Nano-scale pore structure and fractal dimension of organic-rich Wufeng-Longmaxi shale from Jiaoshiba area,Sichuan Basin: Investigations using FE-SEM,gas adsorption and helium pycnometry

Much attention have been recently paid to the upper Ordovician Wufeng shale (O₃w) and lower Silurian Longmaxi shale (S₁l) in the Jiaoshiba area of Sichuan Basin, which is now the largest producing shale gas field in China. Field emission scanning electron microscopy (FE-SEM), low pressure gas (N₂ and CO₂) adsorption, helium pycnometry, X-ray diffraction and geochemical analyses were performed to investigate the pore structure and fractal dimension of the pores in O₃w-S₁l shale formation in the Jiaoshiba area. FE-SEM images show that organic matter (OM) pores are dominant in the organic-rich samples and these pores are often irregular, bubble-like, elliptical and faveolate in shape, while in organic-poor samples, limited and isolated interparticle (interP), intraparticle (intraP) and OM pores are observed. Reversed S-shaped isotherms obtained from nitrogen adsorption are type Ⅱ, and hysteresis loops indicate that the shape of micropore in the samples is slit-or plate-like. BET surface areas and total pore volume vary from 12.2 to 27.1 m²/g and from 1.8 × 10⁻² to 2.9 × 10⁻² cm³/g, with an average of 19.5 m²/g and 2.3 × 10⁻² cm³/g, respectively. Adsorption volume from both N₂ and CO₂ adsorption increases with respect to TOC contents. Porosities obtained from helium porosimetry are comparable with these from gas (CO₂ and N₂) adsorption in O₃w-S₁l shale. However, porosity determined by quantitative FE-SEM analysis is much smaller, which is mainly related to limited resolution and the small areas of investigation.Based on the Frenkel-Halsey-Hill (FHH) model of low-pressure N₂ adsorption, fractal dimensions of the pores varied from 2.737 to 2.823. Relationships between pore structure parameters and TOC content, mineral composition and fractal dimension reveal that the fractal dimension is mainly associated with micropores. Samples with higher TOC content, higher quartz content and lower clay content tend to contain more heterogeneous micropores, resulting in higher fractal dimensions and more complicated pore structure in shales. Therefore, fractal dimension is an effective parameter to reflect the complexity of pore structure and the degree of micropore development in O₃w-S₁l shale.     

Controls on reservoir heterogeneity of tight sand oil reservoirs in Upper Triassic Yanchang Formation in Longdong Area,southwest Ordos Basin,China: Implications for reservoir quality prediction and oil accumulation

Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively.     

Geological control factors of micro oil distribution in tight reservoirs

Understanding the oil distribution characteristics in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil distribution characteristics are mostly concerned with the basin scale. Based on Lucaogou core samples, geochemical approaches including Soxhlet extraction, total organic carbon (TOC), and Rock-Eval are combined with reservoir physical approaches including mercury injection capillary pressure (MICP) and porosity-permeability analysis, to quantitatively evaluate oil distribution of tight reservoirs on micro scale. The emphasis is to identify the key geological control factors of micro oil distribution in such tight reservoirs. Dolomicrites and non-detrital mudstones have excellent hydrocarbon generation capacity while detritus-containing dolomites, siltstones, and silty mudstones have higher porosity and oil content, and coarser pore throat radius. Oil content is mainly controlled by porosity, pore throat radius, and hydrocarbon generation capacity. Porosity is positively correlated with oil content in almost all samples including various lithologies, indicating that it is a primary constraint for providing storage space. Pore throat radius is also an important factor, as oil migration is inhibited by the capillary pressure which must be overcome. If the reservoir rock with suitable porosity has no hydrocarbon generation capacity, pore throat radius will be decisive. As tight reservoirs are generally characterized by widely distributed nanoscale pore throats and high capillary pressure, hydrocarbon generation capacity plays an important role in reservoir rocks with suitable porosity and fine pore throats. Because such reservoir rocks cannot be charged completely. The positive correlation between hydrocarbon generation capacity and oil content in three types of high porosity lithologies (detritus-containing dolomites, siltstones, and silty mudstones) supports this assertion.     

Pore structure and heterogeneity of shale gas reservoirs and its effect on gas storage capacity in the Qiongzhusi Formation

Fine characterization of pore systems and heterogeneity of shale reservoirs are significant contents of shale gas reservoir physical property research.The research on micro-control factors of low productivity in the Qiongzhusi Formation(Fm.)is still controversial.The lower Cambrian Qiongzhusi Fm.in the Qujing,Yunnan was taken as the object to investigate the influence of mineral compositions on the phys-ical properties of the reservoir and the heterogeneity of shale,using the algorithm to improve the char-acterization ability of Atomic Force Microscopy(AFM).The results showed that:(1)The pores are mainly wedge-shaped pores and V-shaped pores.The pore diameter of the main pore segment ranges from 5 to 10 nm.Mesopores are mainly developed in the Qiongzhusi Fm.shale in Well QD1,with the average pore diameter of 6.08 nm.(2)Microscopic pore structure and shale surface properties show strong hetero-geneity,which complicates the micro-migration of shale gas and increases the difficulty of identifying high-quality reservoirs.(3)The increase of clay mineral content intensifies the compaction and then destroys the pores.Conversely,brittle minerals can protect pores.The support and protection of brittle minerals to pores space depend on their content,mechanical properties and diagenesis.(4)Compression damage to pores,large microscopic roughness and surface fluctuations and strong pore structure heterogeneity are the reasons for the poor gas storage capacity of the Qiongzhusi Fm.,which will lead to poor productivity in the Qiongzhusi Fm.     

