灵武煤田煤中镜质组与丝质组的甾萜类化合物对比研究

本文对灵武煤田含煤岩系延安组煤岩显微组分的甾萜类化合物作了对比研究．结果表明,同一沉积环境中镜质组与丝质组的甾萜类化合物特征及不同沉积环境中同一显微组分（镜质组或丝质组）的甾萜类化合物特征有着规律性的变化．     

不同密度镜质组的热解色谱特征及生烃潜力的研究

摘要：用热解色谱（Ｒｏｃｋ－Ｅｖａｌ）对２个褐煤样、３个气煤样的２８个分离组分进行了研究,揭示了不同密度镜质组组分之间生烃潜力具有较大的差异性;镜质组不仅可以作为重要的生气母质,而且还可以作为重要的生油母质。     

Thermal Backstripping from Vitrinite Reflectance Profiles in Comparison with an Extensional Model for Passive Continental Margin Basins on Northern Continental Shelf of South China Sea

INTRODUCTIONVitrinitereflectance(R.)canprovideagreatdealinfor-mationonthermalhistoryofabasin.Itisafunctionofmaximumpaleotemperatureandeffectiveheatingtime,inotherwords,afunctionofdepositionalrateandgeothermalgradientwithirreversiblecharacteristics.Butitalsohasacumulativeeffectthroughoutgeothermalevents.Paleotemperaturesaremainlycontro1ledbythebasalheatflowandheatgenerationfromradioactivesourceswithinthecrust.Themodelforde-terminingpaleoheatflowoflinearchangewithtimefr0mvitri-nitereflecta…     

Thermal structure and paleo-heat flow in the Shimanto accretionary prism, Southwest Japan

Abstract Thermal structural analysis and paleo-heat flow estimation provide clues to understanding the thermal evolution of the accretionary complex. The thermal structure and heat flow in the Jurassic Chichibu and Cretaceous to Tertiary Shimanto accretionary complex, Southwest Japan, have been investigated by vitrinite reflectance measurement and fluid inclusion analysis. As a result, the local and multistage metamorphisms were recognized as follows. First, the Tertiary complex around the Miocene Ashizuri granite underwent exposure to extra-high temperatures. Second, the Okitsu Melange underwent exposure to higher temperatures than the surrounding strata and was formed concurrently with the Kula-Pacific ridge subduction beneath the Japanese Islands in the Eocene. Finally, the thermal structure of most of the Cretaceous and southern Jurassic complexes is independent of the geologic structure, indicating that these areas suffered thermal overprint. Regional radiometric dating studies show that most of the Cretaceous Shimanto complex was heated in the Eocene; the thermal overprint might have occurred as a result of ridge subduction. The heat flow during peak heating was estimated to be 95–120 mW/m² except for the Cretaceous Okitsu melange and the Cretaceous Nonokawa formation, north of the Okitsu Melange; a much higher value of heat flow of ~200 mW/m² was estimated in the Okitsu Melange. An estimation of heat flow failed for the non-okawa formation because thermal equilibrium between the fluid and rocks has not yet been reached. It is probable that the southern strata underwent a higher heat flow. Such a trenchward increase in heat flow resembles the present situation of the Nankai Trough, although the heat flow in the Eocene was much higher.     

利用古温标恢复四川盆地主要构造运动时期的剥蚀量

地层剥蚀量是沉积盆地埋藏史和热史重建中一个关键的参数.本文利用石油钻井的系统古温标(Ro)资料,并结合多种恢复方法,得出四川盆地主要构造运动时期的剥蚀量.研究表明:加里东期,川东南剥蚀量较大,达2000m.东吴运动时期,川西南、川东南等距二叠纪玄武岩喷发区较近地区的剥蚀量较大,分别在260～450 m和800～900m:印支早期盆地整体遭受了抬升剥蚀作用,剥蚀厚度为100～500 m.印支中、晚期龙门山地区褶皱剥蚀,H1、Y1等钻井该时期的地层剥蚀量超过2000 m.燕山期周缘山系的继续隆升造成山前大范围地区的剥蚀:喜山期盆地周缘钻井的剥蚀量较大,在2000 m左右,而早期古隆起上的钻井如GJ、J13、Z12等钻井的地层剥蚀量则较小,在1000 m左右.可见,四川盆地不同地质时期及不同构造区位的剥蚀厚度都不尽相同,这一时空差异反映了构造运动对该区的差异影响.这一研究也表明,以系统的古温标资料(R_o)为基础,针对不同地质情况选用适当的反演方法并结合多种反演方法.能有效地恢复钻井在不同时期的剥蚀量.上述四川盆地各时期剥蚀地层厚度的恢复,对研究该区的构造、沉积和油气演化提供了基础数据.     

