新疆西准噶尔苏云河钼矿床含矿岩体地球化学和年代学

苏云河钼矿床位于新疆西准噶尔巴尔鲁克山西段,容矿岩石为二长花岗岩和二长花岗斑岩。这些花岗岩具有类似的地球化学特征:富集Rb、Th、U和LREE,相对亏损Ba、P、Ti,属于高钾钙碱性I型花岗岩系列,局部经历过强烈的分离结晶作用。LA-ICPMS锆石U-Pb定年结果显示苏云河钼矿区的成岩年龄为309.3~310.2 Ma,这表明与成矿有关的岩浆活动发生于晚石炭世。黑云母的Ti温度计表明Ⅰ号和Ⅲ号岩体的结晶温度相近,为695~728℃;而Ⅱ号岩体的结晶温度较低,为642~668℃。同时根据角闪石-斜长石压力计获得Ⅰ号和Ⅲ号岩体的结晶压力为(3.0~3.9)×108Pa。综合地球化学研究表明,苏云河钼矿区3个岩体均形成于岛弧环境。此外,以苏云河钼矿床为代表的巴尔鲁克山成矿带与哈萨克斯坦境内的巴尔喀什成矿带在岩石地球化学、成岩成矿时代等方面具有许多类似的特点,表明巴尔鲁克山成矿带可能是巴尔喀什成矿带在中国境内的延伸。     

秦祁结合部位宝鸡地区早泥盆世香泉A型正长花岗岩年龄、地球化学特征及其构造意义

对秦祁结合部位宝鸡地区香泉正长花岗岩进行了LA-ICP-MS锆石U-Pb年龄和岩石地球化学研究。结果显示,锆石~(206)Pb/~(238)Pb年龄加权平均值为410±5Ma(MSWD=0.20,n=18),限定该岩体的形成时代为早泥盆世。香泉正长花岗岩具有高硅(SiO_2=69.63%~73.94%)、富钾(K_2O=4.24%~4.88%,K_2O/Na_2O=1.23~1.44)、富铁(TFe_2O_3=2.10%~3.70%,TFe_2O_3/MgO=3.88~6.84)、低镁(MgO=0.31%~0.94%)、低磷(P_2O_5=0.08%~0.21%)的特征,属准铝质、高钾钙碱性系列。香泉正长花岗岩稀土元素含量较高(318×10~(-6)~499×10~(-6)),表现出明显的负Eu异常(δ Eu=0.37~0.46),富集Rb、Th、Zr、Sm、Ga(10000×Ga/Al=2.59~2.93)等微量元素,贫Ba、Nb、Ta、Sr,整体表现出A型花岗岩特征。结合区域资料认为,香泉正长花岗岩形成于造山后环境,为低压环境下长英质地壳物质部分熔融成因。     

西藏班公湖-怒江缝合带中段碰撞后A型花岗岩的时代及其对洋盆闭合时间的约束

近年来地质调查在班公湖-怒江缝合带中段发现了一批A型花岗岩,岩体呈面积不大(＜1 km2)的岩株产出,岩性上分为钾长花岗岩和花岗闪长斑岩两种,侵入白垩系地层中.岩石化学上这些A型花岗岩相对富硅,SiO2含量在68.62％～75.36％之间,全碱含量(K2O+Na2O=8.03％ ～ 9.37％)和全铁含量(FeO(T)...     

Timing of Magma Mixing in the Gangdisě Magmatic Belt during the India-Asia Collision： Zircon SHRIMP U-Pb Dating

Abstract  Abundant mafic microgranular enclaves (MMEs) extensively distribute in granitoids in the Gangdisê giant magmatic belt, within which the Qüxü batholith is the most typical MME‐bearing pluton. Systematic sampling for granodioritic host rock, mafic microgranular enclaves and gabbro nearby at two locations in the Qüxü batholith, and subsequent zircon SHRIMP II U‐Pb dating have been conducted. Two sets of isotopic ages for granodioritic host rock, mafic microgranular enclaves and gabbro are 50.4±1.3 Ma, 51.2±1.1 Ma, 47.0±1 Ma and 49.3±1.7 Ma, 48.9±1.1 Ma, 49.9±1.7 Ma, respectively. It thus rules out the possibilities of mafic microgranular enclaves being refractory residues after partial melting of magma source region, or being xenoliths of country rocks or later intrusions. Therefore, it is believed that the three types of rocks mentioned above likely formed in the same magmatic event, i.e., they formed by magma mixing in the Eocene (c. 50 Ma). Compositionally, granitoid host rocks incline towards acidic end member involved in magma mixing, gabbros are akin to basic end member and mafic microgranular enclaves are the incompletely mixed basic magma clots trapped in acidic magma. The isotopic dating also suggested that huge‐scale magma mixing in the Gangdisê belt took place 15–20 million years after the initiation of the India‐Asia continental collision, genetically related to the underplating of subduction‐collision‐induced basic magma at the base of the continental crust. Underplating and magma mixing were likely the main process of mass‐energy exchange between the mantle and the crust during the continental collision, and greatly contributed to the accretion of the continental crust, the evolution of the lithosphere and related mineralization beneath the portion of the Tibetan Plateau to the north of the collision zone.     

