流体不混溶性和流体包裹体

大多数流体包裹体是捕获于均匀体系,但有一部分包裹体捕获自非均匀体系(不混溶体系)。在自然界存在着许多不混溶的过程,这包括基性岩浆和酸性岩浆之间,岩浆与热液,岩浆与CO₂,盐水溶液与CO₂等。液体的不混溶性对于成矿作用十分重要,这方面有3个典型的例子,第一个是金矿的成矿作用与NaCl-H₂O-CO₂体系流体的不混溶有着重大的关系;第二个例子是斑岩铜矿;第三个例子是伟晶岩,发现在伟晶岩演化和成矿作用中存在着岩浆和热液的不混溶作用。实际上不混溶的大部分证据是从流体包裹体的研究中获得的。现在的问题是如何来确定哪些包裹体是从不混溶过程中捕获的。这种捕获于不混溶过程中的流体包裹体怎么来确定他的T_h和成分。这种捕获于不混溶过程中的流体包裹体怎么与"卡脖子"拉伸作用"中捕获的包裹体和捕获自均匀体系的流体包裹体相区分。     

南岭寨背和陂头花岗岩基属印支期侵位的岩浆动力学证据及构造意义

文章通过对南岭东段寨背和陂头岩基地质-岩石地球化学特征研究,判明它们的侵位深度(7.5 km)、围岩温度(250℃)及岩浆初始温度(950℃),建立起寨背-陂头岩基的数学计算模型,并计算得出:寨背和陂头花岗岩熔体侵位后,其初始温度降低至结晶温度所需的时间(Δtcol)分别为4.04 Ma(寨背岩基)和3.97 Ma(陂...     

吐格尔明背斜核部花岗岩的年代学、地球化学与构造环境及其对塔里木地块北缘古生代伸展聚敛旋回的揭示

塔里木盆地北缘库车坳陷东部地区吐格尔明背斜核部花岗岩发育,该套花岗岩侵位于以云母石英片岩为主的元古界基底岩系中,上覆的三叠系以角度不整合与其接触。本区花岗岩的研究对揭示库车地区的基底性质与构造演化历史具有重要意义。对吐格尔明花岗岩锆石的U-Pb年代学和岩石地球化学的研究表明, 吐格尔明背斜核部的花岗岩锆石为典型岩浆成因锆石,其锆石SHRIMP U-Pb定年结果分别为626.4±5.2Ma~643.3±4.0Ma,表明它们的形成时代为新元古代晚期埃迪卡拉纪早期。该套花岗岩的SiO₂ (67.95%~78.59%)和Al₂O₃ (11.81%~16.21%) 含量均很高,A/CNK在1.2~1.6,为硅和铝过饱和类型,属典型的过铝质花岗岩;稀土元素总量为106×10^-6~207×10^-6,稀土元素配分曲线呈右倾型,具有明显的负Eu异常;高场强元素(Ta、Nb、Ti等)具有明显的负异常,大离子亲石元素(Rb、Ba、Sr等) 具有明显的正异常。吐格尔明花岗岩是由地壳物质在底侵热源或构造动力作用下引起的局部熔融形成的,属典型的壳源成因类型,形成于挤压环境向伸展环境转化阶段,推测塔里木北缘在震旦纪已开始伸展,代表了古亚洲洋早期的伸展构造环境。实验测得花岗岩钾长石⁴⁰Ar/³⁹Ar年龄平均为291.4~255.8Ma,代表了花岗岩的隆升剥蚀年龄,反映出吐格尔明花岗岩在二叠纪受到挤压发生剥露的过程。因而从年代学框架上更好地约束了塔里木地块北缘在古生代由伸展裂解到聚敛隆升的构造旋回。     

