土壤中铅铜锌镉的吸附特性

以徐州王庄矿（WZK）、奎河（KH）、背景-1（BG-1）和背景-2（BG-2）等4个土壤样品为供试对象，加入不同浓度梯度的铅、铜、锌、镉离子，通过静态实验研究了铅、铜、锌、镉的吸附特性。结果表明，土壤对4个重金属的吸附量与加入到土壤中的重金属离子浓度呈正相关性，它们之间大部分满足线性相关关系。在4个土壤样品中加入铅、铜、锌、镉离子的初始浓度比为10：10：10：1时，平衡浓度为Czn〉Ccu〉CPh〉Ccd，吸附量为Scd〉SPh〉Scu〉Szn，4个土壤样品对铅、铜、锌、镉离子的吸附能力依次为WZK〉KH〉BG-2〉BG-1。在所选实验条件下，土壤对铅、铜、锌、镉的吸附能力受土壤中铅、铜、锌、镉的含量、土壤有机质含量、阳离子交换量、土壤饱和含水量和土壤的pH值影响较大。     

火焰原子吸收光谱法测定铜精矿中银含量的测量不确定度评定

采用《测量不确定度评定与表示指南》，以火焰原子吸收光谱法测定铜精矿中的银含量为例，对测量结果进行不确定度评定。分析了不确定度的重要来源，包括称样质量、标准工作溶液、工作曲线拟合、试液定容体积及测量重复性等引入的不确定度分量组成。对各不确定度分量进行分析计算，求得标准不确定度为1．56，扩展不确定度为3．12。     

滇东北含铜矿床峨眉山玄武岩组地层学特征

滇东北与玄武岩有关的铜矿床是我国近年来矿床学研究和资源勘查的热点之一。通过对该地区进行的资源勘查和科学专项研究,发现含矿岩系主要由上二叠统峨眉山玄武岩组(P3e)上部(第三岩性段顶部和第四岩性段)和宣威组(P3x)底部地层组成,在这套地层中识别出5个矿化层,对5个矿化层的岩性组成、矿化特征和成矿前景进行全面总结,为该区域进一步开展找矿勘查和评价提供了方向和依据。     

云南因民铁铜矿区辉长岩类中黑云母-金红石化特征及其指示意义

对云南因民铁铜矿区深部辉长岩类中金红石、黑云母、碳酸盐和绿泥石的矿物地球化学特征进行研究,以探讨赋存于辉长岩类中的铁氧化物铜金型矿(化)体的成岩成矿环境。金红石由岩浆结晶和多期蚀变作用形成,其结晶温度为820~1 082 ℃,多期蚀变温度为444~730 ℃,金红石与黑云母密切共生;黑云母可划分为原生高钛镁质黑云母、热液蚀变镁质黑云母和铁质黑云母,形成温度分别为653~750 ℃、525~619 ℃和551~577 ℃,氧逸度均位于Ni NiO缓冲剂附近,表明黑云母形成于高温强氧化环境,有利于金红石化;铁白云石-菱铁矿化揭示了强还原环境,交代蚀变金红石;绿泥石多由铁镁矿物蚀变形成,形成于中低温(174~243 ℃)、低氧逸度(-4468~-5142)和高硫逸度(-1442~-1976)的强还原环境,有利于金属硫化物形成。本区岩浆结晶演化和黑云母-金红石化蚀变具有高温强氧化地球化学岩相学特征,有利于钛、铁矿化,后期叠加中低温强还原地球化学岩相,为IOCG矿床成矿的有利地球化学岩相学类型。     

The Chalukou deposit in the North Great Xing’an Range of China: A protracted porphyry Mo ore-forming system in a long-lived magmatic evolution cycle