Magmatic evolution of Li–F, rare-metal granites: a case study of melt inclusions in the Khangilay complex, Eastern Transbaikalia (Russia)

We report compositions of homogenized quartz-hosted melt inclusions from a layered sequence of Li-, F-rich granites in the Khangilay complex that document the range of melt evolution from barren biotite granites to Ta-rich, lepidolite–amazonite–albite granites. The melt inclusions are crystalline at room temperature and were homogenized in a rapid-quench hydrothermal apparatus at 200 MPa before analysis. Homogenization runs determined solidus temperatures near 550 °C and full homogenization between 650 and 750 °C. The compositions of inclusions, determined by electron microprobe and Raman spectroscopy (for H₂O), show regular overall trends of increasing differentiation from the least-evolved Khangilay units to apical units in the Orlovka intrusion. Total volatile contents in the most-evolved melts reach over 11 wt.% (H₂O: 8.6 wt.%, F: 1.6 wt.%, B₂O₃: 1.5 wt.%). Concentrations of Rb range from about 1000 to 3600 ppm but other trace elements could not be measured reliably by electron microprobe. The resulting trends of melt evolution are similar to those described by the whole-rock samples, despite petrographic evidence for albite- and mica-rich segregations previously taken as evidence for post-magmatic metasomatism.

Melt variation trends in most samples are consistent with fractional crystallization as the main process of magma evolution and residual melt compositions plot at the granite minimum in the normative Qz–Ab–Or system. However, melts trapped in the highly evolved pegmatitic samples from Orlovka deviate from the minimum melt composition and show compositional variations in Al, Na and K that requires a different explanation. We suggest that unmixing of the late-stage residual melt into an aluminosilicate melt and a salt-rich dense aqueous fluid (hydrosaline melt) occurred. Experimental data show the effectiveness of this process to separate K (aluminosilicate melt) from Na (hydrosaline melt) and high mobility of the latter due to its low viscosity and relatively low density may explain local zones of albitization in the upper parts of the granite.     

REE Abundance and REE Minerals in Granitic Rocks in the Nanling Range,Jiangxi Province,Southern China,and Generation of the REE‐rich Weathered Crust Deposits

Studies of Mesozoic granites associated with rare earth element (REE)‐rich weathered crust deposits in southernmost Jiangxi Province indicate that they have high‐K to shoshonite compositions and belong to ilmenite‐series I‐type granites. Of the studied rocks at 59–292 ppm of bulk REE content, the highest are seen in the biotite granites of Dingnan (358, 429 ppm) and mafic biotite granite of the Wuliting Granite (344 ppm) near the Dajishan tungsten mine, both areas where weathered‐crust REE deposits occur. REE‐bearing accessory minerals in these granites are mainly zircon, apatite and allanite, and REE‐fluorocarbonates are common. REE enrichment occurs in the rims of apatite crystals, and in fluorocarbonates that occur along grain boundaries of and cracks in major silicate minerals, and in fluorocarbonates that replaced altered biotite. It is therefore thought that a major part of the REE content of these granites was concentrated during deuteric activity, rather than during magmatic crystallization. The crack‐filling REE‐fluorocarbonates could subsequently have been easily leached out and deposited in weathered crust developed during a long period of exposure.     

哈密头苏泉哈尔欣巴A型花岗岩厘定

初步研究表明新疆哈密头苏泉地区哈尔欣巴花岗岩为A型花岗岩.该岩体富硅(SiO2=71.87%~76.80%)和碱(K2O+N2O=7.39%~8.94%),贫铁、锰、镁(FeOt 0.67%~2.04%;MnO 0.03%~0.06%;MgO 0.10%~0.61%),具较高FeOt/MgO比值,A/NKC=0.78~1.02,属准铝质花岗岩石.在微量元素和稀土元素组成上,岩石富Zr,Rb,Ce等不相容元素,亏损Ni,Co,Cr等元素.10000×Ga/Al为3.12~4.1,大于A型花岗岩下限值(2.6).在Zr,Ce,Nb,Y与10000×Ga/Al,及(Nb+Zr+Ce+Y)/(FeOt/MgO)、SiO2/( FeOt/MgO)图解中大多数点都落在A型花岗岩区域.在A1-A2构造环境判别图上显示后造山花岗岩特征.对头苏泉地区哈尔欣巴A型花岗岩的厘定,为研究该区地壳物质组成及构造演化具重要意义.     

