辽北清原地区太古宙地质演化及其对成矿的控制作用

辽北清原地区在时空上有系统地发育了三个太古亩地体：浑河以南的小莱河花岗岩-绿岩带（ＸＧＧＢ）、浑河以北的清原花岗岩-绿岩带（ＱＧＧＢ）和在ＱＧＧＢ东北部出露的景家沟麻粒岩-片麻岩区（ＪＧＧＲ）。绿岩带中火山岩组合在ＸＧＧＢ中以双峰式岩套为特征，而在（ＱＧＧＢ中以连续的钙碱性系列为特征。ＸＧＧＢ中斜长角门岩全岩Ｓｍ－Ｎｄ等时线年龄为３０１８±２０Ｍａ，Ｎｄ（ｔ）＝＋０．１９±０．１７，ＴＤＭ＝３３４７～３７３５Ｍａ，而ＱＧＧＢ中的斜长角闪岩全岩Ｓｍ～Ｎｄ等时线年龄为２８８４±４８Ｍａ，∈Ｎｄ（ｔ）＝＋２．６１±０．４１，ＴＤＭ＝２９３８～２９９２Ｍａ。ＪＧＧＲ中黑云麻粒岩的Ｒｂ－Ｓｒ等时线年龄为２９９４±３２５Ｍａ，可能代表变质年龄，表明其形成在ＸＧＧＢ之前。综合研究表明辽北地区太古亩地质演化模式很可能为：ＪＧＧＢ代表了古中太古代古陆的残骸，ＸＧＧＢ于中太古代形成在这个古陆边缘的裂谷盆地内，ＱＧＧＢ则形成在新太古代的大陆边缘岛弧环境，并于新太古代晚期与ＸＧＧＢ拼贴。在此陆一弧碰撞过程中，ＱＧＧＢ逆冲推覆于ＪＧＧＲ之上，后者由于后期的伸展作用而出露于地表。成矿作用是地质演化的组成部分，并受制于各个演化阶段的构造环境     

岩石水压致裂和诱发地震的实验研究

用7种岩石各制备了几类不同预裂纹的系列试件，并在不同围压下进行水压致裂强度实验。结合典型的水库诱发地震的实际资料和现今构造应力场的实验结果，以及应用岩石强度理论和岩石断裂力学的一些原理、方法，进行岩石孔隙水压诱发地震的探讨。初步结果为：(1)若岩体内构造应力很小，一定大小的孔隙水压力σp，可直接使岩体内的薄弱面致裂并发生小地震。(2)若构造应力较大，存在两类诱发地震的可能：①对岩体浅部一些走向与构造应力的主压应力σ1方向相近的薄弱面，σp可促使其发生张性破裂并诱发小地震。②当构造应力接近于断裂的抗剪强度时，因σp，降低了断裂面上的正应力σn，使原处于稳定状态的断裂失稳，发生滑移破裂并诱发出地震。σp导致断裂的破裂深度增大，使诱发地震的震级大于原潜在的地震震级。(3)各种岩体均存在着一个极限深度，此深度后不再有诱发地震。     

The oldest tachyporine rove beetle in amber (Coleoptera,Staphylinidae): A new genus and species from Upper Cretaceous Burmese amber

A new genus and species of extinct rove beetle, Procileoporus burmiticus gen. and sp. n., is described from Upper Cretaceous Burmese amber (Cenomanian; ca. 99 Ma). Due to the condition of the fossil, parts of the body could not be examined, but sufficient characteristics were visible to allow the specimen to be placed within the subfamily Tachyporinae (tribe Tachyporini). Procileoporus is most similar to the extant genus Cileoporus Campbell in having a slender abdomen, but it differs in having much shorter abdominal setae, prominent striated microreticulation on the elytra, non-lobed tergite VIII, and in other details of the male genital segments. This is the first tachyporine rove beetle from Burmese amber and the oldest record of the subfamily in amber. The evolution of sexual dimorphism in the genital segments is briefly discussed.     

Deciphering As and Cu cycling in sediment pore waters in a large marina (Port Camargue,southern France) using a multi-tracer (Fe,Mn, U,Mo) approach

