Estimation of parameters in a split functional model of geodetic observations (<Emphasis Type="Italic">M</Emphasis><Subscript>split</Subscript> estimation)

The paper presents a method of estimating parameters in two competitive functional models. The models considered here are concerned with the same observation set and are based on the assumption that an observation may result from a realization of either of two different random variables. These variables differ from one another at least in the main characteristic (for example, outliers can be realizations of one variable). A quantity that describes the opportunity of identifying a single observation with one random variable is assumed to be known. That quantity, called the elementary split potential, is strictly referred to the amount of information that an observation can provide about two competitive assumptions concerning the observation distribution. Parameter assessments that maximize the global elementary split potential (concerning all observations), are called M _split estimators. A generalization of M _split estimation presented in the paper refers to the theoretical foundation of M-estimation. An erratum to this article can be found at     

Environmental limitations on recruitment from seed in invasive Spartina densiflora on a southern European salt marsh

The South American cordgrass, Spartina densiflora, has invaded a range of different habitats that can support different native species assemblages on salt marshes in the Gulf of Cadiz, Spain. Little is known about the mechanisms of invasion. We examined the potential for seed germination and recruitment in a field transplant experiment, representing a wide range of environments, on elevational gradients across marshes with muddy and sandy sediments. The biotic resistance of native, perennial vegetation (where present) to recruitment of the alien was also investigated. Spartina densiflora seeds were able to germinate over a greater than 2-m range of elevation in the tidal frame. Germination success on unvegetated muddy sediments was related to sediment redox potential, with poor germination at strongly negative redox potentials on the lower sites. On sandy, well-drained sediments, germination was apparently constrained by water availability at the highest elevations. Comparison of vegetated and cleared plots on the upper marsh showed that there was a negative relationship between the presence of Atriplex portulacoides and germination on the muddy sediments. Recruitment (survival of seedlings for 12 weeks) was seen only on unvegetated muddy sediments at the highest elevation. Hence the invasive success and wide elevational tolerance of S. densiflora on the marshes of the Gulf of Cadiz are not reflected in its short-term ability to become established from its prolific seed production. Colonization of sub-optimal habitats may be largely by vegetative propagules and clonal growth.     

海洋功能区开发潜力评价方法

借鉴海洋资源开发潜力、旅游开发潜力、土地开发潜力、主体功能区开发潜力、可持续发展能力和多指标综合评价等方面的研究方法和指标体系,首次提出了海洋功能区开发潜力的概念、构成和指标,并分析了层次分析法在海洋功能区开发潜力评价中的适用性,总结了海洋功能区开发潜力评价的方法、步骤和存在的问题。     

Cadmium and phosphorus cycling in the water column of the South China Sea: The roles of biotic and abiotic particles

The concentrations of cadmium, phosphorus, and aluminum in size-fractionated phytoplankton, zooplankton, and sinking particles are determined using ICPMS to evaluate the roles of biotic and abiotic particles on the cycling and ratios of Cd and P in the water column. Plankton were collected with a filtration apparatus equipped with 10-, 60-, and 150-μm aperture plankton nets on two occasions (2002 and 2006), and sinking particles were sampled by moored sediment traps deployed at depths of 120, 600, and 3500 m from 2004 to 2005. In contrast to what our previous study revealed, i.e., that most of the other bioactive trace metals in plankton were strongly correlated with abiotic Al and adsorbed on phytoplankton [Ho, T.Y., Wen, L.S., You, C.F., Lee, D.C., 2007. The trace metal composition of size-fractionated plankton in the South China Sea: biotic versus abiotic sources. Limnol Oceanogr 52, 1776–88.], Cd/P ratios, ranging from 0.12 to 0.34 mmol/mol P, did not vary with Al and exhibited fairly consistent values among different sizes of plankton, showing that Cd was mostly incorporated on an intracellular basis. In terms of the sinking particles, fluxes in Cd and P as well as in Cd/P ratios were strongly influenced by both biotic and abiotic particles. Overall, the Cd/P ratios in the sinking particles ranged from 0.03 to 1.2 mmol/mol, with the highest value observed in traps at 120 m during the productive season. The lowest value was observed in deep water during high flux periods for lithogenic particles. At surface depth, flux and Cd/P ratios were elevated during the most productive season in the region. The elevated ratios in the traps at 120 m were most likely related to preferential uptake of Cd for the dominant species (coccolithophores) during the productive period. Relatively, Cd/P ratios sharply decreased with increasing Al flux in deep water and ratios were much lower than the expected Cd/P ratios obtained from the relative portion of lithogenic and biogenic particles, indicating that the adsorption of soluble P into lithogenic particles was significant in the deep water during high lithogenic particle flux periods. Using averaged annual fluxes and standing stock in the water column, the residence time of biogenic Cd and P are 0.10 and 0.20, 250 and 100, and 9100 and 5000 years respectively in the top 120 m, 600 m, and water column as a whole, also showing preferential removal for Cd in the euphotic zone but relatively higher removal rates for P in the deep water. Our study suggests that the shift in microalgal community structure along with input of lithogenic minerals are both potentially important factors in influencing Cd/P ratios in oceanic water on a geological time scale.     