新疆东准噶尔老鸦泉富碱花岗岩型锡矿床地质及成矿流体

老鸦泉碱性花岗岩位于新疆北部东准噶尔地区。老鸦泉碱性花岗岩体及其内卡姆斯特、干梁子锡矿床的矿石和岩石的岩矿鉴定、稀土元素以及流体包裹体的系统研究表明,老鸦泉碱性花岗岩及其内的花岗斑岩及含矿石英岩、云英岩化锡矿体、石英脉锡矿体,实际上是富碱花岗质岩浆逐渐分异演化的同源和最终产物,锡成矿流体为中-高温、低盐度。碱性岩浆晚期分异的大量气水热液富锡、富硅、富碱、富含F、Cl、SO²₄离子及离子团,其氧逸度高、酸度高、温度高,这种热液引起花岗岩体的硅化、云英岩化等自变质作用,在该作用中随温度、压力的降低及CH₄等还原性气体及CO₂气体的逃逸,改变了成矿流体的氧化-还原环境,流体向相对还原及碱性条件转化,在新的氧化还原、酸碱度界面条件下,其携带的锡的络合物不稳定而分解,锡沉淀成矿。     

Neoproterozoic granites of the Lajeado intrusive suite,north-center Brazil: A late Ediacaran remelting of a Paleoproterozoic crust

In north-central Brazil, a number of granite plutons, which intrude Paleoproterozoic gneiss-granulite terrains of the Goiás Massif, crop out along a thermal axis parallel to the Transbrasiliano Lineament. Single zircon lead evaporation ages from three granitic bodies span between 552 and 545 Ma. Sm–Nd model ages (T_DM) vary between 2.1 and 1.7 Ga and negative εNd_{(0.55 Ga)} values between −10 and −13 show that Paleoproterozoic crust was involved in the genesis of these granites. These plutons, which form the Lajeado Intrusive Suite are part of an important Ediacaran magmatic event in central-northern of the Tocantins Tectonic Province, composed of metaluminous to slightly peraluminous granites with geochemical characteristics similar to A-type granites, whose crystallization occurred under low water activity during magmatic emplacement. The granitic intrusive bodies are related to a crustal extensional/transtensional tectonic event at the end of the Neoproterozoic. They may have connection with the granitic plutons of similar age (0.56–0.52 Ga) in northwestern Ceará state, on the other side of the Paleozoic Parnaíba Basin in northwest of Borborema Province, along the Transbrasiliano Lineament.     

Leaching behavior of Li and Ga from granitic rocks and sorption on kaolinite: Implications for their enrichment in the Jungar Coalfield,Ordos Basin

The granite collected from the Yinshan Mountain and kaolinite has been selected for the leaching and adsorption experiment,respectively,aiming to clarify the enrichment processes of Li and Ga during the deposition.Results suggest both Li and Ga could be leached out from granite by using different acid solutions of different p H and kaolinite can adsorb Li and Ga with varying degrees.Lithium and Ga had the highest leaching ratio when p H=1.Special geological events(e.g.volcanic eruptions and wildfires),which could result in very low p H values of water in peatland,may have accelerated the release of Li and Ga from the source rocks.Kaolinite has the highest adsorption fraction was obtained at p H=8.The different characteristics of Li and Ga displayed in the leaching and adsorption experiments probably result from the different occurrences and enrichment processes of Li and Ga in the coals.Lithium was probably enriched before the Li carriers(e.g.kaolinite)had been transported into paleomires because of its high leaching ratio and high adsorption fraction under neutral and alkaline conditions,whereas Ga was more likely concentrated by kaolinite and other carriers after it had been transported into the peat mires.     