The sediments of the Port Camargue marina (South of France) are highly polluted by Cu and As (Briant et al., 2013). The dynamics of these pollutants in pore waters was investigated using redox tracers (sulfides, Fe, Mn, U, Mo) to better constrain the redox conditions.In summer, pore water profiles showed a steep redox gradient in the top 24 cm with the reduction of Fe and Mn oxy-hydroxides at the sediment water interface (SWI) and of sulfate immediately below. Below a depth of 24 cm, the Fe, Mn, Mo and U profiles in pore waters reflected Fe and Mn reducing conditions and, unlike in the overlying levels, sulfidic conditions were not observed. This unusual redox zonation was attributed to the occurrence of two distinct sediment layers: an upper layer comprising muddy organic-rich sediments underlain by a layer of relatively sandy and organic-poor sediments. The sandy sediments were in place before the building of the marina, whereas the muddy layer was deposited later. In the muddy layer, large quantities of Fe and Mo were removed in summer linked to the formation of insoluble sulfide phases. Mn, which can adsorb on Fe-sulfides or precipitate with carbonates, was also removed from pore waters. Uranium was removed probably through reduction and adsorption onto particles. In winter, in the absence of detectable pore water sulfides, removal of Mo was moderate compared to summer.Cu was released into solution at the sediment water interface but was efficiently trapped by the muddy layer, probably by precipitation with sulfides. Due to efficient trapping, today the Cu sediment profile reflects the increase in its use as a biocide in antifouling paints over the last 40 years.In the sandy layer, Fe, Mn, Mo and As were released into solution and diffused toward the top of the profile. They precipitated at the boundary between the muddy and sandy layers. This precipitation accounts for the high (75 μg g⁻¹) As concentrations measured in the sediments at a depth of 24 cm.     

基于最优分割分级法的月球撞击坑分级及其演化分析

撞击坑是月球表面广泛分布的重要构造形态,占据了月球表面的大部分面积。撞击坑的直径差别很大,从几微米到数百千米,其退化程度与形成年代具有密切关系。为了研究不同地质年代形成的撞击坑直径大小及其演化规律,需采用量化分级方法对大小不同的撞击坑进行定量分级和统计分析。本文在月表撞击坑数据库LU60645GT和Lunar_Impact_Crater_Database(2011)的基础上,结合数据库中撞击坑的直径、深度和年代信息,利用最优分割分级法对撞击坑直径进行定量化分级,并根据分级结果,综合分析撞击坑几何形态特征及其演化规律。研究结果表明,撞击坑形态特征的演化与年代有密切的关系。在相同级别、相同地体下,撞击坑形成的年代越早,其形态特征的精细结构退化程度越明显,只保留了大体的几何形状;而在不同级别、相同地体、相同年代下的撞击坑形态特征则由简单逐渐变为复杂,坑物质也逐渐变得复杂。     

Nano-scale pore structure and fractal dimension of organic-rich Wufeng-Longmaxi shale from Jiaoshiba area,Sichuan Basin: Investigations using FE-SEM,gas adsorption and helium pycnometry

Much attention have been recently paid to the upper Ordovician Wufeng shale (O₃w) and lower Silurian Longmaxi shale (S₁l) in the Jiaoshiba area of Sichuan Basin, which is now the largest producing shale gas field in China. Field emission scanning electron microscopy (FE-SEM), low pressure gas (N₂ and CO₂) adsorption, helium pycnometry, X-ray diffraction and geochemical analyses were performed to investigate the pore structure and fractal dimension of the pores in O₃w-S₁l shale formation in the Jiaoshiba area. FE-SEM images show that organic matter (OM) pores are dominant in the organic-rich samples and these pores are often irregular, bubble-like, elliptical and faveolate in shape, while in organic-poor samples, limited and isolated interparticle (interP), intraparticle (intraP) and OM pores are observed. Reversed S-shaped isotherms obtained from nitrogen adsorption are type Ⅱ, and hysteresis loops indicate that the shape of micropore in the samples is slit-or plate-like. BET surface areas and total pore volume vary from 12.2 to 27.1 m²/g and from 1.8 × 10⁻² to 2.9 × 10⁻² cm³/g, with an average of 19.5 m²/g and 2.3 × 10⁻² cm³/g, respectively. Adsorption volume from both N₂ and CO₂ adsorption increases with respect to TOC contents. Porosities obtained from helium porosimetry are comparable with these from gas (CO₂ and N₂) adsorption in O₃w-S₁l shale. However, porosity determined by quantitative FE-SEM analysis is much smaller, which is mainly related to limited resolution and the small areas of investigation.Based on the Frenkel-Halsey-Hill (FHH) model of low-pressure N₂ adsorption, fractal dimensions of the pores varied from 2.737 to 2.823. Relationships between pore structure parameters and TOC content, mineral composition and fractal dimension reveal that the fractal dimension is mainly associated with micropores. Samples with higher TOC content, higher quartz content and lower clay content tend to contain more heterogeneous micropores, resulting in higher fractal dimensions and more complicated pore structure in shales. Therefore, fractal dimension is an effective parameter to reflect the complexity of pore structure and the degree of micropore development in O₃w-S₁l shale.     

