Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.     

四元体系Na~ ∥Cl~-,CO_3~(2-),B_4O_7~(2-)-H_2O 273K介稳相平衡研究

采用等温蒸发法研究简单四元体系Na ∥Cl-,CO32-,B4O72--H2O273K时的介稳相平衡,并测定该体系273K平衡液相中各组分的溶解度及密度,该体系的介稳相图和密度组成图显示:该四元体系在273K时的相图由3条溶解度单变量线、3个结晶区及1个共饱和点组成。体系属简单共饱型,无复盐或固溶体形成,3个结晶区分别对应单盐Na2CO3·10H2O,NaCl和Na2B4O7·10H2O。共饱点E处于Na2CO3·10H2O,NaCl及Na2B4O7·10H2O3盐共饱和,所对应的平衡液相组成为w(Na2CO3)=6.81%,w(NaCl)=21.69%,w(Na2B4O7)=0.65%,w(H2O)=70.85%。研究体系在273K下,Na2CO3·10H2O是碳酸钠盐的唯一析出形式,且硼酸钠对碳酸钠有盐析作用。     

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.     

川西南周公山及邻区下二叠统碳酸盐岩成岩作用对储集性的影响

川西南周公山及邻区下二叠统的中-低孔、中-低渗碳酸盐岩储层的储集空间以次生成因的溶孔、溶洞和构造裂缝为主.研究认为,多世代方解石胶结、化学充填作用以及埋藏期的压实(溶)作用是孔隙很难得到保存的主要原因;同生-准同生期的混合水云化作用和表生期、埋藏期的流体溶蚀作用则产生了大量的次生溶孔、洞,使储层的孔渗性得到明显的改善;构造破裂作用可以产生新的储集空间,还影响各储集体之间及单一储集体内部空隙的连通.成岩相分为混合水云化-溶蚀-破裂相、溶蚀-胶结相和胶结-压实-压溶相.各种成岩作用的叠加形成了现今下二叠统油气储层的分布格局.     

Application of Spectral Decomposition to Detection of Fracture-Cavity Carbonate Reservoir Beds in the Tahe Oiifieid, Tarim Basin, NW China

Ordovician fracture-cavity carbonate reservoir beds are the major type of producing formations in the Tahe oilfield, Tarim Basin. The seismic responses of these beds clearly changes depending on the different distance of the fracture-cavity reservoir bed from the top of the section. The seismic reflection becomes weak or is absent when the fracture-cavity reservoir beds are less than 20 ms below the top Ordovician. The effect on top Ordovician reflection became weaker with deeper burial of fracture-cavity reservoir beds but the developed deep fracture-cavity reservoir beds caused stronger reflection in the interior of the Ordovician. This interior reflection can be divided into strong long-axis, irregular and bead string reflections, and was present 80 ms below the top Ordovician. Aimed at understanding reflection characteristics, the spectral decomposition technique, which uses frequency to ＂tune-in＂ bed thickness, was used to predict Ordovician fracture-cavity carbonate formations in the Tahe oilfield. Through finely adjusting the processing parameters of spectral decomposition, it was found that the slice at 30 Hz of the tuned data cube can best represent reservoir bed development. Two large N-S-trending strong reflection belts in the mid-western part of the study area along wells TK440- TK427-TK417B and in the eastern part along wells TK404-TK409 were observed distinctly on the 30 Hz slice and 4-D time-frequency data cube carving. A small N-S trending reflection belt in the southern part along wells T403-TK446B was also clearly identified. The predicted reservoir bed development area coincides with the fracture-cavities connection area confirmed by drilling pressure testing results. Deep karst cavities occur basically in three reservoir bed-development belts identified by the Ordovician interior strong reflection. Spectral decomposition proved to be a useful technique in identifying fracture-cavity reservoir beds.     

中伊朗盆地Garmsar区块Qom组沉积微相及储层特征研究

伊朗Garmsar区块Qom组形成于碳酸盐岩台地沉积环境,岩性以生物屑灰岩、含砂生物屑灰岩、泥晶灰岩为主,是典型的裂缝~孔隙型储层。利用区内野外实测剖面资料和露头岩样测试资料,对Qom组沉积相进行标识及类型划分,并对Qom组沉积微相及其平面展布特征进行分析,指出了该区域开阔台地相~高能红藻滩微相和局限台地相~泻湖夹台内滩微相是研究区储层发育的有利部位。F段中部的粒内溶孔较为发育,而溶缝主要出现在C1、C3亚段,整个Qom组构造微裂缝不甚发育。但储层孔渗条件比较差,属于中~低孔、低渗~特低渗储层,且存在严重的不均一性。为此,从沉积相与储层特征角度研究认为,中伊朗盆地Garmsar区块Qom组油气勘探存在一定的风险。     

