Geochemical approach to estimate the quality of water entering abandoned underground coalmines

Geochemical modeling was employed to estimate the chemistry of water infiltrating into abandoned underground flooded and unflooded coalmines of the Uniontown syncline, Fayette County, Pennsylvania. This was done to help evaluate factors governing the long-term evolution of coalmine discharge water quality in the Uniontown syncline area. The subsurface structure and lithology was delineated using borehole, mine shaft, and stratigraphic information. Hydrogeologic analyses indicated that most of the recharge to mine voids occurs in the zones of shallow overburden cover of less than 20 m in thickness. The water–rock contact period in the recharge areas of the overburden was estimated to be 5 days or greater for the flooded mines, and a day or less for the unflooded mines. Flow-through reaction-path models were applied to the topsoil and shale–sandstone lithological units identified in the recharge areas. The model predicted water entering the flooded mines at a pH of 6.65, alkalinity of 6.92 mequiv. l^–1 and a total sulfate concentration of 7.33 mM, and the unflooded mines at a pH of 6.68, alkalinity of 6.99 mequiv. l^–1 and a total sulfate concentration of 3.08 mM. The model predictions for the flooded and unflooded mines are consistent with groundwater data from the study site, indicating the usefulness of this approach in evaluating the contribution of overburden chemistry to the evolution of mine discharge quality.     

Stratigraphic control of hot fluids on anthracitization, Lackawanna synclinorium, Pennsylvania

The Lackawanna synclinorium of Pennsylvania contains abundant coal that was altered to anthracite rank during the Late Paleozoic Alleghanian orogeny. Why did the coal in the synclinorium undergo anthracitization? Two alternatives have been suggested. (1) The region was buried deeply during and/or after the Alleghanian orogeny and thus became hot in response to Earth's geothermal gradient; and (2) hot fluids migrating from the orogen toward the foreland carried heat into the coal and caused anthracitization. If the second hypothesis is correct, the region should contain evidence that hot fluids passed through the coal. Field observations, illite-crystallinity studies and fluid-inclusion analyses indicate that the coal-bearing Pottsville and Llewellyn Formations, and an underlying detachment fault, called the Pottchunk fault (at or slightly below the base of the Pottsville Formation), acted as a regional aquifer for the migration of hot fluids during the Alleghanian orogeny. The presence of quartz veins and the hydrothermal minerals tosudite and pyrophyllite in strata above the Pottchunk fault, and the apparent absence of an illite-crystallinity burial gradient in the underlying strata, suggest that fluids migrated through large pores in coarse-grained sandstones, through abundant fractures that developed in response to Alleghanian deformation, and along the Pottchunk fault. The quartz veins, tosudite and pyrophyllite mineralization do not occur below the Pottchunk fault (except at one locality), suggesting that fluid flow was greater above the fault, perhaps because fracturing accompanying deformation increased permeability of the fault's hanging wall. Fluid inclusions in the Pottsville and Llewellyn Formations indicate fluids achieved a minimum temperature of 270 °C at a depth of 3.1–8.5 km. Heat-flow calculations constrained by fluid-inclusion data show the heat carried by the migrating fluids through the coal-bearing strata was sufficient to elevate the rock temperature to anthracite-grade conditions (250 °C), assuming that the fluid event lasted about 1 year. Thus, deep burial (6–9 km) of the coal-bearing strata in the Lackawanna synclinorium was not required for anthracitization. Anthracitization was likely the result of stratigraphically controlled hot fluid migration through the coal-bearing strata at shallow depths (≤5 km).     

Temperature–time paths from phosphate accessory phase paragenesis in the Honey Brook Upland and associated cover sequence, SE Pennsylvania, USA

