云南阳宗海表层沉积物有机质组成结构对磷赋存形态特征的影响

利用连续提取分级的方法定量分析阳宗海表层沉积物磷赋存形态,阐明了沉积物C、N、H和O组成及溶解有机质(DOM)紫外-可见光谱特征,探讨沉积物元素组成及DOM组成结构对不同形态磷含量的影响.结果表明:(1)沉积物潜在可移动磷含量在68.67~124.70 mg/kg之间变化,平均占总磷含量的9.81%,表现为BD-PNa OH-nr PNH_4Cl-P;沉积物稳定磷含量在496.73~908.28 mg/kg之间变化,平均占总磷含量的60.86%.(2)沉积物C、N含量和疏水性DOM光谱参数A_(240-400)表现出北部高、南部低的变化趋势,但H/C、O/C和(N+O)/C摩尔比和亲水性DOM光谱参数A_(240-400)变化趋势则与之恰好相反.(3)沉积物NH4Cl-P含量与C、N和H含量之间呈显著正相关,但与H/C、O/C、(N+O)/C摩尔比和亲水性DOM光谱参数E_2/E_3值之间呈显著负相关;NaOH-rP和BD-P+NaOH-rP含量均与O含量及O/H摩尔比呈显著负相关;NaOH-rP、BD-P+NaOH-rP和HCl-P均与疏水性DOM光谱参数A_(240-400)值之间呈显著正相关.因此,天然有机质元素组成及官能团结构是影响沉积物磷赋存形态的重要因素.     

塔里木盆地岩石层热结构特征

在大地热流密度分布的基础上，研究了塔里木盆地中库尔勒－若羌和阿克苏－叶城两条剖面岩石层热结构特征．由岩石层Ｐ波速度分布转换成生热率剖面，用二维数值模型获得了岩石层热结构和热状态特征．结果表明，塔里木盆地壳幔边界温度的高低与其埋深密切相关．居里等温面深度大，地幔热流密度较低．岩石层厚度变化与其新生代期间挠曲过程密切相关．在岩石层温度分布基础上，确定了深部脆－韧性过渡带深度和岩石层屈服强度，表明塔里木盆地岩石层相对较冷，且具有刚性的地球动力学特征．     

恩平凹陷新近系韩江组沉积微相及岩性圈闭类型

新近系韩江组是珠江口盆地恩平凹陷的油气主要储集层段,随着勘探程度的提高,寻找岩性油气藏是未来油气勘探的重要方向。为了系统地研究该地区岩性圈闭的发育类型,在“沉积层序”理论模型的指导下,划分出高位体系域、海侵体系域及低位体系域,并通过井震结合、岩芯观察,结合RGB属性融合技术增强关键沉积单元的刻画,开展了精细的沉积微相研究,共识别出辫状河道、串沟河道、曲流河道、河口坝、海岸砂脊和远砂坝6种沉积微相类型。在微相砂体刻画的基础上,结合构造特征,总结了该地区发育的构造-岩性圈闭、多砂体类型岩性圈闭以及上倾尖灭型岩性圈闭三大岩性圈闭类型,其中凹陷中部、西南部以河道砂为储层的构造-岩性圈闭为最具勘探潜力的目标类型。     

Structural characteristics of the KPR-CBR triple-junction inferred from gravity and magnetic interpretations,Philippine Sea Plate

