Variations in chemical compositions of the eolian dust in Chinese Loess Plateau over the past 2.5 Ma and chemical weathering in the Asian inland

Major and trace elements as well as strontium isotopic composition have been analyzed on the acid-insoluble (AI) phase of the loess-paleosol sequence from Luochuan, Shaanxi Province, China. Results show that the chemical composition of AI phase of loess and paleosols is distinctive to the average composition of upper continental crust (UCC), characterized by depletion of mobile elements Na, Ca and Sr. The distribution pattern of elements in AI phase reveals that initial dust, derived from a vast area of Asian inland, has suffered from Na- and Ca-removed chemical weathering compared to UCC. Some geochemical parameters (such as CIA values, Na/K, Rb/Sr and⁸⁷Sr/⁸⁶Sr ratios) display a regular variation and evolution, reflecting that the chemical weathering in the source region of loess deposits has decreased gradually since 2.5 Ma with the general increase of global ice volume. This coincidence reflects that the aridity of Asian inland since the Quaternary is a possible regional response to the global climate change.     

Computational fluid dynamics modelling of boundary roughness in gravel‐bed rivers: an investigation of the effects of random variability in bed elevation

Results from a series of numerical simulations of two‐dimensional open‐channel flow, conducted using the computational fluid dynamics (CFD) code FLUENT, are compared with data quantifying the mean and turbulent characteristics of open‐channel flow over two contrasting gravel beds. Boundary roughness effects are represented using both the conventional wall function approach and a random elevation model that simulates the effects of supra‐grid‐scale roughness elements (e.g. particle clusters and small bedforms). Results obtained using the random elevation model are characterized by a peak in turbulent kinetic energy located well above the bed (typically at y/h = 0·1–0·3). This is consistent with the field data and in contrast to the results obtained using the wall function approach for which maximum turbulent kinetic energy levels occur at the bed. Use of the random elevation model to represent supra‐grid‐scale roughness also allows a reduction in the height of the near‐bed mesh cell and therefore offers some potential to overcome problems experienced by the wall function approach in flows characterized by high relative roughness. Despite these benefits, the results of simulations conducted using the random elevation model are sensitive to the horizontal and vertical mesh resolution. Increasing the horizontal mesh resolution results in an increase in the near‐bed velocity gradient and turbulent kinetic energy, effectively roughening the bed. Varying the vertical resolution of the mesh has little effect on simulated mean velocity profiles, but results in substantial changes to the shape of the turbulent kinetic energy profile. These findings have significant implications for the application of CFD within natural gravel‐bed channels, particularly with regard to issues of topographic data collection, roughness parameterization and the derivation of mesh‐independent solutions. Copyright © 2001 John Wiley & Sons, Ltd.     

Dissolved Humic Substances Can Directly Affect Freshwater Organisms

Direct effects of pure humic substance (BS1 FA) on three different aquatic organisms (Ceratophyllum demersum, Dreissena polymorpha, and Chaetogammarus ischnus) were demonstrated in this study. Exposure to environmentally relevant concentrations (0.5 mg/L) of this humic substance led to the activation of the microsomal and soluble glutathione S‐transferase (GST) in Ceratophyllum demersum. Exposure to 3‐chlorobiphenyl showed also an elevation of GST activity, which is due to the proposed detoxication metabolism of these chlorinated biphenyl. Coexposure to a mixture of 3‐chlorobiphenyl and BS1 FA showed a reduction of enzyme elevation, but still significant over an untreated control. The direct impact of humic substances seems not to be restricted to a specific class of organisms.     

Improved dynamic correction method in seismic analysis of both classically and non‐classically damped structures

A step‐by‐step approximate procedure taking into consideration high‐frequency modes, usually neglected in the modal analysis of both classically and non‐classically damped structures, is presented. This procedure can be considered as an extension of traditional modal correction methods, like the mode‐acceleration method and the dynamic correction method, which are very effective for structural systems subjected to forcing functions described by analytical laws. The proposed procedure, herein called improved dynamic correction method, requires two steps. In the first step, the number of differential equations of motion are reduced and consequently solved by using the first few undamped mode‐shapes. In the second step, the errors due to modal truncation are reduced by correcting the dynamic response and solving a new set of differential equations, formally similar to the original differential equations of motion. The difference between the two groups of differential equations lies in the forcing vector, which is evaluated in such a way as to correct the effects of modal truncation on applied loads. Copyright © 2001 John Wiley & Sons, Ltd.     

