新疆小热泉子铜(锌)矿床同位素研究

小热泉子矿床是我国最近发现的一个中型富铜( 锌) 矿床,其矿床成因为众多的矿床学家所关注。本文对该矿床中不同类型矿石、矿物的S、O、H、Si 及稀有( 惰性) 气体He、Ar 同位素特征作了较祥细的论述,同时用KAr 法对硫化物的年龄测定进行了初步尝试。该矿床硫化物的δ34S 值为+ 1-5 ‰～+ 11-1 ‰,平均为6-15 ‰(46) ;3 He/4 He( 初始) 值为5 ×10 - 8 ～2-17 ×10 - 6 ,平均为0-64 ×10 - 6(6) ,40 Ar/36Ar 值为305-27     

LMWOA (low molecular weight organic acid) exudation by salt marsh plants: Natural variation and response to Cu contamination

This work aimed to evaluate, in vitro, the capability of roots of two salt marsh plants to release low molecular weight organic acids (LMWOAs) and to ascertain whether Cu contamination would stimulate or not organic acids exudation. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location to obtain plant exudates. In one of the seasons, similar experiments were carried out but spiking the solution with different amounts of Cu in order to embrace the range between 0 and 1600 nM. In the final solutions as well as in sediment pore water LMWOAs were determined by high performance liquid chromatography. Plants were able to release, in a short period of time, relatively high amounts of LMWOAs (oxalate, citrate, malate, malonate, and succinate). In the sediment pore water oxalate, succinate and acetate were also detected. Therefore, plant roots probably contributed to the presence of some of these organic compounds in pore water. Exudation differed between the plant species and also showed some seasonally variation, particularly for S. maritimus. The release of oxalate by J. maritimus increased with Cu increase in the media. However, exudation of the other LMWOAs did not seem to be stimulated by Cu contamination in the media. This fact is compatible with the existence of alternative internal mechanisms for Cu detoxification, as denoted by the fact that in media contaminated with Cu both plant species accumulated relatively high amounts (29–83%) of the initially dissolved Cu. This study expands our knowledge on the contribution of globally dominant salt marsh plants to the release of LMWOAs into the environment.     

中国斑岩铜矿与埃达克(质)岩关系探讨

对比研究了中国26个主要斑岩铜矿的地球化学特征和年代学,结果表明其中25个矿床与埃达克(质)岩有成因联系,且多数与玄武质下地壳熔融形成的埃达克岩(C型)有关,现有数据表明土屋-延东和普朗斑岩铜矿可能与俯冲板片熔融形成的埃达克岩(O型)有关。容矿斑岩的初始锶值为0.7034～0.7090,均大于洋中脊玄武岩和亏损地幔的初始锶值,多数与EMI的初始锶值接近,推测其源区或源岩主要为玄武质下地壳,少数为洋中脊玄武岩,并受到中、上地壳不同程度的混染,这与两类埃达克岩的源区基本一致。虽然埃达克质岩浆具有形成斑岩铜矿的巨大潜力,但并非所有埃达克岩都能成矿,不同岩体需具体分析。     

四川盐源模范村喜马拉雅期斑岩铜矿床地质特征

文章通过野外地质观察,结合岩矿鉴定、化学分析、稳定同位素测定、稀土元素分析、成岩成矿同位素年龄测定、包裹体测温及成分等的研究,表明四川盐源模范村矿床具有典型斑岩铜矿的特征。成岩的多期次构成复式岩体,断裂构造控制的隐爆碎裂岩筒为成矿提供了通道和沉积场所。多期次成矿,特别是次生富集作用形成了中型规模的Ⅰ号矿体,影响次生富集带发育的F7断裂带起了重要作用。模范村矿床确系典型的斑岩铜矿,但又具独自的成矿特征。     

中条裂谷的递进演化与王屋山地区铜矿成矿地质条件分析

对中条—王屋山地区前寒武纪沉积建造、岩浆建造、构造形态的分析后,反演出中条裂谷的递进演化过程,认为王屋山地区在中条裂谷和区域地壳的演化过程中形成了极为有利的成矿条件:①形成多层含矿建造;②通达地幔的深大断裂提供了丰富的矿源和成矿空间;③频繁的岩浆活动补充了矿质并提供了成矿热能;④剥离断层系统进一步提供了扩容空间;⑤以活化转移为主要机制的强烈变形变质作用对已形成的含矿建造(矿源层)进行改造。因此,王屋山地区具有巨大的找矿潜力。     

中国中元古代裂谷作用及其对层控铜矿床的控制

本文以中国几个重要的层控铜矿为例,并以东川式铜矿及其成矿构造背景——昆阳拗拉谷为重点,分析了它们的大地构造背景和其它地质特征,指出它们均受裂谷—拗拉谷或类似的拉张-裂陷构造所控制,并归纳了这类矿床的主要特征。     

块状硫化物矿床的地球化学找矿标志

近年来国外发现了许多大型块状硫化物矿床，而我国进展还不大。原因之一是我们对这类矿床的地质特征，成矿条件尤其是找矿标志研究还不够。这是一类成矿物质通过热液作用在海底沉积而成的特殊矿床，故在找矿勘探讨既要研究沉积矿时形成的原生晕，又要研究热液经过围岩时蚀变而产生的次生晕?Ｍｎ晕，Ｔｌ，Ｈｇ，Ｂａ，Ａｓ和Ｚｎ等元素的异常，络合剂元素的富集，微量元素的分布，铅同位素，岩石化学异指数尤其是块状硫化物Ｃｕ矿中     

滇中郝家河砂岩铜矿的地球化学及其成因意义

本文论术字滇中生代地层与矿区及春外围马头山组中铜的时空分布与迁移富集规律，揭示了矿床的沉积－后期叠加改造成因。成矿作用经历了同生沉积形成矿源层，后期叠加改造形成矿体的过程。后期改造中铜元素发生了大量迁移，矿质主要来自矿体之下伏紫色矿源层。     

福建省上杭县罗卜岭斑岩型铜（钼）矿床地质特征

罗卜岭异常区处于成矿有利部位，本文通过对该区的热液蚀变分带、岩石化学特征、包裹体特征等的初步研究以及对化探异常进行深部验证，认为罗卜岭异常区存在着斑岩型铜（钼）矿床，是寻找斑岩型铜（钼）矿床的有利靶区。     

辉碲铋矿单矿物的化学分析

辉碲铋矿物经ＨＮＯ３－ＫＣｌＯ３溶解，用火焰原子吸收法或乙二胺四乙酸二钠事滴定法测定Ｂｉ，火焰原子吸收法测定Ｔｅ、Ｆｅ、Ｃｕ，３，３＇－二氨基联苯胺光度法测定Ｓｅ，硫酸重量法测定Ｓ。其结果与矿物化学成分理论值十分接近，主、次量元素平行测定６次，其ＲＳＤ小于０．８％，痕量元素ＲＳＤ（ｎ＝６）小于１０％。