Anatomy of garnets in a Jurassic granite from the south-eastern margin of the North China Craton: Magma sources and tectonic implications

The Late Jurassic Jingshan granite located at the south-eastern margin of the North China Craton contains abundant garnets which can be subdivided into three types based on texture and composition: (i) euhedral garnet in mafic biotite and garnet rich enclave (Grt I), (ii) coarse-grained garnet (Grt II) in the host granite, and (iii) small euhedral garnet in aplite (Grt III). In general, Grt I has higher FeO, CaO and lower MnO contents than Grt II. Grt III has higher Mn, but lower Ca contents than others. Grt I has lower MREE and HREE contents than Grt II. Grt III has prominent and distinctly negative Eu anomaly as well as higher MREE composition compared to the others. Systematic variations in oxygen isotope compositions are observed among the three garnet types, with δ¹⁸O values of <3.8‰ in most of Grt I, 3.8–4.7‰ in most Grt II (for inclusion-free garnets), and typically >4.7‰ in Grt III. Some of the Grt II and Grt III display two distinct zonings with cores having similar major and trace element compositions to Grt I.Cathodoluminescence (CL) images revealed that the zircons from different garnet-bearing samples possess fine-scale oscillatory zoned magmatic rims with inherited cores. In situ zircon U–Pb dating and trace element analyses show that the dark-luminescent magmatic rims all have Jurassic concordia ages (∼160 Ma) and similar trace element patterns. Most of the inherited cores also display similar Triassic ages of 210–236 Ma, which is similar to the ages of ultrahigh pressure (UHP) metamorphic rocks of the Dabie–Sulu orogen (230 Ma). In addition, Jurassic concordia ages were also found in a zircon inclusion in Grt I, implying that the Grt I was formed shortly before the main magmatic event. The age data suggest that the three different garnet types may be genetically related and modified by cogenetic magmatic events.Based on the zircon U–Pb ages from different garnet-bearing samples, the major element, trace element, oxygen isotope, and zoning textures of the three kinds of garnet we suggest that Grt I may be peritectic garnet, whereas Grt II and III are probably the results of magmatic dissolution–precipitation processes and re-equilibration of garnets with changing magmatic conditions during melting, differentiation, crystallization, and cooling within the granite. We conclude from the oxygen isotopic character of the garnets and ages of the zircons that the source rocks for the Jingshan granites are from Dabie–Sulu orogen representing the South China Craton.     

新疆尼勒克县圆头山后碰撞花岗斑岩的同位素年代学及地球化学特征

圆头山黑云母花岗斑岩位于尼勒克县城南,岩体普遍发育的铜矿化,以中部碎裂带中矿化最强。岩石具有典型的斑状结构,斑晶由碱性长石和黑云母组成,基质以长石、云母和石英为主,并含有少量的硫化物。圆头山黑云母花岗斑岩的轻重稀土分馏明显,并且明显富集大离子亲石元素(LILE) (除Sr外)和Pb,同时亏损高场强元素(HFSE)和Nb、Ta、P、Ti,显示出弧火山岩的地球化学特征。圆头山黑云母花岗形成年龄为269±3Ma,其源区以具有弧火山岩特征的下地壳为主,同时含有少量的幔源物质,而且在岩体的侵位过程中有高(⁸⁷Sr/⁸⁶Sr)_i (0.706054~0.709228)和高Pb含量(5.05×10^-6~32.5×10^-6)的陆壳物质混染。在下地壳物质熔融过程中,位于下地壳底部的富水和成矿元素的MASH带物质也被圈入,使原始岩浆富水和成矿物质。圆头山黑云母花岗斑形成于碰撞后阶段,岩石的形成主要受岩石圈地幔拆沉作用的控制,而岩石圈地幔的拆沉可能与中亚造山带的垮塌或塔里木地幔柱活动有关。     

延边地区花岗岩的成因类型及其形成的大地构造环境

延边地区地处吉林省的东部。研究区南部为渤海地块 ,北部为兴凯地块 ,东部与朝鲜和俄罗斯相毗邻 ,西部与吉中地区以敦化 -密山断裂为界。本文主要讨论本区古亚洲洋构造演化阶段所形成的花岗岩类问题 ,并据此对渤海地块与兴凯地块之间的增生、碰撞、缝合等问题进行探讨。