利用新近系煤的镜质组反射率计算滇西高原 的隆升幅度

为了定量地计算滇西高原的隆升幅度,在滇西中甸、保山、景东、景谷四地分别取新近纪煤岩样,在野外实测煤层上覆地层残留厚度和测得样品的镜质组反射率并确定有效作用时间后,根据三者关系曲线图计算出成煤时的最大古地温和最大埋深,进而计算出滇西高原上新世时期自北而南的隆升幅度在1500~1700m之间。该时期隆升表现出总体均匀抬升的特征。     

Thermal history of the Rio Muni (West Africa)–NE Brazil margins during continental breakup

We document the thermal record of breakup of the conjugate Rio Muni (West Africa) and NE Brazil margins using apatite fission track analysis, vitrinite reflectance data and stratigraphic observations from both margins. These results permit determination of the timing of four cooling episodes, and the temperature of samples at the onset of each episode. All samples are interpreted to have experienced higher temperatures in the geological past due to i) elevated basal heatflow (palaeogeothermal gradient in Rio Muni-1 well decaying from 58 °C/km during the Mid Cretaceous to 21.5 °C/km in the Late Cenozoic) and ii) progressive exhumation from formerly greater burial depth. A well constrained history of changing palaeogeothermal gradient allows for much more precise quantification of the thickness of eroded section (exhumation) than if a constant heatflow is assumed. Cooling episodes identified from the palaeotemperature data at 110–95 Ma (both margins) and 85–70 Ma (Rio Muni only) coincide with major unconformities signifying, respectively, the cessation of rifting (breakup) and compressional shortening that affected the African continent following the establishment of post-rift sedimentation (drift). The interval between these separate unconformities is occupied by allochthonous rafts of shallow-water carbonates recording gravitational collapse of a marginal platform. The rift shoulder uplift that triggered this collapse was enhanced by local transpression associated with the obliquely divergent Ascension Fracture Zone, and thermal doming due to the coeval St Helena and Ascension Plumes. The data also reveal a c.45–35 Ma cooling episode, attributed to deep sea erosion at the onset of Eo-Oligocene ice growth, and a c.15–10 Ma episode interpreted as the record of Miocene exhumation of the West African continental margin related to continent-wide plume development. Integration of thermal history methods with traditional seismic- and stratigraphy-based observations yields a dynamic picture of kilometre-scale fluctuations in base level through the breakup and early drift phases of development of these margins. Major unconformities at ocean margins are likely to represent composite surfaces recording not only eustasy, but also regional plate margin-generated deformation, local ‘intra-basinal’ reorganization, and the amplifying effect of negative feedbacks between these processes.     

Relationship between statistical thermal alteration index and vitrinite reflectance for sedimentary rocks in northern Japan with reference to effects for unconformity,faulting, and contact metamorphism

Two organic maturity indices, the statistical thermal alteration index (stTAI) and vitrinite reflectance (R_O), are used to gain insight into the geological histories of sequences of Tertiary and Upper Cretaceous sediments in northern Japan that contain an unconformity and which are affected by faulting and contact metamorphism. The stTAI is based on the brightness, or gray level, of fossil pollen of Pinus, Podocarpus, Abies, and Picea species. Pollen brightness is measured using a transmitted‐light microscope equipped with a computer‐driven digital image processor. The stTAI represents the mean value of the modes for the complete array of indigenous pollen in rock samples. The stTAI indicates the level of organic maturation for Neogene sedimentary rocks of Japan, from incipient diagenesis to early catagenesis (R_O ≤1.0%). With the progressive diagenesis and catagenesis of sedimentary rocks, stTAI values generally show a progressive decrease, whereas R_O values increase. The effects of an unconformity and faulting are more clearly recorded in stTAI trends than in R_O trends. During early stages of organic maturation (R_O ≤0.7%), stTAI shows a rapid decrease, while R_O shows a rapid increase during the mature and post‐mature stages (R_O ≥0.8%). The occurrence of a range in R_O values for a given level of organic maturity makes it difficult to determine the influence of the unconformity on the increasing R_O trend. R_O values show a progressive increase toward an igneous dyke, but this trend is not apparent in stTAI values. Measurements of Tertiary and Upper Cretaceous rocks in Japan reveal that stTAI is more sensitive to heating duration than R_O, although R_O is more sensitive to heating temperature.     

论砂岩储集岩相

储集岩相是以基本标志反映储集岩的沉积相、成岩变化以及油气显示面貌的。采用的标志包括：岩石学标志(沉积相、镜质体反射率),物性标志(三维孔喉比、配位数)以及有机地球化学标志(单有机包裹体光化学参数)。区分出的储集岩相类型不仅根据上述定量标志能进行自身评价,还可以编入相柱状图和古地理图进行预测和追索油气藏。依据由岩心或者岩屑制成双面抛光不加盖片的薄光片(岩心部分副样要浸注玫瑰红荧光剂并制成平行与垂直层理的三维薄光片),用显微镜光度法、显微付里叶红外谱和激光拉曼谱确定以上标志。     

煤镜质体反射率测定条件与测定值分析

针对部分应用单位在煤镜质体反射率测定中存在的对测定条件把握不准、对影响测定值准确性的因素理解不深等问题,提出了煤镜质体反射率测定必须遵守的仪器状态一致性与组分定位一致性原则,据此确立了仪器校正、样品测定和结果检验的方法与要求;分析了仪器线性度、稳定性、工作曲线、单色光、温度校正、视频窗口、油浸物镜与浸油、准焦程度和测定样品磨抛质量等对测定值准确性的影响与测定误差控制措施。在此基础上,提出了测定值精密度分级的改进建议,以及用煤镜质体反射率测定结果指导企业生产可简化的仪器条件与测定过程,即：使用50倍干物镜;勿需546 nm滤光片;用有固定反射率值的镀膜玻璃替代宝石标准片;建立工作曲线数据库等。