Isotopic Ages of the Carbonatitic Volcanic Rocks in the Kunyang Rift Zone in Central Yunnan, China

The Mesoproterozoic Kunyang rift, which is located on the western margin of the Yangtze platform and the southern section of the Kangdian axis, is a rare massive Precambrian iron-copper polymetallic mineralization zone in China. The Mesoproterozoic Wulu (Wuding-Lufeng) basin in the middle of the rift is an elliptic basin controlled by a ring fracture system. Moreover, volcanic activities in the basin display zonation of an outer ring, a middle ring and an inner ring with carbonatitic volcanic rocks and sub-volcanic dykes discovered in the outer and middle rings. The Sm-Nd isochron ages have been determined for the outer-ring carbonatitic lavas (1685 Ma) and basaltic porphyrite of the radiating dyke swarm (1645 Ma) and the Rb-Sr isochron ages for the out-ring carbonatitic lavas (893 Ma) and the middle-ring dykes (1048 Ma). In combination of the U-Pb concordant ages of zircon (1743 Ma) in trachy-andesite of the corresponding period and stratum (1569 Ma) of the Etouchang Formation, as well as the Rb-Sr iso     

地下水中铜元素的迁移富集及其控制因素

研究了地下水中铜元素迁移富集的主要控制因素及其分布规律。结果表明，地下水铜元素的迁移富集与含水介质及其上覆土层中的铜元素含量、地下水的酸碱度、地下水的径流条件和氧化还原环境等有密切的关系。     

福建上杭铜矿沟—萝卜岭斑岩型铜矿床地质特征及远景评价

上杭县铜矿沟和萝卜岭矿段组成一个斑岩型铜矿床．萝卜岭矿段位于花岗闪长斑岩北东端的前峰部位，铜矿沟则是其往南西深部的延伸，通过对铜矿沟—箩卜岭斑岩型铜矿床地质特征的研究，认为铜矿沟斑岩型铜矿埋藏总体较浅、品位较低、厚度稳定且较厚，对于指导该区寻找浅部斑岩型铜矿具有重要的意义。     

与斑岩型铜矿有关的角砾岩(筒)

斑岩型铜矿床是重要的铜矿类型，在已探明的铜储量中斑岩型铜矿居首位。研究认为，在板块构造的敛合带上，斑岩铜矿发育地区，常见有角砾状地质体和角砾岩筒。这些角砾状地质体和角砾岩筒对矿化与謇集起着重要作用，是斑岩铜矿的重要找矿标志，有时其本身就是铜矿体。本文中从理论与野外工作相结合的角度，总结了与斑岩型铜矿床有关的角砾状地质体和角砾岩筒的类型及地质特征，通过具体实例介绍了与斑岩铜矿有关的角砾岩筒的找矿思路与方法，适宜野外工作的实际应用。     

新疆铜矿类型与找矿靶区

在分析研究新疆铜矿类型、地质特征、矿区地质构造及找铜潜力的基础上，对进一步的找铜靶区进行了初步预测．新疆铜矿工作程度总体较低，各构造成矿区和类型都有找铜前景，最具潜力和最有希望找到大型铜矿床的是阿尔泰，东、西天山和西昆仑地区斑岩型、海相火山沉积型、斑岩—夕卡岩复合型、海相沉积热液叠加型与铜镍矿化物型的成矿类型．     

云南兰坪-思茅盆地脉状铜矿床铅、硫同位素地球化学与成矿物质来源研究

云南兰坪-思茅盆地中一新生代砂页岩中赋存有许多脉状铜矿床。本文对盆地内从北至南三个典型脉状铜矿床(金满、水泄和白龙厂)进行了详细的铅、硫同位素研究，探讨了该类型矿床的成矿物质来源。分析表明。该类型矿床的铅同位素组成总体变化较小，且均位于上地壳铅演化线附近，说明成矿流体中铅具有稳定的上地壳来源。各矿床由于赋矿层位不同，矿石铅同位素组成表现出一定差异，如由兰坪盆地侏罗纪地层中的金满矿床到思茅盆地二叠纪地层中的白龙厂矿床，铅同位素比值(^207Pb/^204Pb)呈增高趋势，这表明这类矿床的铅主要来源于围岩地层，且地层越老，提供的铅就相对富含放射成因铅。矿床中脉石矿物重晶石、铁白云石等的锶同位素组成也表明，金满矿床成矿流体的^87Sr／^86Sr比值较高(0．70874—0．71232)，而白龙厂矿床的^87Sr／^86Sr比值较低(0．70829—0．70938)，接近于围岩灰岩的值(0．70755)。硫同位素研究表明，金满矿床中硫化物的δ^34S值变化最大，为-20．5‰- 7．0‰。水泄矿床中硫化物的δ^34S值变化最小，为-0．1‰- 4．2‰。而白龙厂矿床中硫化物的δ^34S值为-14．3‰--3．6‰。水泄和白龙厂矿床中重晶石的δ^34S值分别为 12．3‰- 19．0‰和 13．1‰，它们与盆地中蒸发岩层中石膏的δ^34S值( 10．8‰- 15．7‰)相近。分析表明，兰坪-思茅盆地中脉状铜矿的硫源主要来源于盆地热卤水萃取的地层中蒸发岩硫酸盐，它们通过有机质的热分解反应还原为沉淀硫化物所必需的低价硫。各矿床独特的硫同位素组成还表明它们的硫源受局部地层硫源和成矿流体物理化学性质所控制。本文提出大气降水起源的盆地热卤水通过对围岩中新生代地层的淋滤和萃取，获得了成矿所需的金属和硫，并在构造薄弱部位沉淀形成了本区的脉状铜矿床。     