Analysis of monazite-bearing lithologies from the Precambrian Honey Brook Upland (HBU) and overlying metasedimentary Paleozoic Chester Valley Sequence (CVS) (SE PA, USA) reveals overprinting of primary major and accessory phase parageneses by texturally and compositionally disparate secondary accessory phase parageneses. Two-pyroxene temperatures of 915–945 °C for reconstituted pyroxene reflect emplacement temperatures of felsic plutonic rocks (opdalite, charnockite) prior to Mesoproterozoic metamorphism. Monazite in metavolcanic felsic gneiss yields three age domains at 1009 ± 4 Ma (2 s.e.), 965 ± 6, and 876 ± 10 Ma. The first two domains record metamorphism of the HBU after anorthosite intrusion; peak monazite–xenotime temperatures for the monazite core domain are 700 °C, and high Th/U values in the second (overgrowth) age domain likely reflect a second high-T monazite growth episode. Formation of cummingtonite coronas on orthopyroxene in opdalite constrains maximum 1010 Ma metamorphic temperatures in the “granulite-facies” terrane to 730–740 °C. Evidence of increased Cl fluid activity in the 965 Ma metamorphism includes higher Cl content of matrix apatite relative to garnet-included apatite (metavolcanics), and Cl-bearing K-hornblende succeeding cummingtonite in coronal overgrowths (opdalite). Extreme monazite Th/U values (75–250) in the rim domain suggest growth during low-T hydrothermal alteration. In the opdalite, secondary singe-grain monazite and monazite + xenotime metasomites in apatite yield ages of 714 ± 24 and 586 ± 88 Ma, temperatures of 325–425 °C, and are interpreted to reflect thermal disturbances associated with late Proterozoic plutonic and volcanic activity in the Upland. This thermal disturbance may be recorded by Rb–Sr age of 567 Ma for biotite from a HBU gneiss. Monazite age domains in metaquartzite (378 ± 28, 272 ± 44 Ma) suggest that low-grade metamorphism (260–320 °C, Mnz–Xno thermometry) of the CVS is not a result of Taconian orogenesis.     

Influence of streambed hydraulic conductivity on solute exchange with the hyporheic zone

A conservative solute tracer experiment was conducted in Indian Creek, a small urban stream in Philadelphia, Pennsylvania to investigate the role of subsurface properties on the exchange between streamwater and the hyporheic zone (subsurface surrounding the stream). Sodium Bromide (NaBr) was used as a conservative tracer, and it was monitored in the surface water at two stations and in the upper bed sediments (shallow hyporheic zone extending from 7.5 to 10 cm below the streambed). The hydraulic conductivity (K) of the upper bed sediments and the lower bed sediments (10–12.5 cm below the streambed) was measured in situ. High tracer concentrations were observed in the upper layer at locations where the hydraulic conductivity of the upper layer was larger than that of the lower layer. Low concentrations in the upper layer were observed in the converse case. A statistically significant relationship between the mass retained in the upper layer and the difference of K values between layers was observed.     

The Piedmont landscape of Maryland: A new look at an old problem

The Piedmont upland of Maryland has been variously interpreted as a peneplain, a series of peneplains, a surface of marine planation, and a landscape in dynamic equilibrium. These different perspectives of landform evolution are related to different scales of time and space. Both equilibrium and episodic erosion features can be recognized in the modern landscape. An equilibrium condition is suggested by adjustment of first and second order streams to rock structure and lithology, entrenchment of some streams against gneiss domes, altitudinal zonation of rock types around gneiss domes, correlation of lithology with overburden thickness on uplands, decreasing overburden thickness on uplands related to decreasing degree of metamorphism of crystalline rocks, and correlation of secondary mineral assemblages with subsurface drainage and slope. The long-term episodic character of erosion is suggested by clastic wedges on the adjacent Coastal Plain, an upland of low relief that truncates non-carbonate rocks of different lithologies, isovolumetric chemical weathering of alumino-silicate rocks, clastic deposition in marble valleys, and weathering profile truncation by modern drainage. The Maryland Piedmont may have been an area of positive relief subject to subaerial erosion since Triassic and possibly Permian time. The upland surface preserved in the eastern Piedmont developed by the Late Cretaceous. In the interval from the Late Cretaceous to the Late Miocene, low input of terrigenous sediments to the Coastal Plain, dominance of marine sedimentation, and spotty evidence of saprolite formation on crystalline rocks, suggest that the Maryland Piedmont was an area of low relief undergoing intense weathering. Incised valleys were formed during a cycle of erosion probably initiated in the Late Miocene and extensive colluvial sediments were deposited on hillslopes by periglacial processes during the Pleistocene.     

