江西省峡江铀矿床两期印支期花岗岩的年代学、岩石地球化学和岩石成因——对华南印支期构造背景和产铀花岗岩成因的指示

位于江西省的峡江铀矿床为华南一个典型的花岗岩型铀矿床,铀矿体产在金滩花岗岩体中。野外地质调查和锆石U-Pb同位素定年工作表明金滩花岗岩体主要由两期的印支期花岗岩组成,其中含矿的等粒状二云母花岗岩形成于239±1Ma,而主体的斑状黑云母花岗岩则形成于226±2Ma。二云母花岗岩具有较高的SiO₂含量（74.09%~74.53%）和明显低的TiO₂、CaO和MgO含量,铝饱和指数为1.20~1.46,含有白云母和石榴子石等过铝质矿物,属于典型的强过铝S型花岗岩。斑状黑云母花岗岩的地球化学特征略微不同于二云母花岗岩,相对富集高场强元素和稀土元素,具有明显更低的Rb/Sr比值以及更小的Eu负异常,铝饱和指数变化为1.05~1.13,属于弱过铝到强过铝花岗岩。同位素组成上,两者都具有较低的ε_Nd（t）值（二云母花岗岩：-9.0~-8.8;斑状黑云母二长花岗岩：-9.8~-9.4）和古元古代的模式年龄（二云母花岗岩：1.73~1.75Ga;斑状黑云母二长花岗岩：1.77~1.80Ga）。地球化学和同位素特征表明金滩岩体中的这两期印支期花岗岩应该都为S型花岗岩。较高的Rb/Sr比值和较低的CaO/Na₂O比值表明二云母花岗岩主要由富粘土的泥质沉积岩部分熔融而来,而斑状黑云母二长花岗岩则主要由贫粘土的碎屑沉积岩部分熔融而来。金滩岩体中的两期印支期花岗岩分别对应于华南印支期同碰撞挤压和碰撞后伸展期的岩浆作用。二云母花岗岩含有更高的U含量,矿物学以及地球化学特征与华南其他的典型产铀花岗岩类似。对比研究表明,华南印支期产铀花岗岩的形成应与同碰撞期挤压背景下的泥质沉积岩的部分熔融有关。     

Emplacement Ages and Petrogenesis of the Molybdenum–bearing Granites in the Jinduicheng Area of East Qinling, China: Constraints from Zircon U–Pb Ages and Hf Isotopes

The Mesozoic porphyry assemblage in the Jinduicheng area is a special molybdenum area in China, the Mo deposits, including the Jinduicheng, Balipo, Shijiawan, Huanglongpu, are distributed. The emplacement age and geochemical features of the granites in the Jinduicheng area can provide essential information for the exploration and development of the porphyry molybdenum deposit. In this study, we report LA–ICP–MS zircon U–Pb age and zircon Hf isotopic compositions of granite porphyries from the Jinduicheng area, and provide insights on the petrogensis and source characteristics of the granites. The results show that the zircon U–Pb ages of the Jinduicheng granite porphyry (143±1 Ma) and the Balipo granite (154±1 Ma), agree well with the Re–Os ages of molybdenite in the Jinduicheng molybdenum polymetallic deposit (139±3 Ma) and the Balipo molybdenum polymetallic deposit (156±2 Ma), indicating that the emplacement of granite porphyries occurred between Late Jurassic and Early Cretaceous. Zircons granite from the Jinduicheng area give the εHf(t) values mainly ranging from ?10 to ?16, and ?20 to ?24, respectively, corresponding to two–stage model ages (tDM2: mainly focused on 1.86–2.0 Ga, and 2.2–2.6 Ga, respectively) of zircons of the granite from the Jinduicheng values. The ore–forming materials are mainly derived from crust, with minor mantle substances. Zircons of the granite from the Balipo area give εHf(t) values ranging from ?18 to ?20, ?28 to ?38, and ?42 to ?44, respectively, corresponding to two–stage model ages (tDM2: mainly focused on 1.88–3.0 Ga, and 3.2–3.90 Ga, respectively). the εHf(t) values of the Jinduicheng porphyry more than that of the Balipo porphyry, and two–stage model ages (tDM2) less than that of the Balipo porphyry, shows that he source of the porphyries originated from ancient lower crustal materials in the Jinduicheng area, and mixed younger components, more younger components contributed for the source of the Jinduicheng porphyry.     