Long-term bottom water warming in the north Ross Sea

We measured potential temperature, salinity, and dissolved oxygen profiles from the surface to the bottom at two locations in the north Ross Sea (65.2°S, 174.2°E and 67.2°S, 172.7°W) in December 2004. Comparison of our data with previous results from the same region reveals an increase in potential temperature and decreases in salinity and dissolved oxygen concentration in the bottom layer (deeper than 3000 m) over the past four decades. The changes were significantly different from the analytical precisions. Detailed investigation of the temperature, salinity, dissolved oxygen and σ ₃ value distributions and the bottom water flow in the north Ross Sea suggests a long-term change in water mass mixing balance. That is to say, it is speculated that the influence of cool, saline, high-oxygen bottom water (high-salinity Ross Sea Bottom Water) formed in the southwestern Ross Sea has possibly been decreased, while the influences of relatively warmer and fresher bottom water (low-salinity Ross Sea Bottom Water) and the Adélie Land Bottom Water coming from the Australia-Antarctic Basin have increased. The possible impact of global warming on ocean circulation needs much more investigation.     

Palynology and petroleum potential of the Kazhdumi Formation (Cretaceous: Albian–Cenomanian) in the South Pars field,northern Persian Gulf

The Kazhdumi Formation of the Bangestan Group is a well-known source rock that has produced abundant oil in most petroleum fields in the Zagros Basin, which stretches from northwest to southwest Iran over hundreds of kilometres. The formation reaches a thickness of 230 m at the type section in northwest Zagros but thins out to 40–50 m in wells studied from the South Pars giant petroleum field, where it comprises mainly grey shales with occasional intercalations of marls and sandstones. South Pars, best known as the Iranian part of the world's largest non-associated gas field, contains small quantities of oil above and below the Kazhdumi Formation.     

塔里木盆地牙哈-英买力地区寒武系-奥陶系碳酸盐岩储层成因类型、特征及油气勘探潜力

牙哈—英买力地区是塔北隆起上的主要油气富集区,古潜山风化壳型储层的观点一直主导着该地区寒武系—奥陶系碳酸盐岩油气勘探的思路。但储层精细描述揭示了牙哈—英买力地区除古潜山风化壳型储层外,还发育有暴露浅滩型、层间古岩溶型、白云岩型储层。其中位于古潜山面之下经风化作用改造的白云岩型储层是最有勘探价值的,勘探成功率高。其次是暴露浅滩型储层,油藏类型有早成藏残留型和晚成藏型。暴露浅滩型、层间古岩溶型和白云岩型储层也是很有勘探价值的储层类型。早成藏型原生油气藏,位于寒武系—奥陶系与志留系呈假整合接触的地区,与古潜山无关。古潜山风化壳型储层可以形成晚成藏型油气藏,但目前试油结果均为水层,值得进一步探索。     

甘肃岷县锁龙—马坞一带金矿资源潜力评价

西秦岭“五朵金花”岩体是寨上—马坞金矿整装勘查区一带重要的金矿成矿地质体,围绕“五朵金花”岩体已发现有多达100余处金矿（床）点,是西秦岭重要的金矿集中区。锁龙—马坞一带研究区正好包括了整个教场坝岩体以及中川岩体及柏家庄岩体北部大部分区域,具有良好的形成金矿的潜力。因此本次工作在收集前人1∶5万矿调及锁龙金矿矿产勘查成果资料的基础上,利用MRAS软件对该区域金资源潜力进行了评价,同时预测了23处金成矿的有利区域,为该区下一步工作部署提供了靶区。     

长江口及邻近海区营养盐结构与限制

通过研究长江口及邻近海域溶解无机氮(DIN=NO₃-+NO₂-+NH₄+)、磷酸盐(PO₄3-)、硅酸盐(SiO₃2-)所表征的营养盐区域结构特征及影响因素,在分析营养盐绝对限制情况的基础上,划分了潜在相对营养限制区域。结果表明,123°E以西近岸表层区域DIN/P比值全年均高于16,而Si/DIN除秋季外基本小于1,显示出长江冲淡水影响下"过量氮"的特征。春夏季河口锋面区(31°~32.5°N,122.5°~124°E)硅藻的大量生长可使DIN/P异常升高和Si/DIN异常降低。秋季研究区域北部DIN/P西低东高且Si/DIN西高东低是由于在高DIN、低PO₄3-的长江冲淡水影响下,近岸受相对低DIN、高SiO₃2-的苏北沿岸流南下入侵影响而被分割而成。冬季长江口门东北部存在的高DIN/P和低Si/DIN区则主要由于寡营养盐的黑潮水深入陆架,向东北输送的部分长江冲淡水和增强的苏北沿岸流共同作用造成DIN升高所致。利用Redfield比值进行了不同站位表层潜在相对营养限制情况的区分。近岸123°E以西受高DIN、SiO₃2-长江冲淡水影响,四季多呈现PO₄3-潜在相对限制,而在春夏季由于浮游植物的大量吸收PO₄3-,造成局部PO₄3-绝对限制及潜在相对限制。春夏季氮限(DIN潜在相对限制)一般发生在外海部分站位,但较为零散。秋季除了东南外海大部分站位外,受苏北沿岸流影响在长江口北部近岸也存在氮限。随着低DIN/P的黑潮表层水(KSW)的入侵加强,冬季外海氮限站位增多。硅限(SiO₃2-潜在相对限制)在夏季发生在赤潮高发区,而冬季南部存在较多硅限站位表明KSW中SiO₃2-相对较为缺乏。     

金属电极在含油模拟海水中电化学行为的研究

采用电化学阻抗和恒电位阶跃技术研究了金属铂和镍电极在含油氯化钠溶液中的电化学行为特征,测量了不同含油量体系中电化学信号的变化,并建立了相应的等效电路.实验结果表明,同样条件下多孔电极比平面电极的电化学信号响应显著,泡沫镍电极与铂黑电极相比对含油量的响应则更为明显.