山前冲积平原地下水开发利用及保护探讨

本文以山东省宁阳县城东区地下水开发利用情况为例。科学分析了山前冲积平原大量开采地下水引起的区域地下水环境变化，并提出了遏制地下水环境恶化的措施，采取节流与补源并举，严格控制地下水超采。     

准噶尔盆地南缘山前冲断带芦草沟组储层含气性及主控因素分析——以米参2井为例

在野外地质考察、重磁电勘探成果基础上,在准噶尔盆地南缘山前冲断带乌鲁木齐一带进行了页岩气参数井——米参2井施工.综合钻探、地质综合录井、测井和分析测试数据,进行该区芦草沟组泥页岩储层含气性评价,并对储层有机碳含量、孔隙度、矿物组分和页岩裂缝发育特征等方面进行研究.分析储层含气性主控因素,旨在对识别准噶尔盆地南缘山前复杂...     

LATE QUATERNARY FAULTED LANDFORMS AND FAULT ACTIVITY OF THE HUASHAN PIEDMONT FAULT

Based on the 1︰50000 active fault geological mapping, combining with high-precision remote imaging, field geological investigation and dating technique, the paper investigates the stratum, topography and faulted landforms of the Huashan Piedmont Fault. Research shows that the Huashan Piedmont Fault can be divided into Lantian to Huaxian section (the west section), Huaxian to Huayin section (the middle section) and Huayin to Lingbao section (the east section) according to the respective different fault activity. The fault in Lantian to Huaxian section is mainly contacted by loess and bedrock. Bedrock fault plane has already become unsmooth and mirror surfaces or striations can not be seen due to the erosion of running water and wind. 10~20m high fault scarps can be seen ahead of mountain in the north section near Mayu gully and Qiaoyu gully, and we can see Malan loess faulted profiles in some gully walls. In this section terraces are mainly composed of T₁ and T₂ which formed in the early stage of Holocene and late Pleistocene respectively. Field investigation shows that T₁ is continuous and T₂ is dislocated across the fault. These indicate that in this section the fault has been active in the late Pleistocene and its activity becomes weaker or no longer active after that. In the section between Huaxian and Huayin, neotectonics is very obvious, fault triangular facets are clearly visible and fault scarps are in linear distribution. Terrace T₁, T₂ and T₃ develop well on both sides of most gullies. Dating data shows that T₁ forms in 2~3ka BP, T₂ forms in 6~7ka BP, and T₃ forms in 60~70ka BP. All terraces are faulted in this section, combing with average ages and scarp heights of terraces, we calculate the average vertical slip rates during the period of T₃ to T₂, T₂ to T₁ and since the formation of T₁, which are 0.4mm/a, 1.1mm/a and 1.6mm/a, and among them, 1.1mm/a can roughly represent as the average vertical slip rate since the middle stage of Holocene. Fault has been active several times since the late period of late Pleistocene according to fault profiles, in addition, Tanyu west trench also reveals the dislocation of the culture layer of(0.31~0.27)a BP. 1~2m high scarps of floodplains which formed in(400~600)a BP can be seen at Shidiyu gully and Gouyu gully. In contrast with historical earthquake data, we consider that the faulted culture layer exposed by Tanyu west trench and the scarps of floodplains are the remains of Huanxian M_S8½ earthquake. The fault in Huayin to Lingbao section is also mainly contacted by loess and mountain bedrock. Malan loess faulted profiles can be seen at many river outlets of mountains. Terrace geomorphic feature is similar with that in the west section, T₁ is covered by thin incompact Holocene sand loam, and T₂ is covered by Malan loess. OSL dating shows that T₂ formed in the early to middle stage of late Pleistocene. Field investigation shows that T₁ is continuous and T₂ is dislocated across the fault. These also indicate that in this section fault was active in the late Pleistocene and its activity becomes weaker or no longer active since Holocene. According to this study combined with former researches, we incline to the view that the seismogenic structure of Huanxian M_S8½ earthquake is the Huashan Piedmont Fault and the Northern Margin Fault of Weinan Loess, as for whether there are other faults or not awaits further study.     

