石英尾砂对旱地表土磁性的影响及其环境意义

对安徽省凤阳县石英尾砂、受尾砂影响的表土、旱地表土和城镇表土进行了磁学测量,结果表明这4类样品的磁性特征明显不同。尽管这4类样品的磁化率均由磁铁矿主导,但旱地表土中可能含少量磁赤铁矿,石英尾砂、受尾砂影响的表土和城镇表土中可能含少量铁的氢氧化物（如纤铁矿）,受尾砂影响的表土中还含少量赤铁矿。城镇表土中磁铁矿的含量明显高于其他3类样品,受尾砂影响的表土中的磁铁矿含量介于石英尾砂和旱地表土之间。城镇表土中磁铁矿的粒径范围较宽,小于1 μm,石英尾砂中磁铁矿的粒径大于0.1 μm,旱地表土中磁铁矿的粒径小于0.1 μm,受尾砂影响的表土中磁铁矿的粒径介于旱地表土与石英尾砂的粒径之间。城镇表土的磁化率与频率磁化率呈负相关,旱地表土的磁化率与频率磁化率呈正相关,而受石英尾砂影响的表土的磁化率与频率磁化率没有明显的相关关系。在城市工业和交通等人类活动的影响下,城镇表土的磁性较旱地表土增强。而在石英砂生产这一人类活动的影响下,受尾砂影响的表土的磁性较旱地表土减弱,这是由石英尾砂中磁性矿物的含量较旱地表土4的少所致。     

贵州锦丰（烂泥沟）金矿床含砷黄铁矿和脉石英及其包裹体的微量元素特征

贵州锦丰（烂泥沟）金矿是滇黔桂“金三角”目前已探明最大的卡林型金矿床。含砷黄铁矿是该矿床最主要的载金矿物,硅化及石英脉是最显著的热液蚀变类型。本文采用高精度电感耦合等离子质谱（ICP-MS）对含砷黄铁矿和脉石英及其包裹体的微量元素进行了测试,结果表明含砷黄铁矿富亲硫元素,并相对于围岩和上部地壳均强烈富集;亏损V,Sr 及高场强元素。同生黄铁矿也具有类似的特征。脉石英除亲石元素含量高以外,还表现为亲硫元素以及Mo,Bi 含量较高。但与上部地壳相比,绝大部分元素贫化。相应包裹体的微量元素含量普遍低于单矿物,但变化特征一致。结合矿物和包裹体的稀土元素分析,发现脉石英和含砷黄铁矿及其包裹体均表现为HFSE明显亏损,Th/La,Nb/La 比值小于1,说明成矿流体为富Cl 的流体。含砷黄铁矿及其包裹体中Co/Ni 比值远小于1,反映成矿温度较低,推测成矿流体主要来源于以沉积建造水为主的盆地流体。     

Quartz Cement in Middle Jurassic Reservoir Sandstones in North Sea A Review. Part II： Duration and Silica Sources

The timing and duration of quartz cementation in sandstones have been mainly inferred from diagenetic texture, relationship between pore filling minerals, fluid inclusions and isotopic data. Fluid inclusion temperatures from North Sea reservoir sandstones indicate that most of the quartz cement forms at temperature exceeding 90℃ and is continually proceeding after oil emplacement, based on the fluid inclusion temperatures in quartz overgrowth which is approaching the bottom-hole temperatures. The duration of quartz cement after oil emplacement depends upon the saturation of porewater and the distribution of pore water film and the property of water-wet or oil-wet of the reactants. The leaching of K-feldspar by meteoric water requires pore water flow to move the released potassium and sodium and silica out the solution, which suggests the mechanism does not appear to be a major source of silica for quartz cementation. The quartz cementation coincidence with the compaction and pressure solution suggests the major source of silica. The alteration of feldspar by illitization of kaolinite may serve as another important source of silica at deep burial depth. External sources are not need to call on for illustrating the quartz cementation, because there is no evidences for large scale convection of pore water flow occurred in the burial history of reservoir sandstones of middle Jurassic in the North Sea.     

板栗状石英晶簇的发现及其形成条件分析

在上水桥金、萤石矿区的含矿硅化破碎带中,新发现一种围绕断层磨砾呈放射状生长的石英晶簇,因其像有刺、有壳、有仁的板栗,作者将其命名为板栗状石英晶簇。板栗状石英晶簇可能是硅质围绕悬浮于高比重热液中的断层磨砾生长形成,反映当时热液中可能含有高浓度的重金属化合物。     

大别山双河片麻状花岗岩岩体石英组构特征及应变分析

对大别山双河片麻状花岗岩岩体中的石英C轴组构、黑云母(001)解理极点和石英颗粒三维应变分别进行系统测量。结果显示,双河岩体在侵位和后期演化过程中以挤压变形为特点,岩体经过NW-SE向和NE-SW向两次挤压,NW-SE向挤压强度较大,奠定了岩体基本的构造形态。结合区域应力场特征分析得出,双河岩体在早三叠世至早侏罗世应力方位为NW-SE向挤压,中侏罗世及后期为NE-SW向挤压,应力场发生顺时针变化。      