新疆东天山地区土屋、延东铜矿地球化学特征与异常查证方法

对土屋地区干旱荒漠景观地球化学条件和勘查地球化学方法进行了分析，对比研究了不同比例尺地球化学异常特征及对矿床的反映能力，指出了该区铜元素是预测铜矿的最重要的指示元素，论证了在区域铜高背景区和异常区开展1：5万化探是进一步定性、定位预测矿区、矿床的重要环节，提出了东天山地区经济、有效的地球化学勘查和异常查证方法技术组合。     

易门式大型铜矿床构造成矿动力学模型

针对金属矿床隐伏矿定位预测的关键问题,在提出构造成矿动力学的分支学术方向的基础上,以易门式大型铜矿床为例,从成矿地质背景、矿田构造、构造地球化学和成矿构造应力场等方面进行构造成矿动力学研究,阐述在构造应力场控制下成矿流体运移和聚集的规律。构造地球化学研究认为,构造地球化学异常反映矿体的原生晕;构造地球化学异常受构造控制,其分带特征可指示成矿流体的流向,并提供矿床成因和隐伏矿(化)体相对埋深的信息。构造应力场的控矿特征主要表现在:构造应力场导致控矿构造的形成,并驱动成矿流体的运移;构造应力场控制了成矿能量场;应力和能量的高值集中区分布特点可反映某些构造型式。在此基础上建立构造成矿动力学模型,概括隐伏矿成矿预测准则,据此提出若干重点找矿靶区和靶位,其中部分靶区得到工程验证,表明构造成矿动力学方法对隐伏矿定位预测和评价具有重要的指导意义。     

Adsorption of Copper, Nickel, and Cadmium on Goethite in the Presence of Organic Ligands

Adsorption of copper, cadmium and nickel at low concentrations on goethite was studied in the presence of the simple organic ligands oxalate, salicylate, and pyromellitate. The experimental metal adsorption behavior was compared to calculations with a surface complexation model to evaluate the most important interactions. Oxalate mostly decreased Cu and Ni adsorption at high pH-values by competition between solution and surface complexation but had no effect on Cd adsorption. Cu adsorption in the presence of oxalate below pH 6 could best be described by defining a ternary complex of type A (surface-metal-ligand). Salicylate had only minor effects on metal adsorption. The adsorption of Cu in the presence of salicylate above pH 5 could be explained by a ternary complex of type A. Pyromellitate increased the adsorption of Cu and Cd in the acidic pH-range, likely by formation of ternary surface complexes of type B (surface-ligand-metal).     

Geochemical Characteristics of Granitoids of the Erdenet Porphyry Copper Deposit, Mongolia

Abstract. The Erdenet porphyry copper deposit is one of the major mineral deposits in Mongolia. The geochemical data of granitoids acquired for the Erdenet and its surrounding areas are re-examined. The granitoids of the Erdenet deposit with hypogene type mineralization show the lowest TiO₂ content. Although Ti was possibly lost through the pyritization, it is also possible that the hypogene type mineralization occurred accompanied with the most differentiated granitoids. The variation of the element contents related to the mineralization of the Erdenet deposit shows the decrease of MgO and CaO contents, rather constant K₂O content, rather constant to decrease of Na₂O content, with respect to the Cu contents. The rather constant Na₂O in the mineralized zone is owing to the residual albite against the sericitic alteration. The granitoids of the Erdenet area show an increase of Na₂O content and a decrease of K₂O content with an increase of SiO₂ content. This trend makes clear contrast to granitoids in the surrounding areas. The granitoids of the Erdenet area might have the adakitic nature based on the Sr and Y contents.