The Research of the Activity of the Piedmont Fault on the Tangshankou Segment of the Yuguang Basin Southern Marginal Fault

The Yuguang basin is a half-graben basin in the basin-range tectonic zone in northwest Beijing, located at the northern end of the Shanxi graben system, and the Yuguang basin southern marginal fault (YBSMF) controls the formation of this basin. A linear fault escarpment has formed in the proluvial fan on the piedmont fault zone of the Tangshankou segment of YBSMF. A trench across this escarpment reveals three paleo-earthquake events on two active faults. One fault ruptured at about 9ka for the first time, and then faulted again at about 7.3ka, causing the formation and synchronous activity of another fault. Finally, they faulted for the third time, but we cannot determine the faulting time due to the lack of relevant surface deposition. The accumulative vertical displacement of these three events is about 8.1m. We estimate that the average recurrence period of the piedmont fault is about 1.7ka, and the average slip rate of the piedmont fault is about 1.6mm/a. We also estimate the reference magnitude of each event according to the empirical formula.     

Application of a resistivity survey and geographical information system (GIS) analysis for hydrogeological zoning of a piedmont area, Himalayan foothill region, India

A Geographical Information System (GIS) has been used for the integration of the results of 70 vertical electrical soundings and hydrogeological data in the piedmont zone of the Himalayan foothills region of Uttaranchal, India. Indian remote sensing (IRS) LISS-III data has been used to prepare thematic maps for the geomorphology and slope maps of the area. The ranges of electrical resistivity values have been assigned to the different formations by calibrating electrical resistivity values with the borehole data. Electrical resistivity, groundwater level monitoring, and borehole and remote sensing data have been integrated in the GIS analysis to delineate the hydrogeological zoning in the study area. Suitable weights were assigned to the different features affecting the groundwater potential. The total score for a particular location is translated in terms of groundwater potential of the area. The results indicate that the southern part of the study area has a very good groundwater potential for meeting the demand of water for irrigation and domestic purposes whereas the steeply sloping area in the northern part, having high relief, has a poor groundwater potential. The resulting delineation of groundwater potential zones are in general agreement with the available yield data of the tube wells.

---

Resumen Se ha utilizado un Sistema de Información Geográfica (SIG) para la integración de los resultados de 70 sondeos eléctricos verticales y datos hidrogeológicos en la zona piamonte de la región al pie de los Himalaya de Uttaranchal, India. Se han utilizados datos de sensores remotos Indios (IRS) LISS-III para elaborar mapas temáticos de la geomorfología y mapas de pendientes del área. Se han asignado los rangos de valores de resistividad eléctrica a diferentes formaciones mediante la calibración de valores de resistividad eléctrica con datos de barrenos. Se han integrado datos de resistividad eléctrica, monitoreo de niveles de agua subterránea, y barrenos, y datos de sensores remotos mediante un análisis SIG para delimitar la zonificación hidrogeológica del área de estudio. Se asignaron pesos apropiados a las diferentes características que afectan el potencial del agua subterránea. El puntaje total de un lugar particular se ha transformado en términos de potencial de agua subterránea del área. Los resultados indican que la parte sur del área de estudio tiene muy buen potencial de agua subterránea para satisfacer la demanda de agua por riego y uso doméstico mientras que el área de pendientes pronunciadas en la parte norte, de alto relieve, tiene potencial pobre de agua subterránea. La delimitación de zonas potenciales de agua subterránea encaja muy bien con los datos disponibles de rendimiento de pozos entubados.

---

Résumé Un système d’information géographique (SIG) a été utilisé pour l’intégration de résultats en provenance de 70 sondages électriques et données hydrogéologiques dans la zone de piedmont, au pied de l’Himalaya dans la région de Uttaranchal en Inde. Des données du satellite IRS LISS-III ont été utilisées pour préparer des cartes thématiques sur la géomorphologie et les pentes de la zone d’étude. Les valeurs de résistivités électriques ont été assignées aux différentes formations en les calibrant sur les données de sondages. La résistivité électrique, la piézométrie, et les données de sondages et de télédétection ont été intégrées dans une analyse par SIG pour délimiter les zones hydrogéologiques de l’aire d’étude. Des poids ont été assignés aux différents éléments affectant le potentiel en eau souterraine. Le résultat final pour une localisation particulière est traduit en terme de potentiel en eau souterraine. Les résultats indiquent que la partie Sud a un potentiel très bon pour la demande en eau domestique et eau d’irrigation, tandis que les zones plus pentues dans la partie Nord, caractérisée par un relief élevé, présente un potentiel assez pauvre. La délinéation globale des zones à différents potentiels s’accorde assez bien avec les données disponibles concernant la capacité des puits.