滇东北渔户村组内的富铅锌矿床成矿地质特征及成因

渔户村组为滇东北富铅锌矿床的重要产出层位。通过茂粗、金沙厂、五星、乐红、大海等矿床，总结了滇东北渔户村组内的富铅锌矿床的地质特征及成因，认为其与喷流沉积成矿作用和后期改造作用有关，为海底火山喷流沉积－改造成因。     

大功率激电在鄂拉山口寻找隐伏矿体中的应用

鄂拉山口银多金属矿床位于鄂拉山成矿带东南端,第四系覆盖厚,沼泽发育,存在常年冻土层和碎石流,用常规物探在该区找矿效果不显著.后经大功率激电剖面测量,圈出了具一定规模的激电异常带1条,推断为矿异常,经工程验证,发现隐伏银铅锌矿（化）体多条,说明本区采用大功率激电指导找矿效果显著.     

隐伏矿体定位预测的方法学基础及方法论

隐伏矿体定位预测是当前成矿学和成矿预测学的科学前沿和研究重点.重点讨论了隐伏矿体定位预测的方法学基础及方法论.指出:(1)大思路、小尺度、高精度是隐伏矿体定位预测的方法学基础;(2)成矿分析是隐伏矿体定位预测的方法论;(3)结构分析是隐伏矿体定位预测的最有效途径;(4)组合预测方法是隐伏矿体定位预测的新工具.     

发挥高精度磁测作用的几个实例

简要介绍了高精度磁测的应用现状.通过金厂沟金矿区辽河群大石桥岩组与盖县组接触界限的划分,以及阜新建设花岗岩与长英质糜棱岩边界的划分等实例,说明得用高精度磁测结果,在配合地质填图、划分地质界线、圈定矿体和寻找古墓及古坑道等地质问题方面的优越性.用于隐伏区地质填图时,不仅能确定强磁性岩石边界,而且还能确定弱磁性岩石边界.在提高信息密度的前提下,根据磁化率K值和剩余磁化强度J_r值的不同,在典型成矿区能直接圈定弱磁性矿体.     

马槽滩磷矿区的矿体形态特征及合理勘查工程间距

马槽滩磷矿区矿体形态复杂,底板起伏不定,多年来勘查工程间距不断改变,因此用多种方法讨论了合理工程间距.探采对比和数理统计学方法求得控制资源量的合理工程间距分别为200m×150m和200m×100m;控制半变异函数的变程亦为200m×100m,均与现行规范相吻合。但沿走向和倾向的变异相同,因此建议用正方形网格进行勘查更为合理,间距为150m×150m。     

含铁闪锌矿热容的实验测定与分析

利用美国ＤｕＰｏｎｔ公司的９９００型差示扫描量热仪对３个含铁闪锌矿样品的热容进行了实验测定,并讨论了定压摩尔热容实验值与实验温度的关系。实验结果表明,在实验条件下,含铁闪锌矿的定压摩尔热容与纯闪锌矿的定压摩尔热容存在显著差异,Ｆｅ置换Ｚｎ是造成这种差异的主要原因。     

Formation of the Dongmozhazhua Pb–Zn Deposit in the Thrust‐Fold Setting of the Tibetan Plateau,China: Evidence from Fluid Inclusion and Stable Isotope Data

The Dongmozhazhua deposit, the largest Pb–Zn deposit in south Qinghai, China, is stratabound, carbonate‐hosted and associated with epigenetic dolomitization and silicification of Lower–Middle Permian—Upper Triassic limestones in the hanging walls of a Cenozoic thrust fault system. The mineralization is localized in a Cenozoic thrust‐folded belt along the northeastern edge of the Tibetan plateau, which was formed due to the India–Asia plate collision during the early Tertiary. The deposit comprises 16 orebodies with variable thicknesses (1.5–26.3 m) and lengths (160–1820 m). The ores occur as dissemination, vein, and breccia cement. The main sulfide assemblage is sphalerite + galena + pyrite + marcasite ± chalcopyrite ± tetrahedrite, and gangue minerals consist mainly of calcite, dolomite, barite, and quartz. Samples of pre‐ to post‐ore stages calcite yielded δ¹³C and δ¹⁸O values that are, respectively, similar to and lower than those yielded by the host limestones, suggesting that the calcite formed from fluids derived from carbonate dissolution. Fluid inclusions in calcite and sphalerite in the polymetallic sulfidization stage mostly comprise liquid and gas phases at room temperature, with moderate homogenization temperatures (100–140°C) and high salinities (21–28 wt% NaCl eq.). Micro‐thermometric fluid inclusion data point to polysaline brines as ore‐forming fluids. The δD and δ¹⁸O values of ore fluids, cation compositions of fluid inclusions, and geological information suggest two main possible fluid sources, namely basinal brines and evaporated seawater. The fluid inclusion data and regional geology suggest that basinal brines derived from Tertiary basins located southeast of the Dongmozhazhua deposit migrated along deep detachment zones of the regional thrust system, leached substantial base metals from country rocks, and finally ascended along thrust faults at Dongmozhazhua. There, the base‐metal‐rich basinal brines mixed with bacterially‐reduced H₂S‐bearing fluids derived from evaporated seawater preserved in the Permo–Triassic carbonate strata. The mixing of the two fluids resulted in Pb–Zn mineralization. The Dongmozhazhua Pb–Zn deposit has many characteristics that are similar to MVT Pb–Zn deposits worldwide.     