Timing of Magma Mixing in the Gangdisě Magmatic Belt during the India-Asia Collision： Zircon SHRIMP U-Pb Dating

Abstract  Abundant mafic microgranular enclaves (MMEs) extensively distribute in granitoids in the Gangdisê giant magmatic belt, within which the Qüxü batholith is the most typical MME‐bearing pluton. Systematic sampling for granodioritic host rock, mafic microgranular enclaves and gabbro nearby at two locations in the Qüxü batholith, and subsequent zircon SHRIMP II U‐Pb dating have been conducted. Two sets of isotopic ages for granodioritic host rock, mafic microgranular enclaves and gabbro are 50.4±1.3 Ma, 51.2±1.1 Ma, 47.0±1 Ma and 49.3±1.7 Ma, 48.9±1.1 Ma, 49.9±1.7 Ma, respectively. It thus rules out the possibilities of mafic microgranular enclaves being refractory residues after partial melting of magma source region, or being xenoliths of country rocks or later intrusions. Therefore, it is believed that the three types of rocks mentioned above likely formed in the same magmatic event, i.e., they formed by magma mixing in the Eocene (c. 50 Ma). Compositionally, granitoid host rocks incline towards acidic end member involved in magma mixing, gabbros are akin to basic end member and mafic microgranular enclaves are the incompletely mixed basic magma clots trapped in acidic magma. The isotopic dating also suggested that huge‐scale magma mixing in the Gangdisê belt took place 15–20 million years after the initiation of the India‐Asia continental collision, genetically related to the underplating of subduction‐collision‐induced basic magma at the base of the continental crust. Underplating and magma mixing were likely the main process of mass‐energy exchange between the mantle and the crust during the continental collision, and greatly contributed to the accretion of the continental crust, the evolution of the lithosphere and related mineralization beneath the portion of the Tibetan Plateau to the north of the collision zone.     

湖南城步火成岩锆石SHRIMP U-Pb年龄及其对江南造山带新元古代构造演化的约束

目前对新元古代中期江南造山带构造演化及钦杭结合带南西段构造性质存在不同认识。本文对湘西南城步地区新元古代火山岩和花岗岩进行了锆石SHRIMPU-Pb年龄测定并厘定其构造环境,从而为区域构造演化提供了约束。城步新元古代花岗岩侵入于云场里组变质火山-沉积地层中。云场里组变质火山岩与花岗岩的锆石SHRIMPU-Pb年龄分别为828±10Ma和805.7±9.2Ma。构造环境的地球化学判别图解表明花岗岩形成于岛弧环境;区域地质背景指示云场里组可能形成于活动陆缘弧前盆地。以城步火山岩和花岗岩研究为基础,结合区域地质资料,提出新元古代中期江南造山带西段构造演化过程:872～835Ma期间为陆缘盆地;835～820Ma期间俯冲造山,江南造山带形成基性—超基性岩和早阶段岛弧花岗闪长岩,东侧的城步地区为弧前盆地;820～810Ma期间江南造山带发生弧-陆碰撞;810～800Ma期间江南造山带进入后碰撞环境并形成晚阶段强过铝(黑云母)花岗岩,东侧城步地区因华南洋洋壳俯冲而形成新的岛弧;800Ma后华南进入伸展裂陷盆地演化阶段。上述认识揭示出扬子陆块东南缘的连续岛弧增生过程,同时为钦杭结合带南西段雪峰期"残留洋盆"属性提供了新证据。     

新疆西准噶尔苏云河钼矿床含矿岩体地球化学和年代学

苏云河钼矿床位于新疆西准噶尔巴尔鲁克山西段,容矿岩石为二长花岗岩和二长花岗斑岩。这些花岗岩具有类似的地球化学特征:富集Rb、Th、U和LREE,相对亏损Ba、P、Ti,属于高钾钙碱性I型花岗岩系列,局部经历过强烈的分离结晶作用。LA-ICPMS锆石U-Pb定年结果显示苏云河钼矿区的成岩年龄为309.3~310.2 Ma,这表明与成矿有关的岩浆活动发生于晚石炭世。黑云母的Ti温度计表明Ⅰ号和Ⅲ号岩体的结晶温度相近,为695~728℃;而Ⅱ号岩体的结晶温度较低,为642~668℃。同时根据角闪石-斜长石压力计获得Ⅰ号和Ⅲ号岩体的结晶压力为(3.0~3.9)×108Pa。综合地球化学研究表明,苏云河钼矿区3个岩体均形成于岛弧环境。此外,以苏云河钼矿床为代表的巴尔鲁克山成矿带与哈萨克斯坦境内的巴尔喀什成矿带在岩石地球化学、成岩成矿时代等方面具有许多类似的特点,表明巴尔鲁克山成矿带可能是巴尔喀什成矿带在中国境内的延伸。     