Modelling the Quaternary evolution of shore platforms and erosional continental shelves

A mathematical model was used to investigate the effect of glacially induced fluctuations in sea level on the evolution of wave‐cut shore platforms and erosional continental shelves during the Quaternary. The model used two deep‐water wave sets, which were used to calculate breaker height and depth, and the force of the waves at the waterline, according to the width and bottom roughness of the surf zone and the gradient of the submarine slope. The model also incorporated an erosional threshold related to the strength of the rocks, the number of hours each year in which the water level is at each intertidal elevation and the amount and persistence of the debris at the cliff foot. Most runs were made using a sea level model that consisted of 26 glacial cycles from 2 million to 0·9 million years ago, and nine, of approximately twice the amplitude and wavelength, in the last 0·9 million years. The model emphasized the dynamic association between the contemporary intertidal platform and the continental shelf. Both surfaces trend towards a state of static equilibrium under oscillating sea level conditions, when attenuated waves are unable to continue eroding the rock. If there has not been enough time to reduce the gradient of the shallower portions of the continental shelf, however, intertidal shore platforms can be in a temporary, though possibly long‐lasting, state of dynamic equilibrium. The model suggests that most platforms are, at least in part, inherited from one, or in many cases more, interglacial stages when sea level was similar to today's. Copyright © 2001 John Wiley & Sons, Ltd.     

Pounding of structures modelled as non‐linear impacts of two oscillators

A new formulation is proposed to model pounding between two adjacent structures, with natural periods T₁ and T₂ and damping ratios ζ₁ and ζ₂ under harmonic earthquake excitation, as non‐linear Hertzian impact between two single‐degree‐of‐freedom oscillators. For the case of rigid impacts, a special case of our analytical solution has been given by Davis (‘Pounding of buildings modelled by an impact oscillator’ Earthquake Engineering and Structural Dynamics, 1992; 21 :253–274) for an oscillator pounding on a stationary barrier. Our analytical predictions for rigid impacts agree qualitatively with our numerical simulations for non‐rigid impacts. When the difference in natural periods between the two oscillators increases, the impact velocity also increases drastically. The impact velocity spectrum is, however, relatively insensitive to the standoff distance. The maximum relative impact velocity of the coupled system can occur at an excitation period T_n^* which is either between those of the two oscillators or less than both of them, depending on the ratios T₁/T₂ and ζ₁/ζ₂. Although the pounding force between two oscillators has been primarily modelled by the Hertz contact law, parametric studies show that the maximum relative impact velocity is not very sensitive to changes in the contact parameters. Copyright © 2001 John Wiley & Sons, Ltd.     

Distorted Froude‐scaled flume analysis of large woody debris

This paper presents the results of a movable‐boundary, distorted, Froude‐scaled hydraulic model based on Abiaca Creek, a sand‐bedded channel in northern Mississippi. The model was used to examine the geomorphic and hydraulic impact of simplified large woody debris (LWD) elements. The theory of physical scale models is discussed and the method used to construct the LWD test channel is developed. The channel model had bed and banks moulded from 0·8 mm sand, and flow conditions were just below the threshold of motion so that any sediment transport and channel adjustment were the result of the debris element. Dimensions and positions of LWD elements were determined using a debris jam classification model. Elements were attached to a dynamometer to measure element drag forces, and channel adjustment was determined through detailed topographic surveys. The fluid drag force on the elements decreased asymptotically over time as the channel boundary eroded around the elements due to locally increased boundary shear stress. Total time for geomorphic adjustment computed for the prototype channel at the Q₂ discharge (discharge occurring once every two years on average) was as short as 45 hours. The size, depth and position of scour holes, bank erosion and bars created by flow acceleration past the elements were found to be related to element length and position within the channel cross‐section. Morphologies created by each debris element in the model channel were comparable with similar jams observed in the prototype channel. Published in 2001 John Wiley & Sons, Ltd.     