The Chalukou deposit is located in the North Great Xing’an Range of the Xing’an-Mongolia Orogen bordering and to the northeast of the North China Craton. The deposit is a high-F-type porphyry Mo deposit hosted by the Chalukou composite igneous body containing small intrusive bodies genetically related to Mo mineralization. The composite igneous body includes pre-mineralization dolerite, monzogranite and syenogranite, syn-mineralization rhyolitic porphyry, granitic porphyry and fine-grained monzogranite, and post-mineralization rhyolitic porphyry, quartz porphyry, dioritic porphyry and andesitic porphyry. Detailed laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon dating of the igneous components of the composite igneous body was carried out to determine the temporal framework for magmatism in the Chalukou region. The new LA-ICP-MS U-Pb ages constraint documented here, together with the published ages, indicate that there was a protracted porphyry Mo ore-forming event of approximately 7 million years between ca. 152 when the ore related rhyolitic porphyry was emplaced and ca.145 Ma when molybdenite ceased being deposited. The dating reveals that the mineralization is a part of relatively long-lived magmatic cycle involving the emplacement of small doleritic stocks at ca. 165 Ma that progressively evolved into extensive granitic intrusions at ca. 164 Ma, and then diminished with the emplacement of mineralization-related porphyries to ca. 152 Ma. The emplacement of barren Early Cretaceous magmatism, represented by volcanic units in the ca. 136 Ma Guanghua Formation and porphyries, followed the mineralized magmatism.The syn-mineralization porphyry units associated with Mo contain zircons assaying ∼15 times higher in U and Th than the pre-mineralization magmatic phases. This indicates that there was a significant enrichment of Mo, U and Th in the magma, and directly associated with ore fluid exsolution. The return to their normal levels in the three elements in the post-mineralization magmatic phases indicates that they were exhausted from the magma chamber in the later phases. A genetic model is proposed for the enormous introduction of ore metals and enrichment at the Chalukou deposit. The protracted and multiphase igneous activity during the long-lived magmatism reflects a multistage enrichment of metal, and may play a crucial role in the formation of a volatile-enriched, fertile and large-volume magma chamber beneath the Chalukou deposit. Such a chamber is envisaged to be required for the formation of porphyry Mo deposits in general.     

Cenozoic metallogeny of Greece and potential for precious,critical and rare metals exploration

The Cenozoic metallogeny in Greece includes numerous major and minor hydrothermal mineral deposits, associated with the closure of the Western Tethyan Ocean and the collision with the Eurasian continental plate in the Aegean Sea, which started in the Cretaceous and is still ongoing. Mineral deposits formed in four main periods: Oligocene (33–25 Ma), early Miocene (22–19 Ma), middle to late Miocene (14–7 Ma), and Pliocene-Pleistocene (3–1.5 Ma). These metallogenic periods occurred in response to slab-rollback and migration of post-collisional calc-alkaline to shoshonitic magmatism in a back-arc extensional regime from the Rhodopes through the Cyclades, and to arc-related magmatism along the active south Aegean volcanic arc. Invasion of asthenospheric melts into the lower crust occurred due to slab retreat, and were responsible for partial melting of metasomatized lithosphere and lower crustal cumulates. These geodynamic events took place during the collapse of the Hellenic orogen along large detachment faults, which exhumed extensive metamorphic core complexes in mainly two regions, the Rhodopes and the Cyclades. The detachment faults and supra-detachment basins controlled magma emplacement, fluid circulation, and mineralization.The most significant mineralization styles comprise porphyry, epithermal, carbonate-replacement, reduced intrusion-related gold, intrusion-related Mo-W and polymetallic veins. Porphyry and epithermal deposits are commonly associated with extensive hydrothermal alteration halos, whereas in other cases alteration is of restricted development and mainly structurally controlled. Porphyry deposits include Cu-Au-, Cu-Mo-Au-Re, Mo-Re, and Mo-W variants. Epithermal deposits include mostly high- and intermediate-sulfidation (HS and IS) types hosted in volcanic rocks, although sedimentary and metamorphic rock hosted mineralized veins, breccias, and disseminations are also present. The main metal associations are Cu-Au-Ag-Te and Pb-Zn-Au-Ag-Te in HS and IS epithermal deposits, respectively. Major carbonate-replacement deposits in the Kassandra and Lavrion mining districts are rich in Au and Ag, and together with reduced intrusion-related gold systems played a critical role in ancient economies. Finally hundreds of polymetallic veins hosted by metamorphic rocks in the Rhodopes and Cyclades significantly add to the metal endowment of Greece.     