A型花岗岩的研究进展及意义

A型花岗岩主要形成于伸展的构造背景中,是构造环境识别的重要岩石学标志之一。由于形成于特殊的构造背景和重要的地球动力学意义,A型花岗岩的研究一直得到广泛的关注,但是仍旧有许多问题(如命名、分类和成因等)在争论之中。本文从下面几个方面对A型花岗岩的研究现状进行了较系统的总结:(1)A型花岗岩的概念及特征;(2)A型花岗岩与高分异I、S型花岗岩的区别;(3)A型花岗岩的物质来源及成因模式;(4)A型花岗岩的实验岩石学成果;(5)A型花岗岩的分类;(6)A型花岗岩的构造背景及动力学意义。A型花岗岩在形成过程中斜长石、斜方辉石可能为主要的残留或分离结晶矿物相。除了传统的A1(非造山)、A2(后碰撞)分类外,"还原型"和"氧化型"的分类方案最近也受到广泛关注。     

江南造山带新元古代中期(830～750Ma)岩浆活动及对构造演化的制约

连接扬子地块和华夏地块的江南造山带是华南前寒武纪最重要的构造单元,其形成和演化长期以来备受关注。在江南造山带的范围内广泛发育了新元古代岩浆岩,它们是探讨江南造山带构造演化的重要对象,但其成因和形成的构造背景却备受争论。本文系统收集和分析了江南造山带830~820 Ma花岗岩、800~780 Ma酸性岩和800~750 Ma基性岩的地球化学数据。研究表明,不同时间段的岩石成因类型存在系统差异,830~820 Ma的花岗岩主要为S型花岗岩,800~780 Ma的酸性岩主要为A型酸性岩,而800~750 Ma的基性岩以拉斑系列和碱性系列为主,并在构造判别图中显示了板内玄武岩(WPB)和洋中脊玄武岩(MORB)的特征。综合同位素年代学、岩石地球化学和沉积学等学科领域的研究成果我们认为:扬子北缘和西缘应先于东南缘在1000~900 Ma期间发生碰撞,而此时的东南缘仍为活动大陆边缘;直到~830 Ma,扬子地块与华夏地块沿江南造山带发生拼贴,但只是陆-弧-(微)陆之间的"软碰撞",而无山脉隆升和高级变质作用,各个块体之间处于"联而不合"的状态,大洋岩石圈拆沉之后的软流圈上涌和由拆沉所引起的拉张作用导致了上覆岩石圈和陆壳发生部分熔融,产生了江南造山带830~820 Ma的S型花岗岩;随着全球Rodinia超大陆的裂解,~820 Ma,华南裂谷盆地开启,并在随后的裂解过程中发育了大量与伸展有关的800~780 Ma A型酸性岩和基性岩脉/墙,而其明显高于同时代MORB源区的地幔潜能温度显示,导致Rodina超大陆裂解的地幔柱可能对该时期岩浆岩的地幔源区有一定影响;随着拉张作用的不断加强,出现了760~750 Ma碱性系列和具MORB特征的基性岩,此时的软流圈地幔既提供热量又有物质供应。     

Interaction of crustal and mantle materials,sources of trace elements during the formation and evolution of Early Paleozoic Li-rich granite-pegmatite systems in southeastern Tuva

We present new data on the age, composition, and environments of formation of granites of the Kystarys complex and the associated Li-rich rare-element pegmatites of the South Sangilen pegmatite belt including the large Tastyg lithium deposit. It has been established that they formed during the Early Paleozoic collisional orogeny in the Tuva-Mongolian massif at the Cambrian-Ordovician boundary. The granites of the Kystarys complex are moderately alkaline high-K rocks and are enriched in Zr, Nb, Y, and REE; therefore, they are classified as postcollisional, transitional to within-plate (A-type). The spodumene pegmatites of the South Sangilen pegmatite belt are similar to the above granites in age and isotopic and geochemical parameters, which suggests a paragenetic relationship between these rocks. Pegmatites form several pegmatite fields within the belt, which differ in trace-element signatures. In addition to predominant Li, Cs, and Ta, specific to all spodumene pegmatites (LCT family), pegmatites of two fields have high contents of Nb, Y, REE, and Zr, which are indicator elements of NYF family pegmatites. It has been established that the formation of spodumene pegmatites with combined LCT-NYF geochemical signatures was preceded by the intrusion of dikes of monzogabbro with the geochemical characteristics of OIB and of alkali aegirine granites and by the formation of associated metasomatites enriched in Zr, Nb, Y, and REE. Based on the geological, mineralogical, and geochemical data, we substantiate the hypothesis of the formation of Li-bearing granite-pegmatite melts from a mixed source resulted from the influence of fluids of an alkaline igneous complex of mantle genesis on the crustal protolith.