朝鲜半岛平南盆地中元古代岩浆事件

朝鲜平南盆地翁津地区发育中元古代黄海群和同时期(称之为瓮津期)花岗岩,花岗岩体侵入于黄海群。本文采用锆石原位微区U-Pb定年技术,对黄海群中的酸性火山岩及花岗岩进行了年龄测试。获得的数据表明,黄海群中下部层位及上部层位的酸性火山岩分别在1235±5Ma和1203±7Ma喷发,由此说明黄海群的沉积时代应为中元古代,而不是传统上认为的古元古代;两个翁津期花岗岩体(翁津和黄衣山岩体)的侵位年龄分别为1251±22Ma和1248±13Ma,为中元古代花岗质岩浆活动的产物。上述1251~1203Ma年龄的获得,表明朝鲜半岛发育中元古代岩浆作用,从而明确朝鲜黄海裂谷与华北东缘裂谷在时间上具有同期性,同时也表明中国华北与朝鲜在中元古代具有类似的发展历史。     

鲁西峄山花岗岩中粗大钾长石斑晶成因探讨

在鲁西地区新太古代晚期(五台期)峄山花岗岩的黑石查和望子山花岗质岩体的岩石中,钾长石粗大斑晶内有自形程度较高的斜长石等矿物包裹体沿其环带定向排列.根据野外观察及岩石、矿物学特征测试分析,钾长石斑晶属于岩浆结晶形成的原生斑晶,受化学成分及侵位结晶过程中的物理化学条件影响,钾长石的生长速度大于其成核密度,因而形成粗大斑晶.估算岩浆温度＞950℃,钾长石斑晶快速生长时岩浆温度为750℃,过冷度△T≈150℃,基质结晶时岩浆温度为600℃,△T≈300℃.     

瑶岭钨矿白基寨花岗岩地质特征及成矿意义

通过地质填图、钻探、土壤地球化学、磁法测量和岩石地球化学等手段,揭露了白基寨花岗岩的空间架构和地质特征,并分析了花岗岩的地球化学特征。该岩体具有高分异性(SiO270%,δEu在0.03～0.09之间),高K2O,且K2O/Na2O1等特征。Ba、Nb、P和Ti相对亏损,Rb、Ta、Th和K等大离子亲石元素富集,稀土元素四分组效应明显,呈海鸥"V"型。花岗岩源岩为泥质岩和硬砂岩混合而成,形成于同碰撞环境。岩体具有边部倾角小,高挥发份元素向上运移明显、强烈流体、熔体相互作用等有利成矿条件特点,在岩体边部成矿流体与碳酸岩盐相互作用形成白钨矿化体。矿区中部凹勺状区域和ZK3002-ZK3001段是找矽卡岩型白钨矿的有利潜在区域。     

Significance of Devonian–Carboniferous igneous activity in Tasmania as derived from U–Pb SHRIMP dating of zircon

A series of new Sensitive High-Resolution Ion MicroProbe (SHRIMP) U – Pb ages is presented for Palaeozoic (mainly Devonian and Carboniferous) granites from Tasmania. In virtually all instances the new ages are significantly older than previously determined Rb – Sr and K – Ar ages, even though the level of emplacement had been thought to be too shallow to allow loss of radiogenic daughter products. In two extreme cases, granite bodies at South West Cape and Elliott Bay that had previously yielded Carboniferous Rb – Sr and Early Devonian K – Ar ages, respectively, are now both shown to be Late Cambrian. In northeast Tasmania, granitic activity in the Blue Tier Batholith lasted for about 22 million years, with I-type magmas being followed by S-types only toward the end of that time. The exclusively I-type granites of the Scottsdale Batholith formed about 10 million years after the initiation of igneous activity in the Blue Tier Batholith, and were emplaced over a comparatively short time interval (4 – 5 million years). The new data confirm a previously held view, based on Rb – Sr analysis, that the economically important Lottah Granite crystallised roughly 9 million years later than the nearby Poimena Granite and, therefore, could not have been derived by magmatic fractionation of the latter. A regional deformation equated with the Tabberabberan Orogeny has been dated at about 390 Ma in northeastern Tasmania, based on the presence or absence of a northwest-trending foliation in the different granite bodies. The oldest granites occur in the northeast of Tasmania, with an irregular progression of ages to the west coast. A trend of this type could have arisen in an arc-free or arc-related environment. If the latter applies, either flat subduction or processes associated with the amalgamation of eastern and western basement terranes might be the controlling mechanism. Eastern Tasmania experienced a trend from mafic I-type to progressively more felsic, largely S-type igneous activity, but the trend for western Tasmania is not as obvious. The trend for eastern Tasmania is an exception to the general rule for the Lachlan Orogen, possibly signifying that the mid-crust was relatively cool when the first I-type granites were generated. Crustal thickening during the Tabberabberan Orogeny may have been a prerequisite for the generation of later, more felsic, S- and I-types.