Controls on reservoir heterogeneity of tight sand oil reservoirs in Upper Triassic Yanchang Formation in Longdong Area,southwest Ordos Basin,China: Implications for reservoir quality prediction and oil accumulation

Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively.     

Geological control factors of micro oil distribution in tight reservoirs

Understanding the oil distribution characteristics in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil distribution characteristics are mostly concerned with the basin scale. Based on Lucaogou core samples, geochemical approaches including Soxhlet extraction, total organic carbon (TOC), and Rock-Eval are combined with reservoir physical approaches including mercury injection capillary pressure (MICP) and porosity-permeability analysis, to quantitatively evaluate oil distribution of tight reservoirs on micro scale. The emphasis is to identify the key geological control factors of micro oil distribution in such tight reservoirs. Dolomicrites and non-detrital mudstones have excellent hydrocarbon generation capacity while detritus-containing dolomites, siltstones, and silty mudstones have higher porosity and oil content, and coarser pore throat radius. Oil content is mainly controlled by porosity, pore throat radius, and hydrocarbon generation capacity. Porosity is positively correlated with oil content in almost all samples including various lithologies, indicating that it is a primary constraint for providing storage space. Pore throat radius is also an important factor, as oil migration is inhibited by the capillary pressure which must be overcome. If the reservoir rock with suitable porosity has no hydrocarbon generation capacity, pore throat radius will be decisive. As tight reservoirs are generally characterized by widely distributed nanoscale pore throats and high capillary pressure, hydrocarbon generation capacity plays an important role in reservoir rocks with suitable porosity and fine pore throats. Because such reservoir rocks cannot be charged completely. The positive correlation between hydrocarbon generation capacity and oil content in three types of high porosity lithologies (detritus-containing dolomites, siltstones, and silty mudstones) supports this assertion.     

The evolution of the Huangling uplift and its control on the accumulation and preservation of shale gas

There are plenty of Sinian and Cambrian potential shale gas resources in South China, which is characterized by high thermal evolution degrees, poor drilling performances and only occurs in local areas. Taking the principle “high to find low” is the key issue to achieving a breakthrough in older shale. China Geological Survey drilled in the periphery of the Proterozoic basement, i.e. the Huangling anticline, in the western Hubei, and Hannan paleocontinent in the southern Shanxi. It received high-quality gas-bearing shale with relatively low Ro in the in Lower Cambrian Niutitang formation and Sinian Doushantuo formation. Based on geological conditions of shale gas reservoirs in the Huangling anticline, this paper puts forward the new model named “Control over reservoirs by periphery of basement” about shale gas accumulation, suggesting that the shale deposited in a deepwater continental shelf in the periphery of the basement is characterized by shallow burial, a short burial time, stable tectonics, relatively low thermal evolution degrees, and shale gas reservoirs in a good condition. The shale of the Sinian-Cambrian strata deposited in deepwater continental shelves in the periphery of Chuanzhong paleo-uplift in Sichuan, Hannan paleocontinent in the southern Shanxi, Huangling anticline in western Hubei and Jiangnang-Xuefeng paleo-uplift in Hunan and Guizhou province have good shale gas exploration potential.     

A new tribe of Galerucinae leaf beetle (Insecta: Coleoptera: Chrysomelidae) from the Upper Cretaceous Taimyr amber

The new tribe Taimyralticini trib. nov., new genus Taimyraltica gen. nov. and new species Taimyraltica calcarata sp. nov. (Coleoptera: Chrysomelidae: Galerucinae) are described from Upper Cretaceous (Santonian) Taimyr amber of northern Siberia (Yantardakh locality). The new genus shares characters with genera of the tribe Alticini (small size, transverse antebasal groove on pronotum, regular punctate-striate elytra) and the Galerucini (narrow, non-swollen metafemora). A possible apomorphy of the new genus and tribe is a large and acute metatibial spur, erect and oriented transversely to the longitudinal axis of tibia. This character state is unknown in recent and fossil genera of Galerucinae. Early evolution and divergence of leaf beetles are discussed, and a Jurassic and Early Cretaceous subfamily radiation is proposed. Fossil galerucines are reviewed. The oldest Phyllotreta is recorded from the lower Miocene of Izarra (Spain). Our findings show an extreme rarity of Phytophaga in Taimyr amber from Yantardakh. Absence of Phytophaga was recorded earlier at Obeschayuschiy (Santonian-Campanian of the Magadan Region) and compared with their much larger share in Khetana (north of Khabarovsk Krai); we find nearly the same differences between Taimyr amber from Yantardakh and Canadian amber. In Obeschayuschiy this appears due to the Mesophytic character of the flora. It is assumed that the Santonian amber gymnosperm forest of the Khatanga Basin had the same character.