新疆包古图斑岩铜矿伴生元素金和银赋存状态初步研究

新疆西准噶尔包古图斑岩铜矿床Au平均含量0.25g/t,Ag为2.56g/t,Cu为0.30%,属于富金斑岩铜矿。伴生金和银矿化作用有两期:早期为斑岩矿化,形成了Cu-Mo-Au矿化组合,是主矿化期;后期叠加了Cu-Au-Ag-Te-Bi矿化,规模不大,出露于矿床的局部部位,但对矿石起到了加富作用。通过对钻孔薄片和光薄片的镜下观察及电子探针成分分析,认为早期矿化中Au和Ag主要呈固溶体形式存在于硫化物中,分布比较均匀,基本上不出现独立矿物,Au含量明显高于Ag;晚期矿化形成了复杂的Cu-Au-Ag-Te-Bi矿物,矿石呈浸染状和脉状叠加在早期矿化之上,以银矿物为主,与多种碲铋类矿物共生,主要银矿物有碲银矿、铋-碲银矿(?)、银-辉碲铋矿(?)、银-硫铋铜矿、银金矿等。晚期矿化规模不大,但对于提高矿床的经济价值具有重要意义。     

Weights of Evidence Modeling of Mineral Potential: A Case Study Using Small Number of Prospects,Abra, Philippines

Weights of evidence (WofE) modeling usually is applied to map mineral potential in areas with large number of deposits/prospects. In this paper, WofE modeling is applied to a case study area measuring about 920 km² with 12 known porphyry copper prospects. A pixel size of 100 m × 100 m was used in the spatial data analyses to represent in a raster-based GIS lateral extents of prospects and of geological features considered as spatial evidence. Predictor maps were created based on (a) estimates of studentized values of positive spatial association between prospects and spatial evidence; (b) proportion of number of prospects in zones where spatial evidence is present; and (c) geological interpretations of positive spatial association between prospects and spatial evidence. Uncertainty because of missing geochemical evidence is shown to have an influence on tests of assumption of conditional independence (CI) among predictor maps with respect to prospects. For the final predictive model, assumption of CI is rejected based on omnibus test but is accepted based on a new omnibus test. The final predictive model, which delineates 30% of study area as zones with potential for porphyry copper, has 83% success rate and 73% prediction rate. The results demonstrate plausibility of WofE modeling of mineral potential in large areas with small number of mineral prospects.     

滇西兰坪盆地西缘铜矿床矿物流体包裹体研究

滇西兰坪中新生代盆地西缘发育众多的铜多金属矿床，主要以脉状或透镜状赋存于由砂岩、粉砂岩和页岩组成的含盐红色碎屑岩建造中，或产于火山岩中。本文在前人工作基础上，对区域3个代表性矿床进行了系统的矿物流体包裹体地球化学研究，结果表明：区域铜矿床矿物流体包裹体类型简单，以气液两相包裹体和液相包裹体为主；均一温度不高，显示成矿为中低温度；流体包裹体成分显示为a^＋（K^＋）＋Ca^2＋Cl^-＋SO^2-4型，表明成矿流体主要是以大气降水补给的热卤水；成矿流体气相组成主要为H2O和CO2，还原性烃类气体的存在并与氧化性气体的反相关关系显示其与盆地有机质的密切关系及在成矿过程中的重要性。结合成矿地质背景及矿物氢氧同位素的分析，认为该带中的矿床地幔物质参与成矿是次要的，成因上应为受深断裂控制的、大气降水补给的热卤水型矿床。