台风“摩羯”与“温比亚”环流中龙卷小尺度涡旋特征及可预警性分析

利用多普勒天气雷达探测资料,结合常规气象观测资料和天气实况及灾情调查,对2018年8月14日台风“摩羯”（1814）和8月19日台风“温比亚”（1818）产生龙卷的环境物理量及龙卷风暴强度结构特征进行了分析,对诱发龙卷和未诱发龙卷的小尺度气旋性涡旋特征进行了对比。结果表明：两次台风减弱低压东北象限是龙卷发生的关键区,低层高湿,强的低层垂直风切变和大的相对风暴螺旋度是关键物理量;龙卷出现时都伴有ΔV＞20.0 m·s-1的小尺度气旋性涡旋,且基本出现在2.0 km高度以下,但并不是所有这种低层小尺度气旋性涡旋都能诱发龙卷;以ΔV＞20.0 m·s-1为阈值,龙卷识别具有较高的命中率,识别准确率为31.8%,空报率为67.4%,漏报率为6.7%;约35.7%的龙卷没有识别时间提前量,半数龙卷几乎没有预警时间提前量。     

相控震源对地震信号信噪比的改善研究

当测区噪声很强,采用组合震源工作仍然不能满足信噪比要求时,为进一步提高地震勘探信噪比,引入能形成定向地震波的相控震源.针对水平层状介质模型,对组合震源、相控震源地震进行了数值模拟,并定量计算了采用4,8,15,20单元的组合与相控震源地震数据的信噪比,同组合地震相比,相控地震使来自不同反射层的反射波信号的信噪比平均提高了154～990 dB.结果表明,相控震源地震得到的反射波信号信噪比高于组合地震,并且随着激震器数目增加,相控震源合成地震记录中的反射波地震数据信噪比明显提高.     

轴压比对中等高度LC结构剪力墙抗震性能的影响

轻骨料混凝土(L ight-we ight concrete,简称LC)剪力墙的轴压比是剪力墙抗震设计时一个重要的控制因素,直接关系到其延性性能。为使设计规程具有足够的理论依据,本文通过对六榀轻骨料混凝土剪力墙试件的试验,研究了在低周反复荷载作用下,着重考虑不同轴压比对中等高度有边框剪力墙的破坏形态和变形性能的影响效应,对其滞回特性进行分析,计算了各剪力墙的刚度退化率与延性系数,并将无竖缝剪力墙与带竖缝剪力墙的抗震性能进行了对比。     

震源机制和场地条件对近场强震地面运动特性的影响

将欧洲数百条地震动记录按震级、震中距、场地类别及震源机制等条件分类,通过对地震动记录加速度峰值比、加速度峰值衰减规律及反应谱比等内容的统计分析,研究了震源机制、场地类别等因素对竖向地震动的影响。结果表明,震源机制和场地类别这两种因素在近场区对竖向地震动特性有显著的影响。     

Landslide susceptibility modeling based on ANFIS with teaching-learning-based optimization and Satin bowerbird optimizer

As threats of landslide hazards have become gradually more severe in recent decades,studies on landslide prevention and mitigation have attracted widespread attention in relevant domains.A hot research topic has been the ability to predict landslide susceptibility,which can be used to design schemes of land exploitation and urban development in mountainous areas.In this study,the teaching-learning-based optimization(TLBO)and satin bowerbird optimizer(SBO)algorithms were applied to optimize the adaptive neuro-fuzzy inference system(ANFIS)model for landslide susceptibility mapping.In the study area,152 landslides were identified and randomly divided into two groups as training(70%)and validation(30%)dataset.Additionally,a total of fifteen landslide influencing factors were selected.The relative importance and weights of various influencing factors were determined using the step-wise weight assessment ratio analysis(SWARA)method.Finally,the comprehensive performance of the two models was validated and compared using various indexes,such as the root mean square error(RMSE),processing time,convergence,and area under receiver operating characteristic curves(AUROC).The results demonstrated that the AUROC values of the ANFIS,ANFIS-TLBO and ANFIS-SBO models with the training data were 0.808,0.785 and 0.755,respectively.In terms of the validation dataset,the ANFISSBO model exhibited a higher AUROC value of 0.781,while the AUROC value of the ANFIS-TLBO and ANFIS models were 0.749 and 0.681,respectively.Moreover,the ANFIS-SBO model showed lower RMSE values for the validation dataset,indicating that the SBO algorithm had a better optimization capability.Meanwhile,the processing time and convergence of the ANFIS-SBO model were far superior to those of the ANFIS-TLBO model.Therefore,both the ensemble models proposed in this paper can generate adequate results,and the ANFIS-SBO model is recommended as the more suitable model for landslide susceptibility assessment in the study area considered due to its excellent accuracy and efficiency.     

唐山7.8级地震前地磁异常的综合分析

利用昌黎等台的磁测资料,并用多种方法进行综合分析,结果显示,在震前出现了约3个月的短期异常,这对于地震的预测预报有一定意义。