The interpretation of reaction textures in Fe‐rich metapelitic granulites of the Musgrave Block,central Australia: constraints from mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3

Fe‐rich metapelitic granulites of the Musgrave Block, central Australia, contain several symplectic and coronal reaction textures that post‐date a peak S2 metamorphic assemblage involving garnet, sillimanite, spinel, ilmenite, K‐feldspar and quartz. The earliest reaction textures involve spinel‐ and quartz‐bearing symplectites that enclose garnet and to a lesser extent sillimanite. The symplectic spinel and quartz are in places separated by later garnet and/or sillimanite coronas. The metamorphic effects of a later, D3, event are restricted to zones of moderate to high strain where a metamorphic assemblage of garnet, sillimanite, K‐feldspar, magnetite, ilmenite, quartz and biotite is preserved. Quantitative mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using Thermocalc 3.0 and the accompanying internally consistent dataset provide important constraints on the influence of TiO₂ and Fe₂O₃ on biotite‐bearing and spinel‐bearing equilibria, respectively. Biotite‐bearing equilibria are shifted to higher temperatures and spinel‐bearing equilibria to higher pressures and lower temperatures in comparison to the equivalent equilibria in K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH). The sequence of reaction textures involving spinel is consistent with a D2 P–T path that involved a small amount of decompression followed predominantly by cooling within a single mineral assemblage stability field. Thus, the reaction textures reflect changes in modal proportions within an equilibrium assemblage rather than the crossing of a univariant reaction. The D3 metamorphic assemblage is consistent with lower temperatures than those inferred for D2.     

Mixing, sediment accumulation and focusing using 210Pb and 137Cs

The Portil lagoon is a natural freshwater reservoir located at the southwest of Spain, near the coast. In its surroundings an important tourist complex has been developed since the earlier 1970s. This has resulted in increased loads of nutrients, specially during summer months. In order to evaluate the impact from humans on the lagoon caused by anthropogenic activities, we have determined vertical profiles of excess ²¹⁰Pb and ¹³⁷Cs in a sediment core taken from its bottom. Vertical profile of excess ²¹⁰Pb seems to indicate that the sediment core was affected by large-scale mixing processes. Nevertheless this possibility was ruled out based on the shape of the ¹³⁷Cs vertical distribution after modelling the ¹³⁷Cs profile considering large-scale mixing. The chronology developed from ²¹⁰Pb and ¹³⁷Cs has allowed us to calculate the temporal evolution of the mass sedimentation rate during the last century. This mass sedimentation rate increased in 1973: from 0.08(2) g cm^-2 a^-1 in the period 1900-1973 to 0.17(5) g cm^-2 a^-1 in the period 1973-1995. This increase could be related to land-movements in the drainage area and to permitted sewage inputs into the lagoon, both with its origin in the growing/running of the surrounding tourist complex.     

Microbial production of CO2 in red soil in Stone Forest National Park

Lunan stone forest is a kind of typical karst in China, which is mainly developed under red soil. In the winter of 1999, three study sites were chosen in stone forest national park according to vegetation cover, geomorphologic location and soil types. CO2 concentration was measured with Gastec pump at different depths of soil (20, 40, 60 cm) and at the same time soil samples were gathered and soil properties such as soil moisture, pH, soil organic content were analyzed and the total number of viable microbes were counted in laboratory. In the study, dependent variable was chosen as the mean soil log (PCO2), and soil properties were chosen as the independent variables. Multiple stepwise regression analysis showed that the total amount of microbes and soil moisture are the best indicators of the CO2 production, with the equation LOG(PCO2) = - 0.039(TNM) - 0.056(Mo) + 1.215 accounting for 86% of the variation of the soil CO2 concentration, where TNM is the total number of microbes in the soil and Mo is the moisture of soil sample.     

不同浓度Li2SO4水溶液结构的X射线衍射研究

用θ～ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。     

长江中下游晚中生代中基性岩的铅同位素特征:富集地幔的证据

长江中下游东段庐枞、怀宁、繁昌、铜陵和宁芜地区的中基性岩属于碱性系列 ,具有高的U ,Th含量和Th/Pb ,U/Pb比值 ,分别平均为 2 .82× 10 -6,9.5 6× 10 -6和 0 .6 35 ,0 .184。样品的初始铅同位素 (130Ma)组成为 :(2 0 6Pb/ 2 0 4Pb) i=17.6 5～ 18.6 0 ,(2 0 7Pb/ 2 0 4Pb) i=15 .4 2～ 15 .5 0 ,(2 0 8Pb/ 2 0 4Pb) i=37.6 7～ 38.0 4。形成中基性岩的原始岩浆来源于富集的岩石圈地幔 ,具有EMⅠ和EMⅡ ,且以EMⅡ为主的特征。和长江中下游西段黄石地区以及大别地块西南部玄武岩的比较表明 ,长江中下游地区岩石圈地幔高的Th/Pb和U/Pb比值可能和俯冲板片析出流体的交代有关。晚中生代时期 ,华北板块岩石圈地幔以EMⅠ特征为主 ,华南板块岩石圈地幔以EMⅡ特征为主 ,岩石圈地幔性质的区域性分布与印支期扬子板块深俯冲事件密切相关。虽然中国东部新生代玄武岩因岩石圈大规模减薄表现了亏损特征 ,但残留的富集岩石圈地幔在中国东部新生代玄武岩的Pb同位素中仍有所反映     

光催化氧化法处理难降解废水的研究进展

综述了光催化氧化处理难降解废水的研究现状及发展趋势。介绍了影响光催化氧化反应速率的因素及光催化氧化法在处理难降解废水中的应用。     

渤海湾老狼坨子海岸带^14C,^137Cs、^210Pb测年与现代沉积速率的加速趋势

通过对渤海湾西岸L剖面中同一关键层的碳酸钙和原生腹足类壳债权的^14C测年对比研究，确定了晚全新世的2800cal BP的层位及沉积速率0.045cm/a;8个样柱的^137Cs和^210Pbex强度、蓄积量揭示了距今约120年来堤后盐沼的平均沉积速率约为0.35cm/a，而面向开放海湾的潮坪上部则达到约2-3cm/a。研究区近1个世纪以来沉积速率的加速趋势，是渤海湾西岸泥质海岸带的特征之一。     

陕北新庄地区延长组长2油层组储层特征

一般河道砂体的正粒序性决定了其下部物性条件优于上部，但新庄地区长2油层组河道砂体的物性特征截然相反，而是中上部物性条件好，下部物性条件普遍差。在储层岩石学特征、孔隙类型等研究的基础上，对此进行了探讨，认为造成其特殊性的原因主要是由于压实、胶结、次生加大等作用。指出河道边滩砂体中上部储层为该区的主力储层。     

利用高铁钾长石粉合成13X沸石分子筛的实验研究

对江苏丰县的富钾页岩进行预处理，得到钾长石含量达76．4％的钾长石粉，其Fe2O3含量高达7．52％。以此钾长石粉为原料经过焙烧处理、水热合成实验，在铁含量较高情况下成功合成了13X沸石分子筛，并采用正交实验法确定了优化工艺参数。对实验产物的主要性能测试表明，合成的富铁沸石产品与13X沸石分子筛工业产品相似，吸附量达到国家化学工业产品标准，可用于对含重金属离子废水的吸附处理。