The intersection of the Kyushu-Palau Ridge (KPR) and the Central Basin Rift (CBR) of the West Philippine Basin (WPB) is a relic of a trench-trench-rift (TTR) type triple-junction, which preserves some pivotal information on the cessation of the seafloor spreading of the WPB, the emplacement and disintegration of the proto-Izu-Bonin-Mariana (IBM) Arc, and the transition from initial rifting to steady-state spreading of the Parece Vela Basin (PVB). However, the structural characteristics of this triple-junction have not been thoroughly understood. In this paper, using the newly acquired multi-beam bathymetric, gravity, and magnetic data obtained by the Qingdao Institute of Marine Geology, China Geological Survey, the authors depict the topographic, gravity, and magnetic characteristics of the triple-junction and adjacent region. Calculations including the upward continuations and total horizontal derivatives of gravity anomaly are also performed to highlight the major structural features and discontinuities. Based on these works, the morphological and structural features and their formation mechanisms are analyzed. The results show that the last episode amagmatic extension along the CBR led to the formation of a deep rift valley, which extends eastward and incised the KPR. The morphological and structural fabrics of the KPR near and to the south of the triple-junction are consistent with those of the western PVB, manifesting as a series of NNE-SSW- and N-S-trending ridges and troughs, which were produced by the extensional faults associated with the initial rifting of the PVB. The superposition of the above two reasons induced the prominent discontinuity of the KPR in deep and shallow crustal structures between 15°N–15°30′N and 13°30′N–14°N. Combined with previous authors’ results, we propose that the stress produced by the early spreading of the PVB transmitted westward and promoted the final stage amagmatic extension of the CBR. The eastward propagation of the CBR destroyed the KPR, of which the magmatism had decayed or ceased at that time. The destruction mechanism of the KPR associated with the rifting of the PVB varies along strike the KPR. Adjacent to the triple-junction, the KPR was destroyed mainly due to the oblique intersection of the PVB rifting center. Whereas south of the triple-junction, the KPR was destroyed by the E-W-directional extensional faulting on its whole width.©2021 China Geology Editorial Office.     

松辽盆地西部斜坡英台地区姚二、三段辫状河三角洲沉积特征研究

松辽地区西部斜坡英台地区姚家组二、三段,是在干旱一半干旱、源近流短、东倾陡坡背景下,在洪积扇前,由辫状河入湖形成的辫状河三角洲沉积。可明显区分出狭窄的辫状河三角洲平原,河口坝不太发育的辫状河三角洲前缘和夹浊积砂的辫状河前三角洲三种沉积亚相。辫状河三角洲平原由灰色含砾砂岩,粗、中砂岩,少量细砂岩,粉砂岩夹紫红色泥岩组成。具有明显的正韵律为特征。辫状河三角洲前缘沉积为灰色-绿灰色中、粗砂岩、细砂岩、少量的含砾砂岩,成正韵律或反韵律夹在灰绿色、灰黑色泥质岩中。辫状河前三角洲沉积多为灰绿色、灰黑色泥质岩,可夹少量砂质浊积岩。上述沉积特征明显地区别于正常河流三角洲沉积和扇三角洲沉积。     

Geochemical Characteristics of Volcanic Rocks from ODP Site 794, Yamato Basin: Implications for Deep Mantle Processes of the Japan Sea

Deep mantle processes and the dynamic mechanism of magmatism in the Japan Sea Basin are important processes that have not been studied in detail. In this paper, systematic evaluation of basalt samples from the ocean drilling program Site 794 in the Japan Sea was performed, which included petrography, whole-rock major- and trace-element analysis, Sr-Nd-Pb isotopic composition, and electron microprobe analysis of plagioclase and clinopyroxene. These basalts belong to the tholeiitic series with porphyritic texture and massive Ca-rich plagioclase, clinopyroxene, and minor olivine phenocrysts. The basalts are characterized as flat rare earth elements and high-field-strength elements with remarkably low ratios of(La/Yb)N(0.75–2.51), significant positive anomalies of Ba, Sr, and Rb and no Eu anomaly(δEu = 0.99–1.36). The samples showed relatively high 87Sr/86Sr(0.70425–0.70522), 207Pb/204Pb(15.511–15.610), and 208Pb/204Pb(38.064–38.557) values and a low 143Nd/144 Nd ratio(0.51271–0.51295). The basalts from Site 794 can be divided into upper, middle, and lower volcanic rocks(UVR, MVR, and LVR) on the basis of their stratigraphic level. The MVR was geochemically derived from the depleted mantle, whereas the UVR and LVR originated from a nondepleted and relatively enriched mantle source with contributions from subducted Pacific plate fluid and sediments. Use of geothermobarometers indicates that the crystallization pressure for the UVR and LVR(6.25–11.19 kbar) was significantly higher than that of the MVR(3.48–5.84 kbar). The UVR and LVR may have been derived from the low-degree(5%–10%) partial melting of spinel lherzolite, while the MVR originated from a shallower mantle source with a high degree(10%–20%) of partial melting. In addition, the geochemical characteristics of the samples are consistent with a younger age(13–17 Ma) and the depleted composition of the MVR and an older age(17–23 Ma) and slightly enriched composition of the UVR and LVR. Therefore, temporal changes in the mantle source from old and enriched to young and depleted and subsequently to old and nondepleted may have been associated with progressive lithospheric extension and thinning, as well as at least two episodes of diverse asthenospheric upwelling and pull-apart tectonic motion in the Yamato Basin.     