含盐量对松嫩平原碳酸盐渍土抗剪强度的影响

松嫩平原分布着大量的碳酸盐渍土,其不良的工程性质给穿越其中的道路质量造成不同程度的影响。由于盐渍土所含易溶盐成分主要为碳酸氢钠,该研究通过向碳酸盐渍土内加入碳酸氢钠制备不同含盐量的盐渍土,进行室内直剪试验。试验表明：随着含盐量的增加土的粘聚力减小,内摩擦角有先减小后变大的趋势;随着含水量的增加,土的含盐量越高,土的粘聚力减小越明显。易溶盐在土中的状态形式是影响其抗剪强度参数变化的一个重要原因。     

碳酸盐型磷矿的反浮选工艺研究

针对某碳酸盐型磷矿,采用反浮选工艺流程进行试验研究,获得了低镁优质磷精矿。反浮选工艺具有药剂种类少,分选效率高,选矿技术指标先进,操作控制容易等优点,是选别碳酸盐型磷矿的先进浮选工艺。     

Variation in the composition of Lake Bonneville marl: a potential key to lake-level fluctuations and paleoclimate

Lake Bonneville marl provides a stratigraphic record of lake history preserved in its carbonate minerals and stable isotopes. We have analyzed the marl in shallow cores taken at three localities in the Bonneville basin. Chronology for the cores is provided by dated volcanic ashes, ostracode biostratigraphy, and a distinctive lithologic unit believed to have been deposited during and immediately after the Bonneville Flood.A core taken at Monument Point at the north shore of Great Salt Lake encompasses virtually the entire Bonneville lake cycle, including the 26.5 ka Thiokol basaltic ash at the base and deposits representing the overflowing stage at the Provo shoreline at the top of the core. Two cores from the Old River Bed area near the threshold between the Sevier basin and the Great Salt Lake basin (the main body of Lake Bonneville) represent deposition from the end of the Stansbury oscillation ( 20 ka) to post-Provo time ( 13 ka), and one core from near Sunstone Knoll in the Sevier basin provides a nearly complete record of the period when Lake Bonneville flooded the Sevier basin (20–13 ka).In all cores, percent calcium carbonate, the aragonite to calcite ratio, and percent sand were measured at approximately 2-cm intervals, and ¹⁸O and ¹³C were determined in one core from the Old River Bed area. The transgressive period from about 20 ka to 15 ka is represented in all cores, but the general trends and the details of the records are different, probably as a result of water chemistry and water balance differences between the main body and the Sevier basin because they were fed by different rivers and had different hypsometries. The Old River Bed marl sections are intermediate in position and composition between the Monument Point and Sunstone Knoll sections. Variations in marl composition at the Old River Bed, which are correlated with lake-level changes, were probably caused by changes in the relative proportions of water from the two basins, which were caused by shifts in water balance in the lake.This is the second paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.     

Form, function and feedbacks in a tidally dominated ooid shoal, Bahamas

Although the general aspects of oolitic depositional systems are well documented, seascape‐scale (≈10³–10⁶ m²) patterns of oolitic shoals and the details of processes acting on them are not well understood or quantified. To begin to fill this basic gap in understanding, this paper describes the morphology and hydrodynamics of Lily Bank, a Modern tidally dominated Bahamian ooid shoal. In this study, integrating remote sensing imagery with quantitative, geo‐located bathymetrical, hydrological and granulometric data in a Geographic Information System documents geomorphic and sedimentological patterns and facilitates interpreting these patterns in the context of the processes operating in this system. The results of these analyses reveal that parabolic bars up to several kilometres in wavelength and several metres in height form a common morphologic motif, although there is considerable variation on that general theme. The seascape‐scale configuration of bars and superimposed sedimentary structures is closely linked to spatial patterns of tidal movements, and includes the presence of mutually evasive flood and ebb channels. Sedimentologically, bars are neither homogenous nor random bodies; instead, granulometric parameters such as sorting and percentage mud vary systematically, as shaped by hydro‐geomorphic controls. The best sorted, coarsest ooids are on bar crests, whereas the finest grains are found in the lower energy, deeper interior and flanking regions. In short, results clearly document hydrodynamic‐bathymetrical influences on these ooid shoals and their granulometry, linkages akin to siliciclastic analogues. Sedimentological, hydrodynamic and geomorphic observations are consistent with a conceptual model for the formation of parabolic bars in which initial irregularities in non‐parabolic bars are enhanced through their effect of focusing flow. Constricted flow leads to higher flow velocities, tidal flow velocity asymmetries, differential net sediment transport and growth of bathymetrical highs. This bathymetrical divergence creates separate paths for flood‐ and ebb‐tides, facilitating emergence of better‐developed parabolic forms. The resultant parabolic geometries and component bedforms appear to be either in dynamic equilibrium with both ebb‐ and flood‐tide flows, or evolving toward that state. In exploring patterns and processes within carbonate shoals, this study illustrates some of the first documented insights on quantitative details of morphology and dynamics and in the links between geomorphic framework and grain‐size and sorting in an oolitic carbonate system. Assuming a continuity of processes between ancient and modern, the insights from this shoal provide information on possible facies geometries and on the characteristics of grains and depositional porosity of analogous facies within ancient ooid shoals.