: Alpine Barrovian metamorphism; diffusion; metamorphic fluid composition; metamorphic fluid flow; reaction progress     

Orthopyroxene–sillimanite–sapphirine granulites from the Bamble granulite terrane, southern Norway

Silica-deficient sapphirine-bearing rocks occur as an enclave within granulite facies Proterozoic gneisses and migmatites near Grimstad in the Bamble sector of south-east Norway (Hasleholmen locality). The rocks contain peraluminous sapphirine, orthopyroxene, gedrite, anthophyllite, sillimanite, sapphirine, corundum, cordierite, spinel, quartz and biotite in a variety of assemblages. Feldspar is absent.
Fe²⁺/(Fe²⁺+ Mg) in the analysed minerals varies in the order: spinel > gedrite ≥ anthophyllite ≥ biotite > sapphirine>orthopyroxene > cordierite.
Characteristic pseudomorph textures indicate coexistence of orthopyroxene and sillimanite during early stages of the reaction history. Assemblages containing orthopyroxene-sillimanite-sapphirine-cordierite-corundum developed during a high-pressure phase of metamorphism and are consistent with equilibration pressures of about 9 kbar at temperatures of 750–800°C. Decompression towards medium-pressure granulite facies generated various sapphirine-bearing assemblages. The diagnostic assemblage of this stage is sapphirine-cordierite. Sapphirine occurs in characteristic symplectite textures. The major mineralogical changes can be described by the discontinuous FMAS reaction: orthopyroxene + sillimanite → sapphirine + cordierite + corundum.
The disequilibrium textures found in the Hasleholmen rocks are characteristic for reactions which have been in progress but then ceased before they run to completion. Textures such as reaction rims, symplectites, partial replacement, corrosion and dissolution of earlier minerals are characteristic of granulite facies rocks. They indicate that, despite relatively high temperatures (700–800° C), equilibrium domains were small and chemical communication and transport was hampered as a result of dry or H₂O-poor conditions.     

Low-grade metamorphic rocks from the Pulur complex,NE Turkey: implications for the pre-Liassic evolution of the Eastern Pontides

In the Pulur complex (Sakarya Zone, Eastern Pontides, Turkey) a low-grade tectonometamorphic unit (Doankavak) is exposed in three tectonic windows beneath a complex medium-pressure high-temperature metamorphic unit of late Carboniferous age. The thrust plane between both units is transgressively covered by Liassic conglomerates. The Doankavak unit comprises a sequence of metabasites with MORB-type chemical compositions and phyllites, with subordinate calcareous phyllites, marbles, quarzofeldspathic schists and metacherts. This sequence is interpreted as a former accretionary complex related to the consumption of the Palaeotethys. Mineral parageneses in the metabasites allow for the distinction of two domains with slightly different peak metamorphic conditions, i.e. 375–425 °C/0.5–0.8 GPa (greenschist facies) and 400–470 °C/0.6–1.1 GPa (albite-epidote amphibolite facies). The age of metamorphism is constrained at ~ 260 Ma (early Late Permian) by two Rb-Sr mineral-whole rock ages (hornblende, phengite) and one ⁴⁰Ar/³⁹Ar single step total fusion age (phengite). In conjunction with previous data on other accretionary complexes in the Sakarya zone in Northern Turkey, the data presented in this study suggest a continuous subduction of the Palaeotethys at least from Early/Late Permian to Late Triassic and a discontinuous preservation of accretion complexes in both space and time.     

The thermal evolution of Corsica as recorded by zircon fission-tracks

New zircon fission-track (ZFT) ages from Corsica record multiple thermal events that can be tied to the structural evolution of the western Mediterranean region. The Corsican zircons have a wide scatter of ZFT grain ages (243–14 Ma), which together define several age domains. Western Corsica consists largely of stable Hercynian basement characterized by ZFT ages in the range 161–114 Ma. We interpret these ages (Late Jurassic–Early Cretaceous) as the product of a long-lived Tethyan thermal event related to continental rifting and subsequent drifting during the separation of the European and African plates and the formation of the Liguro–Piemontese ocean basin. In contrast to Hercynian Corsica, Alpine Corsica (northeast Corsica) experienced widespread deformation and metamorphism in Late Cretaceous(?)–Tertiary time. Dated samples from Alpine Corsica range in age from 112 to 19 Ma and all are reset or partially reset by one or more Alpine thermal events. The youngest ZFT grain ages are from the northernmost Alpine Corsica and define an age population at  24 Ma that indicates cooling after Tertiary thermal events associated with the Alpine metamorphism and the opening of the Liguro–Provençal basin. A less well-defined ZFT age population at  72 Ma is present in both Alpine Corsica and Hercynian basement rocks. The thermal history of these rocks is not clear. One interpretation is that the ZFT population at  72 Ma reflects resetting during a Late Cretaceous event broadly synchronous with the early Alpine metamorphism. Another interpretation is that this peak is related to variable fission-track annealing and partial resetting during the Tertiary Alpine metamorphic event across central to north-eastern Corsica. This partial age resetting supports the presence of a fossil ZFT partial annealing zone and limits the peak temperature in this area below 300 °C, for both the affected pre-Alpine and Alpine units.     