Non‐stationary seismic response of tanks with soil interaction by wavelets

A wavelet‐based random vibration theory has been developed for the non‐stationary seismic response of liquid storage tanks including soil interaction. The ground motion process has been characterized via estimates of statistical functionals of wavelet coefficients obtained from a single time history of ground accelerations. The tank–liquid–soil system has been modelled as a two‐degree‐of‐freedom (2‐DOF) system. The wavelet domain equations have been formulated and the wavelet coefficients of the required response state are obtained by solving two linear simultaneous algebraic equations. The explicit expression for the instantaneous power spectral density function (PSDF) in terms of the functionals of the input wavelet coefficients has been obtained. The moments of this PSDF are used to estimate the expected pseudo‐spectral acceleration (PSA) response of the tank. Parametric variations are carried out to study the effects of tank height, foundation natural frequency, shear wave velocity of soil and ratio of the mass of tank (including liquid) to the mass of foundation on the PSA responses of tanks. Copyright © 2001 John Wiley & Sons, Ltd.     

Storm deposits and storm-generated coarse carbonate breccias on a pelagic outer shelf (South-East Basin, France)

Uppermost Jurassic limestones of the South‐East Basin (France) are organized into four facies associations that were deposited in four distinct zones: (1) peritidal lagoonal limestones; (2) bioclastic and reefal limestones; (3) pelagic lime mudstones; (4) lime mudstones/calcarenites/coarse breccias. Calcarenite deposits of zone 4 exhibit sedimentary structures that are diagnostic of deposition under wave‐induced combined flow. In subzone 4a, both vertical and lateral transitions from lime mudstone/calcarenite to breccia indicate in situ brecciation under wave‐cyclic loading. Breccias were produced by heterogeneous liquefaction of material previously deposited on the sea floor. Deposits in subzone 4a record relatively long periods (>400 kyr) of sedimentation below wave base, alternating with periods of deposition under wave‐induced currents and periods of in situ deformation. In this zone, storm waves were attenuated by wave–sediment interaction, and wave energy was absorbed by the deformation of soft sediment. With reference to present‐day wave attenuation, water depths in this zone ranged between 50 and 80 m. Landwards of the attenuation zone, in zone 3, storm waves were reduced to fair‐weather wave heights. Storm wave base was not horizontal and became shallower landwards. As a consequence, water depth and wave energy were not linearly related. On a small area of the seaward edge of subzone 4a, cobbles were removed by traction currents and redeposited in subzone 4b. There, they formed a 100‐m‐thick wedge, which prograded over 3 km and was built up by the stacking of 5‐ to 20‐m‐thick cross‐stratified sets of coarse breccia. This wedge records the transport and redeposition of cobbles by a high‐velocity unidirectional component of a combined flow. The increase in flow velocity in a restricted area is proposed to result from flow concentration in a channel‐like structure of the downwelling in the gulf formed by the basin. In more distal subzone 4c, the hydrodynamic effect of wave‐induced currents was quasi‐permanent, and brecciation by wave–sediment interaction occurred only episodically. This indicates that, seawards of the attenuation zone, hydrodynamic storm wave base was deeper than mechanical storm wave base. Uppermost Jurassic carbonates were deposited and soft‐sediment deformed on a hurricane‐dominated ramp of very gentle slope and characterized by a zone of storm wave degeneration, located seawards of a zone of sedimentation below wave base.     

Petrographic and geochemical evidence for the formation of primary, bacterially induced lacustrine dolomite: La Roda 'white earth' (Pliocene, central Spain)

Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg‐carbonates (dolomite unit) occur as a 3·5‐ to 4‐m‐thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1‐ to 2‐μm‐sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca‐dolomite (51–54 mol% CaCO₃), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO₂ and K contents are highly correlated. δ¹⁸O‐ and δ¹³C‐values in dolomites range from ?3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from ?6·34‰ to ?0·39‰ PDB (mean=?3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in ¹⁸O and ¹³C between the two minerals. The correlation coefficient between δ¹⁸O and δ¹³C for dolomite is extremely low and negative (r=?0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO₃^?/CO₃^2? groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi‐arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.