Chronological Study of Coal-seam Water and its Implication on Gas Production in the South Qinshui Basin

The knowledge of the residence time of formation water is fundamental to understanding the subsurface flow and hydrological setting. To better identify the origin and evolution of coal seam water and its impact on gas storage and production, this study collected coalbed methane co-produced water in the southeast Qinshui Basin and detected chemical and isotopic compositions, especially 36Cl and 129I concentrations. The calculated tracer ages of 129I (5.2–50.6 Ma) and 36Cl (0.13–0.76 Ma) are significantly younger than the age of coal-bearing formation (Pennsylvanian - Cisuralian), indicating freshwater recharge after coal deposition. The model that utilises 129I/I and 36Cl/Cl ratios to constrain the timing of recharge and the proportion of recharge water reveals that over 60% of pre-anthropogenic meteoric water entered coal seams since 10 Ma and mixed with residue initial deposition water, corresponding to the basin inversion in Cenozoic. The spatial distribution of major ion concentrations reveals the primary recharge pathway for meteoric water from coal outcrops at the eastern margin to the basin center. This study demonstrates the occurrence of higher gas production rates from wells that accept water recharge in recent times and suggests the possible potential of the non-stagnant zones for high gas production.     

Rock magnetic properties and palaeomagnetic results of sediments from a stone implement layer in the Bose Basin,Guangxi

Directional samples were taken to study rock magnetism and palaeomagnetic records from the Dong- sheng profile, which is 5 m thick and on the northwest edge of the Bose Basin. Mineralogy and rock magnetism of typical samples indicate that coarse granular titanomagnetite, and fine-grained hematite, superparamagnetic maghemite formed by pedogenesis are in the sediment, which has undergone many transformative processes during different stages of pedogenesis. Parallel samples were taken for thermal demagnetization (TH) (0 to 680℃) and alternating field (AF) demagnetization (0 to 80 mT) respectively. Experimental results of these two kinds of demagnetization illustrate that there are two or more magnetic components in the samples. Intensity of NRM decreases by almost 60% to 90% rapidly when the temperature ranges from 100℃ to 350℃, with a steady magnetic component. It is impossible to analyze the magnetic components at high temperature because those fluctuate widely when the temperature is higher than 400℃. Steady magnetic components from 100℃ to 350℃ indicate that the remanence was mainly carried by fine-grained hematite formed by pedogenesis, reflecting a change in the geomagnetic field while the magnetite was being oxidized into hematite by chemical weathering after deposition. The formative age of the sediments cannot be obtained by magnetic methods in this profile.     

琼东南盆地华光凹陷天然气水合物稳定带厚度的影响因素

为了探讨琼东南盆地华光凹陷海底天然气水合物稳定带的分布规律,定量研究了静水压力、底水温度、地温梯度和气源组分对水合物稳定带的影响程度。在此基础上,分析了华光凹陷现今甲烷水合物稳定带的厚度分布。最后,综合各因素的历史演化过程,初步探讨了华光凹陷1.05 Ma BP以来天然气水合物稳定带的演化。结果表明:(1)气源组分和海底温度的变化对研究区内水合物稳定带的影响较大;水合物稳定带厚度与海底温度呈良好的线性负相关性。(2)水深超过600 m的海域具备形成天然气水合物的温压条件;超过600 m水深的海域水合物稳定带厚度大部分超过 100 m,其中西北部稳定带的最大厚度超过300 m,是有利的水合物勘探区。(3)华光凹陷1.05 Ma BP以来天然气水合物稳定带厚度经历了快速增厚–窄幅变化–快速减薄和恢复的过程。麻坑群与水合物稳定变化敏感区在空间上具有较好的叠合关系。结合前人的研究成果,推测其形成与天然气水合物的分解释放有关。