Polymetamorphism, zircon growth and retention of early assemblages through the dynamic evolution of a continental arc in Fiordland, New Zealand

The Marguerite Amphibolite and associated rocks in northern Fiordland, New Zealand, contain evidence for retention of Carboniferous metamorphic assemblages through Cretaceous collision of an arc, emplacement of large volumes of mafic magma, high‐P metamorphism and then extensional exhumation. The amphibolite occurs as five dismembered aluminous meta‐gabbroic xenoliths up to 2 km wide that are enclosed within meta‐leucotonalite of the Lake Hankinson Complex. A first metamorphic event (M1) is manifest in the amphibolite as a pervasively lineated pargasite–anorthite–kyanite or corundum ± rutile assemblage, and as diffusion‐zoned garnet in pelitic schist xenoliths within the amphibolite. Thin zones of metasomatically Al‐enriched leucotonalite directly at the margins of each amphibolite xenolith indicate element redistribution during M1 and equilibration at 6.6 ± 0.8 kbar and 618 ± 25 °C. A second phase of recrystallization (M2) formed patchy and static margarite ± kyanite–staurolite–chlorite–plagioclase–epidote assemblages in the amphibolite, pseudomorphs of coronas in gabbronorite, and thin high‐grossular garnet rims in the pelitic schists. Conditions of M2, 8.8 ± 0.6 kbar and 643 ± 27 °C, are recorded from the rims of garnet in the pelitic schists. Cathodoluminescence imaging and simultaneous acquisition of U‐Th‐Pb isotopes and trace elements by depth‐profiling zircon grains from one pelitic schist reveals four stages of growth, two of which are metamorphic. The first metamorphic stage, dated as 340.2 ± 2.2 Ma, is correlated with M1 on the basis that the unusual zircon trace element compositions indicate growth from a metasomatic fluid derived from the surrounding amphibolite during penetrative deformation. A second phase of zircon overgrowth coupled with crosscutting relationships date M2 to between 119 and 117 Ma. The Early Carboniferous event has not previously been recognized in northern Fiordland, whereas the latter event, which has been identified in Early Cretaceous batholiths, their xenoliths, and rocks directly at batholith margins, is here shown to have also affected the country rock. However, the effects of M2 are fragmentary due to limited element mobility, lack of deformation, distance from a heat source and short residence time in the lower crust during peak P and T. It is possible that many parts of the Fiordland continental arc achieved high‐P conditions in the Early Cretaceous but retain earlier metamorphic or igneous assemblages.     

Ubiquitous post-peak zircon in an eclogite from the Kumdy-Kol,Kokchetav UHP-HP Massif (Kazakhstan): Significance of exhumation-related zircon growth and modification in continental-subduction settings

U–Pb geochronological, trace-element and Lu–Hf isotopic studies have been made on zircons from ultrahigh-pressure (UHP) mafic eclogite from the Kumdy-Kol area, one of the diamond-facies domains of the Kokchetav Massif (northern Kazakhstan). The peak eclogitic assemblage equilibrated at > 900 °C, whereas the bulk sample composition displays light rare-earth element (LREE) and Th depletion evident of partial melting. Zircons from the eclogite are represented by exclusively newly formed metamorphic grains and have U–Pb age spread over 533–459 Ma, thus ranging from the time of peak subduction burial to that of the late post-orogenic collapse. The major zircon group with concordant age estimates have a concordia age of 508.1 ±4.4 Ma, which corresponds to exhumation of the eclogite-bearing UHP crustal slice to granulite- or amphibolite-facies depths. This may indicate potentially incoherent exhumation of different crustal blocks within a single Kumdy-Kol UHP domain. Model Hf isotopic characteristics of zircons (ε_Hf(t) +1.5 to +7.8, Neoproterozoic model Hf ages of 1.02–0.79 Ga) closely resemble the whole-rock values of the Kumdy-Kol eclogites and likely reflect in situ derivation of HFSE source for newly formed grains. The ages coupled with geochemical systematics of zircons confirm that predominantly late zircon growth occurred in Th–LREE-depleted eclogitic assemblage, that experienced incipient melting and monazite dissolution in melt at granulite-facies depths, followed by amphibolite-facies rehydration during late-stage exhumation-related retrogression.     