风化成壤对原始粉尘粒度组成的改造证据

对现代粉尘、黄土、古土壤、红粘土全样和对应石英样的粒度分析结果表明,现代粉尘和对应石英样的粒度组成最为相似,而其它经历了风化成壤改造后的全样,粒度组成发生了不同程度的变化,其中以古土壤和红粘土样尤为显著。全样和石英样品的平均粒径比值变化,反映了原始粉尘经风化成壤改造而细化的程度,可能与夏季风强度关系密切。灵台剖面L₆以来的黄土—古土壤序列的磁化率、全样和石英样平均粒径及其比值变化对比表明,在冰期-间冰期旋回时间尺度上,全样和石英样平均粒径记录的冬季风变化特征类似,但在千年时间尺度上,平均粒径比值和石英样的平均粒径变化则揭示出东亚季风具有更高频次的变率特征。     

辽西兰家沟钼矿床成矿流体特征及成因探讨

兰家沟钼矿床是中国北方重要的独立钼矿床,矿体主要赋存于细粒花岗岩体内部及与粗粒花岗岩的接触部位,矿石类型以辉钼矿-石英大脉为主。流体包裹体研究表明,兰家沟钼矿床含钼石英脉中流体包裹体较少,类型主要为气液两相,个别含子矿物多相包裹体;激光拉曼光谱测试表明,成矿流体成分主要为H2O,微量的CO2、CO23-。成矿期流体包裹体的均一温度为160~405℃,集中于180~320℃;盐度w(NaCleq)为2.4%~16.5%,多数在8%~14%。成矿流体在演化过程中发生了中等盐度和低盐度流体的混合作用,2种不同成分流体的混合作用使得辉钼矿大量沉淀而成矿。氢氧同位素研究表明,成矿流体的δD为-81‰~-101‰,δ18O水为-0.1‰~4.5‰,小于兰家沟花岗岩全岩δ18O水值,反映成矿流体来自混合的岩浆水与大气降水。通过与典型斑岩型钼矿床地质特征、矿化、围岩蚀变、流体包裹体特征及同位素组成的对比,认为兰家沟钼矿床属于热液脉型向斑岩型过渡类钼矿床。     

光释光测年中石英样品提纯方法的改进

为了解决光释光前处理中遇到的传统方法无法获得满足纯度石英的问题,通过大量对比实验,结合玻璃工艺中石英分离研究成果,最后获得了新的石英提纯流程,与传统方法相比,新方法通过化学分离避免了密度变化对石英长石分离的影响,从而解决了斜长石和岩屑在传统的重液分离中无法剔除的问题,新方法能够获得满足纯度要求和量要求的石英,同时,新方法比传统方法实验室工作效率更高。     

Geochemical and electron paramagnetic characteristics of quartz from a multi-stage vein environment, Cowarra gold deposit, New South Wales

The characterisation of quartz using trace element geochemistry and electron paramagnetic resonance measurements has been tested for different generations of quartz veining in the multi-stage hydrothermal vein system at Cowarra. Quartz closely associated with gold mineralisation can be distinguished from earlier and later quartz generations in the mineralised environment, and both types can be distinguished from regional, barren quartz veins. These separate stages of quartz veins are also recognised from their fluid inclusion characteristics. Geochemical differences in the quartz partly reflect the presence of minor mineral inclusions, particularly sulfides and arsenopyrite.The study highlights the importance of understanding the paragenetic sequence of quartz vein development in a mineralised environment and the need for careful, thorough sampling before attempting geochemical and EPR characterisation of quartz as an exploration technique.     

The magmatic–hydrothermal transition—evidence from quartz phenocryst textures and endoskarn abundance in Cu–Zn skarns at the Empire Mine, Idaho, USA

Information about the magmatic to hydrothermal transition is preserved in late-stage features of quartz phenocrysts and endoskarn alteration in some Cu–Zn skarn deposits such as the Empire Mine in Idaho. Important features include: (1) quartz phenocrysts with strong resorption textures such as vermicular zones of igneous groundmass cutting primary quartz cathodoluminescence banding, (2) anomalous amounts of endoskarn (more than 50% of mineralized rock), (3) high F activities as evidenced by fluorite as an accessory mineral in igneous rocks, in alteration assemblages, and in fluid inclusions and by high F in hydroxyl sites in igneous biotite and amphibole, and (4) direct association of Zn, which normally is deposited distally at low temperature, with Cu in proximal locations and in endoskarn. These features are explained by the following model: (1) F lowers the solidus temperature of the magma, thus changing the timing, temperature, and duration of hydrothermal fluid exsolution. (2) Upon magmatic vapor saturation the F-rich hydrothermal fluids form bubbles that adhere to quartz phenocrysts and chemically corrode/tunnel into the quartz forming vermicular resorption textures. (3) F-rich hydrothermal fluids also promote the formation of endoskarn; silicic rocks are attacked by F-rich fluids in the same sense that carbonate wall rocks are dissolved by weakly to moderately acidic hydrothermal fluids. (4) Low fluid exsolution temperature facilitated by high F activity promotes high Zn/Cu ratios in proximal locations due to the solubility of Zn relative to Cu at lower temperatures. This model may be applicable at other localities such as the world-class Cu–Zn skarn Antamina mine, as well as some tin and rapakivi granites.