The magmatic–hydrothermal transition—evidence from quartz phenocryst textures and endoskarn abundance in Cu–Zn skarns at the Empire Mine, Idaho, USA

Information about the magmatic to hydrothermal transition is preserved in late-stage features of quartz phenocrysts and endoskarn alteration in some Cu–Zn skarn deposits such as the Empire Mine in Idaho. Important features include: (1) quartz phenocrysts with strong resorption textures such as vermicular zones of igneous groundmass cutting primary quartz cathodoluminescence banding, (2) anomalous amounts of endoskarn (more than 50% of mineralized rock), (3) high F activities as evidenced by fluorite as an accessory mineral in igneous rocks, in alteration assemblages, and in fluid inclusions and by high F in hydroxyl sites in igneous biotite and amphibole, and (4) direct association of Zn, which normally is deposited distally at low temperature, with Cu in proximal locations and in endoskarn. These features are explained by the following model: (1) F lowers the solidus temperature of the magma, thus changing the timing, temperature, and duration of hydrothermal fluid exsolution. (2) Upon magmatic vapor saturation the F-rich hydrothermal fluids form bubbles that adhere to quartz phenocrysts and chemically corrode/tunnel into the quartz forming vermicular resorption textures. (3) F-rich hydrothermal fluids also promote the formation of endoskarn; silicic rocks are attacked by F-rich fluids in the same sense that carbonate wall rocks are dissolved by weakly to moderately acidic hydrothermal fluids. (4) Low fluid exsolution temperature facilitated by high F activity promotes high Zn/Cu ratios in proximal locations due to the solubility of Zn relative to Cu at lower temperatures. This model may be applicable at other localities such as the world-class Cu–Zn skarn Antamina mine, as well as some tin and rapakivi granites.     

吉林集安铅锌矿地球化学与分散元素

吉林集安铅锌矿床是我国最早报导的少数几个典型低温铅锌矿床之一。矿化具有多期次特点 ,富矿体都是多期次矿化叠加的产物。根据矿化先后和矿物生成顺序将矿化分为五个阶段 :①石英 黄铁矿矿化阶段 ;②重晶石 闪锌矿矿化阶段 ;③石英 方铅矿矿化阶段 ;④石英 黄铁矿矿化阶段 ;⑤碳酸盐 氧化矿物矿化阶段。用均一法和爆裂法测得石英、重晶石、闪锌矿包裹体成矿温度变化在 1 1 0℃～ 1 97℃之间。矿床中除含铅锌矿外 ,还有微量的Pt和Pd,并普遍含分散元素Cd、Ga、Tl、In、Se、Ge、Te,其中以Cd含量最高 ,闪锌矿中Cd含量最高可达 71 5 5× 1 0 6。分散元素主要呈类质同象形式赋存在各种矿物之中 ,未发现独立矿物。通过矿床地质和硫铅同位素研究表明该铅锌矿床属低温沉积 改造型层控矿床。     

干旱区绿洲土壤共存重金属元素形态变化及生物有效性实验分析——以Cd、Zn、Ni元素为例

采用盆栽试验,初步研究了干旱区绿洲土壤—胡萝卜系统中镉、锌、镍3种重金属的形态变化特征及其生物有效性问题。结果表明:供试绿洲土壤原状土中,Cd、Zn、Ni均以稳定的残渣态形式存在,而处理土壤中重金属被钝化的量有限,Cd的存在形式主要以碳酸盐态为主,Zn、Ni则主要以铁锰氧化态为主;3种元素的活性大小依次为Cd>Ni>Zn。根据回归分析,元素Zn对胡萝卜块茎和茎叶吸收Zn量贡献最大的分别是Zn的碳酸盐结合态和铁锰氧化态;元素Ni对胡萝卜各部位吸收贡献最大的均为Ni的铁锰氧化态。