煤的吸附性能及影响因素

为了研究煤的储气性能,笔者对124个煤样进行等温吸附试验、煤岩测试、工业分析、压汞试验和低温液氮测试．研究表明：(1)煤变质对煤吸附能力具有控制作用,反射率从0．3％～4．25％,可燃基的Langmuir体积是11．25～47．16cm^2／g;(2)平衡水煤样吸附量与镜质组含量呈正相关、与惰质组含量呈负相关、与孔隙比表面积、微孔比表面积、微孔孔体积呈正相关;(3)水分、温度对煤的吸附能力有负面影响．煤变质程度不同,吸附曲线的变化趋势不同：气煤随着温度和压力增加吸附量一直增大,说明压力的影响起主导作用;无烟煤在温度小于60℃、压力小于15MPa之前,随着温度和压力同时增加吸附量增大,说明压力的影响起主导作用,之后,吸附量减小,说明温度的影响大于压力的影响。     

粤西金矿床成矿地球化学研究

粤西金矿床分为构造蚀变岩型、石英脉型和变质岩型.赋金地层主要为云开群上亚群和寒武系八村群,它们具有较高的含金丰度,可作为本区金的矿源层.在区域变质或混合岩化作用下,矿源层中的金可能发生活化、转移并在局部富集.海西-印支期花岗岩有继承变质岩、混合岩的特征,分异演化程度不高,这对金成矿有利.     

Classification of 24 New Ordinary Chondrites from the Grove Mountains, Antarctica

Petrography and mineral chemistry of 24 ordinary chondrites from the Grove Mountains, Antarctica, have been studied in order to identify their chemical-petrographic types. These samples were selected from a total of 4448 Grove Mountains (GRV) meteorites collected during the 19th Chinese Antarctic Research Expedition so as to make an estimation of the large GRV meteorite collection. The chemical-petrographic types of these meteorites are presented below: 1 H3,2 H4, 4 H5, 2 H6, 1 L4, 7 L5, 5 L6, 1 LL4 and 1 LL6. The new data weaken the previous report that unequilibrated ordinary chondrites are unusually abundant in the Grove Mountains region. However, this work confirms significant differences in distribution patterns of chemical-petrographic types between the Grove Mountains and other     

中阿尔金南缘志留纪高压泥质片麻岩的发现及其构造地质意义

在中阿尔金南缘西段尤努斯萨依北部原划长城系巴什库尔干岩群中首次发现一套高压泥质片麻岩。根据岩相学观察和矿物化学成分可识别出其四期矿物共生组合:早期为石榴子石+多硅白云母+单斜辉石(?)+斜长石+黑云母+石英+金红石+钛铁矿;第二期为石榴子石+蓝晶石+钾长石+斜长石+黑云母+石英+金红石+钛铁矿;第三期为石榴子石+夕线石+钾长石+斜长石+黑云母+石英+金红石+钛铁矿;晚期为石榴子石+夕线石+斜长石+黑云母+石英+钛铁矿。依据矿物内部一致性热力学数据,基于THERMOCALC 3. 40程序平台,计算出P-T视剖面图,并结合矿物等值线、矿物对温压计等计算,依次确定四期变质温压条件为15. 8～18. 3kbar/646～729℃、10. 30～12. 30kbar/781～821℃、8. 50～9. 60kbar/812～838℃和4. 65～5. 70kbar/698～725℃。上述四期变质阶段共同构成一个早期降压升温后降压降温的顺时针型演化的P-T轨迹,指示出与陆壳俯冲-折返相关的变质地质事件。利用LA-ICP-MS进行的锆石原位微区U-Pb定年和微量元素分析结果表明,该岩石记录了432. 0±2. 7Ma、401. 4±2. 5Ma和381. 1±2. 4Ma三期变质年龄,可能分别代表了该岩石早期高压、中期高压麻粒岩相-麻粒岩相和后期角闪岩相变质阶段的时代。该高压岩石出露于中阿尔金地块西段南缘长城系巴什库尔干岩群之中,与南侧以断裂带分隔的赋存于阿尔金岩群之中的南阿尔金高压-超高压岩石出露的构造位置明显不同,其峰期变质时代(～432Ma)亦明显不同于南阿尔金高压-超高压岩石的峰期变质时代(～500Ma)。因此,该高压岩石与南阿尔金高压-超高压岩石显然不能构成同一条变质岩带。结合区域地质背景和前人关于柴北缘陆壳属性高压-超高压岩石峰期变质时代(～430Ma)的研究成果综合分析,本文初步认为该高压岩石可能是柴北缘高压-超高压变质岩带的西延或是被中新生代以来阿尔金复杂多期次走滑断裂系迁移而就位于中阿尔金南缘的部分柴北缘高压-超高压变质岩片/岩块。